Chemistry of snow and lake water in Antarctic region

Surface snow and lake water samples were collected at different locations around Indian station at Antarctica, Maitri, during December 2004–March 2005 and December 2006–March 2007. Samples were analyzed for major chemical ions. It is found that average pH value of snow is 6.1. Average pH value of lake water with low chemical content is 6.2 and of lake water with high chemical content is 6.5. The Na⁺ and Cl^? are the most abundantly occurring ions at Antarctica. Considerable amount of SO ₄ ^2? is also found in the surface snow and the lake water which is attributed to the oxidation of DMS produced by marine phytoplankton. Neutralization of acidic components of snow is mainly done by NH ₄ ⁺ and Mg²⁺. The Mg²⁺, Ca²⁺ and K⁺ are nearly equally effective in neutralizing the acidic components in lake water. The NH ₄ ⁺ and SO ₄ ^2? occur over the Antarctica region mostly in the form of (NH₄)₂SO₄.     

Behavior of the cosmic ray density during the initial phase of the Forbush effect

Variations in the cosmic ray density during the initial phase of the Forbush effect during the first hours after the arrival of the interplanetary shock wave have been studied with the use of data on variations in the cosmic ray density with a rigidity of 10 GV obtained by the global survey method by the world network of neutron monitors in 1957?2012. It is found that behavior of this parameter after the arrival of the shock wave demonstrates high variability. A small (~1/5 of total number), though distinct, group of Forbush effects, in which the density of the cosmic ray increases (not decreases) after the arrival of the shock wave, is defined. As a whole, the initial variation in cosmic ray density is correlated with the Forbush effect magnitude and the strength of the associated geomagnetic disturbance.     

Laboratory kinetics of C2H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.     

Partially Fused Granite Blocks from Mt. Elephant, Victoria, Australia

Petrological and chemical evidence is presented to show thatsmall patches of brown glass found in blocks of granite eruptedin basaltic scoria at Mt. Elephant are the result of the partialfusion of biotite and quartz. The glass has moderate SiO₂ (63–66per cent), high AI₂O₃ (17.5–19 per cent), high FeO (3.8–5.2per cent) and very high K₂O (7.0–7.8 per cent) relativeto Na₂O (3.3–3.7 per cent) and is similar in compositionto many high K alkali syenites and trachytes.     

Ultramafic–Mafic Assemblage of Plutonic Rocks and Hornblende Schists of Shirshov Rise,Bering Sea,and Stalemate Ridge,Northwest Pacific: Geodynamic Interpretations of Geochemical Data

The paper presents data on plutonic and metamorphic rocks dredged during Cruise 249 of the German R/V Sonne to the Stalemate Ridge, Northwest Pacific Ocean and the Shirshov Rise, western Bering Sea. Dredges in the northwestern sector of the Stalemate Ridge and central portion of the Shirshov Rise show that the plutonic and metamorphic rocks obtained here are amazingly similar. Our petrologic and geochemical data led us to view the rocks as members of a mafic–ultramafic assemblage typical of cumulate portions of ophiolite complexes and backarc spreading centers. The plutonic complexes of the Shirshov Rise and Stalemate Ridge show similarities not only in the petrography and mineralogy of their protoliths but also in the character of their metamorphic transformations. Plutonic rocks from both areas display mineralogical evidence of metamorphism within a broad temperature range: from the high-temperature amphibolite facies to the greenschist facies. Relations between the index mineral assemblages indicate that the metamorphic history of plutonic complexes in the Stalemate Ridge and Shirshov Rise proceeded along a retrograde path. Hornblende schists accompanying the plutonic rocks of the Stalemate Ridge and Shirshov Rise are petrographically close to foliated amphibolites in subophiolitic metamorphic aureoles. Within the framework of geodynamic interpretations of our results, it is realistic to suggest that the examined plutonic complexes were exhumed from subduction zones of various age.     

Application on Floor Water Inrush Evaluation Based on AHP Variation Coefficient Method with GIS

The prediction and prevention of floor water inrush is directly related to the safety of the coal mine production. The previous evaluation method of floor water inrush was more one-sided and lacked main control factors related to mining conditions. In order to evaluate the floor water inrush more accurately, under the project background of geological data of Wanglou coal mine, stope width, mining depth, fault scale index, water pressure, water abundance and thickness of aquifer were selected as main controlling factors of floor water inrush. Combined with the subjective weight analytical hierarchy process and the objective weight variation coefficient method, the weight coefficients corresponding to the main controlling factors were obtained respectively. The thematic map of the risk assessment of coal seam floor water inrush was drawn by combining the constructed comprehensive weight vulnerability index model and geographic information system. The results show that: ① according to the actual geological data of mine, two fault related factors were removed. And stope width and mining depth were increased as the main controlling factors to evaluate floor water inrush. It is easier to compare and calculate the weight of evaluation factors. ② The constructed comprehensive weight vulnerability index model can comprehensively evaluate the risk of floor water inrush. And the results of the evaluation are more accurate. ③ The related thematic maps can directly reflect the risk of floor water inrush, which is of guiding significance for the prediction and prevention of coal seam floor water inrush.     

Magmatic Evolution of the La Pacana Caldera System, Central Andes, Chile: Compositional Variation of Two Cogenetic, Large-Volume Felsic Ignimbrites

La Pacana is one of the largest known calderas on Earth, andis the source of at least two major ignimbrite eruptions witha combined volume of some 2700 km³. These ignimbrites have stronglycontrasting compositions, raising the question of whether theyare genetically related. The Toconao ignimbrite is crystal poor,and contains rhyolitic (76–77 wt % SiO₂) tube pumices.The overlying Atana ignimbrite is a homogeneous tuff whose pumiceis dacitic (66–70 wt % SiO₂), dense (40–60% vesicularity)and crystal rich (30–40 % crystals). Phase equilibriaindicate that the Atana magma equilibrated at temperatures of770–790°C with melt water contents of 3·1–4·4wt %. The pre-eruptive Toconao magma was cooler (730–750°C)and its melt more water rich (6·3–6·8 wt% H₂O). A pressure of 200 MPa is inferred from mineral barometryfor the Atana magma chamber. Isotope compositions are variablebut overlapping for both units (⁸⁷Sr/⁸⁶Sr_i 0·7094–0·7131;¹⁴³Nd/¹⁴⁴Nd 0·51222–0·51230) and are consistentwith a dominantly crustal origin. Glass analyses from Atanapumices are similar in composition to those in Toconao tubepumices, demonstrating that the Toconao magma could representa differentiated melt of the Atana magma. Fractional crystallizationmodelling suggests that the Toconao magma can be produced by30% crystallization of the observed Atana mineral phases. Toconaomelt characteristics and intensive parameters are consistentwith a volatile oversaturation-driven eruption. However, thelow H₂O content, high viscosity and high crystal content ofthe Atana magma imply an external eruption trigger. KEY WORDS: Central Andes; crystal-rich dacite; eruption trigger; high-silica rhyolite; zoned magma chamber     

A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.