Trace-element composition and zoning in clinopyroxene- and amphibole-group minerals: Implications for element partitioning and evolution of carbonatites

The present work is a first comprehensive study of the trace-element composition and zoning in clinopyroxene- and amphibole-group minerals from carbonatites, incorporating samples from 14 localities worldwide (Afrikanda, Aley, Alnö, Blue River, Eden Lake, Huayangchuan, Murun, Oka, Ozernaya Varaka, Ozernyi, Paint Lake, Pinghe, Prairie Lake, Turiy Mys). The new electron-microprobe data presented here significantly extend the known compositional range of clinopyroxenes and amphiboles from carbonatites. These data confirm that calcic and sodic clinopyroxenes from carbonatites are not separated by a compositional gap, instead forming an arcuate trend from nearly pure diopside through intermediate aegirine–augite compositions confined to a limited range of CaFeSi₂O₆ contents (15–45 mol%) to aegirine with < 25 mol% of CaMgSi₂O₆ and a negligible proportion of CaFeSi₂O₆. A large set of LA-ICPMS data shows that the clinopyroxenes of different composition are characterized by relatively low levels of Cr, Co and Ni (≤ 40 ppm) and manifold variations in the concentration of trivalent lithophile and some incompatible elements (1–150 ppm Sc, 26–6870 ppm V, 5–550 ppm Sr, 90–2360 ppm Zr, and nil to 150 ppm REE), recorded in some cases within a single crystal. The relative contribution of clinopyroxenes to the whole-rock Rb, Nb, Ta, Th and U budget is negligible. The major-element compositional range of amphiboles spans from alkali- and Al-poor members (tremolite) to Na–Al-rich Mg- or, less commonly, Fe-dominant members (magnesiohastingsite, hastingsite and pargasite), to calcic–sodic, sodic and potassic–sodic compositions intermediate between magnesio-ferrikatophorite, richterite, magnesioriebeckite, ferri-nyböite and (potassic-)magnesio-arfvedsonite. In comparison with the clinopyroxenes, the amphiboles contain similar levels of tetravalent high-field-strength elements (Ti, Zr and Hf) and compatible transition elements (Cr, Co and Ni), but are capable of incorporating much higher concentrations of Sc and incompatible elements (up to 500 ppm Sc, 43 ppm Rb, 1470 ppm Sr, 1230 ppm Ba, 80 ppm Pb, 1070 ppm REE, 140 ppm Y, and 180 ppm Nb). In some carbonatites, amphiboles contribute as much as 25% of the Zr + Hf, 15% of the Sr and 35% of the Rb + Ba whole-rock budget. Both clinopyroxenes and amphiboles may also host a significant share (~ 10%) of the bulk heavy-REE content. Our trace-element data show that the partitioning of REE between clinopyroxene (and, in some samples, amphibole) and the melt is clearly bimodal and requires a revision of the existing models assuming single-site REE partitioning. Clinopyroxenes and amphiboles from carbonatites exhibit a diversity of zoning patterns that cannot be explained exclusively on the basis of crystal chemistry and relative compatibility of different trace-element in these minerals. Paragenetic analysis indicates that in most cases, the observed zoning patterns develop in response to removal of selected trace elements by phases co-precipitating with clinopyroxene and amphibole (especially magnetite, fluorapatite, phlogopite and pyrochlore). With the exception of magnesiohastingsite–richterite sample from Afrikanda, the invariability of trace-element ratios in the majority of zoned clinopyroxene and amphibole crystals implies that fluids are not involved in the development of zoning in these minerals. The implications of the new trace-element data for mineral exploration targeting REE, Nb and other types of carbonatite-hosted rare-metal mineralization are discussed.     

The Mechanical Coupling of Fluid-Filled Granular Material Under Shear

The coupled mechanics of fluid-filled granular media controls the physics of many Earth systems, for example saturated soils, fault gouge, and landslide shear zones. It is well established that when the pore fluid pressure rises, the shear resistance of fluid-filled granular systems decreases, and, as a result, catastrophic events such as soil liquefaction, earthquakes, and accelerating landslides may be triggered. Alternatively, when the pore pressure drops, the shear resistance of these geosystems increases. Despite the great importance of the coupled mechanics of grain–fluid systems, the basic physics that controls this coupling is far from understood. Fundamental questions that must be addressed include: what are the processes that control pore fluid pressurization and depressurization in response to deformation of the granular skeleton? and how do variations of pore pressure affect the mechanical strength of the grains skeleton? To answer these questions, a formulation for the pore fluid pressure and flow has been developed from mass and momentum conservation, and is coupled with a granular dynamics algorithm that solves the grain dynamics, to form a fully coupled model. The pore fluid formulation reveals that the evolution of pore pressure obeys viscoelastic rheology in response to pore space variations. Under undrained conditions elastic-like behavior dominates and leads to a linear relationship between pore pressure and overall volumetric strain. Viscous-like behavior dominates under well-drained conditions and leads to a linear relationship between pore pressure and volumetric strain rate. Numerical simulations reveal the possibility of liquefaction under drained and initially over-compacted conditions, which were often believed to be resistant to liquefaction. Under such conditions liquefaction occurs during short compactive phases that punctuate the overall dilative trend. In addition, the previously recognized generation of elevated pore pressure under undrained compactive conditions is observed. Simulations also show that during liquefaction events stress chains are detached, the external load becomes completely supported by the pressurized pore fluid, and shear resistance vanishes.     

Data base management system for erosivity values

In order to check the premature siltation of the reservoirs and guard against the drop in the irrigation potential, the Government of India has launched the schemes of soil conservation and integrated watershed management in the catchments of RVPs and Flood Prone rivers. Owing to the large financial and manpower commitments needed to implement and execute soil conservation measures over vast catchment areas, a priority approach for treatment was identified. The methodology developed for prioritization of watersheds of a catchment area conceptualizes sedimentation of the reservoirs as a multiplicative function of erosivity value and the delivery ratio. This paper deals with the development of a computerized data base software module ‘WEIGHT’ for determination of erosivity values for the mapping units comprising assemblages of the varying combinations of climate, physiography and slope, land use and cover conditions, soil characteristics (texture, solumn thickness, permeability and pH) and the existing erosion and soil conservation measures. The WEIGHT software package is coded in FORTRON-4 for PDP 11/83 operating system. the data base comprises storage of the attributes of the different erosivity determinants of the mapping units with predetermined erosivity values sequentially on a disk and comparing the attributes of a new mapping unit to get the most probabilities erosivity value. The objective has been to eliminate the personal bias and bring about the objectivity in the process of assigning erosivity values to the different mapping units. The data base design, design logic and operational sequence of the data base are discussed in the paper.     

X-ray transient sources

The galactic distribution and physical nature of X-ray transient sources is investigated. Two types of transients are considered. The observational data on 41 X-ray transient sources are given, and the average parameters of hard and soft X-ray transients are estimated.     

On the existence of a second scale of convection in the upper mantle

Summary. This paper is concerned with an examination of the possibility that there might exist a small scale of convective circulation beneath the oceanic lithosphere. Recent suggestions that this might be the case have been made in an effort to understand why the bathymetry of the sea-floor deviates from the prediction of boundary layer theory for ages in excess of about 100 Ma. The energy source which sustains the secondary motion is supposed to be found in the steep temperature gradient near the planetary surface which is itself presumably maintained by the large-scale convective circulation associated with plate creation and destruction. Here we investigate the extent to which the temperature dependence of viscosity may act so as to stabilize the upper boundary layer against disruption by such secondary instability. If the viscosity profile is monotonie and the asymptotic upper mantle viscosity is about 10²²poise, as suggested by post-glacial rebound data, then the existence of the second scale is extremely unlikely. On the other hand, if a sufficiently pronounced low viscosity zone does exist under old sea-floor then the development of such a second scale cannot be ruled out completely. Some recently obtained geophysical evidence is reviewed which suggests that this is unlikely to be the case.     

Density and conductivity properties of Na−CO3−Cl−SO4 brine from Mono Lake, California, USA

Relationships among conductivity, temperature, total dissolved solids (TDS), and density were determined for hypersaline brine (TDS, 83 g kg⁻¹) from Mono Lake. A theoretical estimate of density based on ionic composition and calculated partial molar volumes compared well with actual measurements (difference, 390 ppm). However, an empirically derived equation of state based on temperature and conductivity provides the most accurate density estimates (residual errors, 190 ppm) and can be used with data collected with CTD profilers.     

The Upper Middle Rhine Valley as a risk area

The Upper Middle Rhine Valley, granted the status of a World Heritage site, is well known for its unique inner narrow valley of Quaternary age with its historical legacy of numerous medieval castles and old towns. Less known is that this has always been a risk area of floods and gravitative mass movements. Up to the recent past, mainly ice floods caused enormous damage. The inhabitants of the valley were well aware that they lived in a risk area, but they had learned to handle the flood hazard. With the demise of ice floods over the last 40 years, due to climate change and because of the additional heating of the river water by power plants, the awareness of flood hazards has been much diminished, in contrast to that of potential damage by rockfalls and landslides which were also much feared in the past, though at the local level only. Still in the people’s memory is the Kaub catastrophe of March 10, 1876, when 28 persons were killed by a landslide. Nowadays, even minor rockfalls are a major threat, as they will affect the much-used traffic lines on both banks of the river, in particular the railroads. Therefore, since 2002, on behalf of German Rail (Deutsche Bahn, DB), all problematic slopes have been protected by costly steel-ring nets, although they are an aesthetic problem by UNESCO standards. The feeling of absolute safety created among the public is only subjective, though, as planners are well aware of. Moreover, the impact of modern climate change on slope stability is nearly unknown. Therefore, it is still necessary to develop a risk map for the narrow valley, with emphasis on gravitational hazards.     

The impact of binary-star yields on the spectra of galaxies

One of the complexities in modelling integrated spectra of stellar populations is the effect of interacting binary stars besides Type Ia supernovae (SNeIa). These include common envelope systems, cataclysmic variables, novae, and are usually ignored in models predicting the chemistry and spectral absorption line strengths in galaxies. In this paper, predictions of chemical yields from populations of single and binary stars are incorporated into a galactic chemical evolution model to explore the significance of the effects of these other binary yields. Effects on spectral line strengths from different progenitor channels of SNeIa are also explored. Small systematic effects are found when the yields from binaries, other than SNeIa, are included, for a given star formation history. These effects are, at present, within the observational uncertainties on the line strengths. More serious differences can arise in considering different types of SNIa models, their rates and contributions.