Kerogen: chemical structure and formation conditions

The available data on the composition of the pyrolysis products of kerogen from the Mesozoic carbonaceous strata of the Russian Plate evidence that changes in the contents of total organic carbon (TOC) lead to a regular change of the mechanisms of organic-matter (OM) conservation in sediments. Each mechanism prevails for particular TOC contents. The initial increase in the TOC content of rocks is accounted for by the fact that the higher is the biologic productivity of the basin, the higher is the portion of nonmineralized organic matter. This is due mainly to the mechanism of selective accumulation of the most stable biochemical components such as algaenan. The appearance of H₂S first in the pore waters of sediment and then in the water column increases the degree of preservation of initial OM at the expense of its sulfurization. This process runs first in the lipid and then in the carbohydrate fractions of initial OM.     

Overview of the potential of microalgae for CO2 sequestration

An economic and environmentally friendly approach of overcoming the problem of fossil CO₂ emissions would be to reuse it through fixation into biomass. Carbon dioxide (CO₂), which is the basis for the formation of complex sugars by green plants and microalgae through photosynthesis, has been shown to significantly increase the growth rates of certain microalgal species. Microalgae possess a greater capacity to fix CO₂ compared to C₄ plants. Selection of appropriate microalgal strains is based on the CO₂ fixation and tolerance capability together with lipid potential, both of which are a function of biomass productivity. Microalgae can be propagated in open raceway ponds or closed photobioreactors. Biological CO₂ fixation also depends on the tolerance of selected strains to high temperatures and the amount of CO₂ present in flue gas, together with SO_x and NO_x. Potential uses of microalgal biomass after sequestration could include biodiesel production, fodder for livestock, production of colorants and vitamins. This review summarizes commonly employed microalgal species as well as the physiological pathway involved in the biochemistry of CO₂ fixation. It also presents an outlook on microalgal propagation systems for CO₂ sequestration as well as a summary on the life cycle analysis of the process.     

Volatile emissions and gas geochemistry of Hot Spring Basin,Yellowstone National Park,USA

We characterize and quantify volatile emissions at Hot Spring Basin (HSB), a large acid-sulfate region that lies just outside the northeastern edge of the 640 ka Yellowstone Caldera. Relative to other thermal areas in Yellowstone, HSB gases are rich in He and H₂, and mildly enriched in CH₄ and H₂S. Gas compositions are consistent with boiling directly off a deep geothermal liquid at depth as it migrates toward the surface. This fluid, and the gases evolved from it, carries geochemical signatures of magmatic volatiles and water–rock reactions with multiple crustal sources, including limestones or quartz-rich sediments with low K/U (or ^40?Ar/^4?He). Variations in gas chemistry across the region reflect reservoir heterogeneity and variable degrees of boiling. Gas-geothermometer temperatures approach 300 °C and suggest that the reservoir feeding HSB is one of the hottest at Yellowstone. Diffuse CO₂ flux in the western basin of HSB, as measured by accumulation-chamber methods, is similar in magnitude to other acid-sulfate areas of Yellowstone and is well correlated to shallow soil temperatures. The extrapolation of diffuse CO₂ fluxes across all the thermal/altered area suggests that 410 ± 140 t d^− 1 CO₂ are emitted at HSB (vent emissions not included). Diffuse fluxes of H₂S were measured in Yellowstone for the first time and likely exceed 2.4 t d^− 1 at HSB. Comparing estimates of the total estimated diffuse H₂S emission to the amount of sulfur as SO₄²⁻ in streams indicates ~ 50% of the original H₂S in the gas emission is lost into shallow groundwater, precipitated as native sulfur, or vented through fumaroles. We estimate the heat output of HSB as ~ 140–370 MW using CO₂ as a tracer for steam condensate, but not including the contribution from fumaroles and hydrothermal vents. Overall, the diffuse heat and volatile fluxes of HSB are as great as some active volcanoes, but they are a small fraction (1–3% for CO₂, 2–8% for heat) of that estimated for the entire Yellowstone system.     

Variability of parameters of the <Emphasis Type="Italic">F</Emphasis>2-layer maximum in the quiet midlatitude ionosphere under low solar activity: 1. Statistical properties

Results of statistical analysis of the properties of variability of F2-layer maximum parameters (critical frequency foF2 and the height hmF2) in quiet midlatitude ionosphere under low solar activity in the daytime (1000–1500 LT) and nighttime (2200–0300 LT) hours are presented on the basis of Irkutsk station data for 2007–2008. It is found that the distribution density of δfoF2 could be presented as consisting of two distinctly different normal laws of this distribution, one of which corresponds to weak (|δfoF2| < 10%) fluctuations in foF2 and the other corresponds to strong (30% > |δfoF2| > 10%) fluctuations. Weak fluctuations in foF2 to a substantial degree are related to ionospheric variability at times less of than 1–3 h and determine the δfoF2 variability in the daytime hours. Strong fluctuations in foF2 are mainly related to day-to-day variability of the ionosphere at a fixed local time, the variability increasing by approximately a factor of 3 during the transition from day to night and determining the δfoF2 variability in the nighttime hours. The distribution density of ΔhmF2 is close to the normal distribution law. An interpretation of the different character of the distribution densities of δfoF2 and ΔhmF2 is given.     

The effect of low level supplementary heating on diving duration

The exothermic reaction which proceeds when small sachets containing particulate mixtures of iron and magnesium are flooded with sea water, has been used for thermal support of free divers. Initial application of such generators to heating of the hands (Burton and Chan, 1981), and later extension to heating of the torso, have been described previously (Chan and Burton, 1981, 1982). Of considerable interest during field trials of the torso heating system was a strong subjective impression among those taking part, that significant increases of dive duration and decreases of perceived discomfort could be obtained with relatively low levels of power generation, for example less than 50% of that required for thermal balance. In this paper, a simple mathematical model of human stored heat loss is used to rationalize this observation. Also it successfully predicts voluntary exposure times of unheated divers who become cold. When used to estimate body heat debt, the model enables documented dives by this laboratory and by others, including recent exposures in Antarctica using low level supplementary heating, to be analysed.     

Some anisotropic spatially-homogeneous cosmological models with electromagnetic field

Considering Bianchi type-I metric, cosmological models of a perfect fluid with an electromagnetic field have been obtained, using a supplementary condition between the metric potentials. The four-current is either zero or space-like. The model has expanding and shearing but non-rotating fluid flow which is also geodetic. The requirement of positive conductivity imposes an additional restriction on the model. Various physical and mathematical properties of the model have been discussed.     

Comparisons of the Mg II index products from the NOAA-9 and NOAA-11 SBUV/2 Instruments

The Mg II Index is a proxy indicator of solar UV activity which is produced from measurements of the chromospheric Mg II absorption line at 280 nm. Mg II index data sets have been derived from the NOAA-9 and NOAA-11 SBUV/2 irradiance data sets using both discrete scan measurements about the Mg II line and continuous scan (sweep) measurements over the UV spectrum from 160–400 nm. This paper will discuss the rationale behind the creation of the different Mg II index products, and make a quantitative assessment of the differences between these products. Recommendations for future use of the Mg II index will also be presented.     

Seismic Noise H/V Spectral Ratio Can Be Inverted Jointly with Receiver Functions

Izvestiya, Physics of the Solid Earth - The possibility of jointly inverting the receiver function waveforms and the seismic noise horizontal-to-vertical spectral ratio to study the Earth’s...     

Age, composition of rocks, and geological setting of the Snezhnoe beryllium deposit: Substantiation of the Late Paleozoic East Sayan rare-metal zone, Russia

The Snezhnoe phenakite-beryl deposit is one of the highest-grade deposits in the Altai-Sayan beryllium province. This deposit is spatially associated with the alkali granite of the Ognit Complex and localized in the apical part of the granitic pluton. The trace element composition of granite, as well as of Be and Ta-Nb ores was studied. The Rb-Sr age of Be mineralization estimated at 305 Ma is consistent with the time of formation of numerous rare-metal alkali granitic plutons in the Eastern Sayan and the eastern Tuva. The region of these granitic plutons is outlined as the Late Paleozoic East Sayan rare-metal metallogenic zone specialized for Nb, Ta, Be, Li, Zr, Th, and REE mineralization. The East Sayan zone is localized in the marginal part of the Barguzin igneous province and is similar to the marginal zone of this province in composition of igneous associations and metallogenic specialization. The formation of the Barguzin igneous province and the East Sayan metallogenic zone is related to the evolution of the Late Carboniferous-Early Permian mantle plume.