Aqueous alteration of the Bali CV3 chondrite: evidence from mineralogy, mineral chemistry, and oxygen isotopic compositions

A petrographic, geochemical, and oxygen isotopic study of the Bali CV3 carbonaceous chondrite revealed that the meteorite has undergone extensive deformation and aqueous alteration on its parent body. Deformation textures are common and include flattened chondrules, a well-developed foliation, and the presence of distinctive (100) planar defects in olivine. The occurrence of alteration products associated with the planar defects indicates that the deformation features formed prior to the episode of aqueous alteration. The secondary minerals produced during the alteration event include well-crystallized Mg-rich saponite, framboidal magnetite, and Ca-phosphates. The alteration products are not homogeneously distributed throughout the meteorite, but occur in regions adjacent to relatively unaltered material, such as veins of altered material following the foliation. The alteration assemblage formed under oxidizing conditions at relatively low temperatures (<100 degrees C). Altered regions in Bali have higher Na, Ca, and P contents than unaltered regions which suggests that the fluid phase carried significant dissolved solids. Oxygen isotopic compositions for unaltered regions in Bali fall within the field for other CV3 whole-rocks, however, the oxygen isotopic compositions of the heavily altered material lie in the region for the CM and CR chondrites. The heavy-isotope enrichment of the altered regions in Bali suggest alteration conditions similar to those for the petrographic type-2 carbonaceous chondrites.     

Solubilities of some hydrous REE phosphates with implications for diagenesis and sea water concentrations

Solubility product determinations suggest that the hydrous phosphates of the rare earths, REPO₄ · $\text{xH}{}_2\text{O}$, are important in controlling the sea water REE concentrations. Two of these solids, rhabdophane, (P6₂22) and “hydrous xenotime”, (14₁/amd), have been synthesized at 100°C via the acid hydrolysis of the respective REE pyrophosphate. The solubility products at infinite dilution were determined to be $\text{pK}{}^0\text{= 24.5}$, (La at 25°C); 26.0, (Pr at 100°C); 25.7, (Nd at 100°C): and 25.5, (Er at 100°C). On the basis of calculations involving the reaction of RE³⁺ with apatite to form the hydrous phosphate, the lanthanum concentration in sea water is predicted to be about 140 pmol/L. Laboratory experiments support the hypothesis that apatite is a substrate for reactions with dissolved REE.     

The influence of subsurface moisture on rill system evolution

Rill development studies have focused almost exclusively on surface erosion processes and critical threshold hydraulic conditions. Characteristic rill features, such as arcuate headcuts and knickpoints, are morphologically similar to the ‘theatre-headed’ valleys which have been associated with ‘sapping’ processes at various scales. This paper reports on laboratory experiments designed to identify linkages between surface flow hydraulics, subsurface moisture conditions and rill development. Experiments were carried out in a 16·57 m² flume under simulated rainfall with soil samples up to 0·15 m depth in which moisture conditions were monitored by miniature time-domain reflectometer probes. Tests showed complex responses in which some rill incision reflected surface flow conditions, but major rill system development with markedly enhanced sediment yield was closely associated with high soil moisture contents. It was not possible to measure seepage forces directly, but calculation and observation indicate that these were less important than reduction in soil strength with saturation, which resulted in increased effective runoff erosivity. This caused concentrated undercutting along the water table at rill walls, while slightly stronger surface layers above the water table formed microscarps. These retreated along the water table into interrill surfaces, producing residual pediment transport slopes. The microscarps eventually disappeared when the water table reached the surface, eliminating differential soil strength. The experiments showed complex relationships between surface and subsurface erosional processes in evolving rill systems, strongly influenced by soil moisture dynamics. The very small topographic and hydraulic head amplitudes indicate that seepage forces and ‘sapping’ were minimal. The dominant effect of soil moisture was reduction of soil strength with saturation, and increased runoff entrainment. Experimental conditions were not unusual, either for agricultural fields or natural hillslopes, and the intricate interrelationship of surface and subsurface erosion processes observed is probably not uncommon. Attempts to link specific morphologic features at rill scale to dominance of surface or subsurface processes alone are therefore unlikely to be successful or reliable. © 1998 John Wiley & Sons, Ltd.     

Isolation of integrals for centroid orbits in stellar system models

In this paper we present two solutions for isolating integrals of the centroid motion in a non-stationary stellar system under the ellipsoidal hypothesis with point-axial symmetry.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.     

Symbiotic Binary YY Her – Eclipses, Flares and Outbursts

The long-term CCD and photoelectric observations of YY Her covering the period of its post-outburst activity (JD 2 451 823 -- 2 452 996) are presented. We explain the periodic variations of the brightness of YY Her by the eclipses of the components in the system. The model with a deformed (non-homogeneous) envelope, surrounding the white dwarf is discussed. In addition, we observed a flare in about JD 2 452 440, during the primary minimum, that was later followed by an energetic outburst in JD 2 452 700.     

Successful sidetracking of a well onshore Germany by integration of 3D vertical seismic profiling technology – a case study

The exploration for and exploitation of deep Lower Rotliegend gasfields onshore in North Germany often suffers from poor surface seismic imaging. This is owing to the depth of the reservoirs and a thick and complex Zechstein salt overburden. RWE Dea conducted a 3D vertical seismic profile (VSP) survey in a low‐performing production well after the borehole was plugged near total depth. Our main objective was to improve the seismic image of the reservoir zone in the vicinity of the well to determine a new landing point for a planned sidetrack. Because acquisition was in a densely populated and also partially environmentally protected area, there were surface restrictions concerning source deployment. Additionally, due to the complex geological setting, we conducted two 2D VSP field tests and thorough pre‐survey modelling to achieve the best results in terms of seismic imaging, environmental impact and reasonable cost. Deformation bands in the drill core suggest that the initial well was drilled close to a major fault, which was regarded as the main reason for the disappointing production rate. Therefore, we put special emphasis on fault detection in our processing and interpretation. Our interpretation approach used an enhanced structural mapping workflow that helped to design a sidetrack. When the sidetrack was drilled two years later, it ended up being one of the most productive wells in the field.     

Continental ridges in the Arctic Ocean: Lorex constraints

Recent multidisciplinary geophysical measurements over the Lomonosov Ridge close to the North Pole support the widely held belief that it was formerly part of Eurasia. The known lithologies, ages, P-wave velocity structure and thickness of the crust along the outer Barents and Kara continental shelves are similar to permitted or measured values of these parameters newly acquired over the Lomonosov Ridge. Seismic, gravity and magnetic data in particular show that the ridge basement is most likely formed of early Mesozoic or older sedimentary or low-grade metasedimentary rocks over a crystalline core that is intermediate to basic in composition. Short-wavelength magnetic anomaly highs along the upper ridge flanks and crest may denote the presence of shallow igneous rocks. Because of the uncertain component of ice-rafted material, seafloor sediments recovered from the ridge by shallow sampling techniques cannot be clearly related to ridge basement lithology without further detailed analysis. The ridge is cut at the surface and at depth by normal faults that appear related to the development of the Makarov Basin. This and other data are consistent with the idea that the Makarov Basin was formed by continental stretching rather than simple seafloor spreading. Hence the flanking Alpha and Lomonosov ridges may originally have been part of the same continental block. It is suggested that in Late Cretaceous time this block was sheared from Eurasia along a trans-Arctic left-lateral offset that may have been associated with the opening of Baffin Bay. The continental block was later separated from Eurasia when the North Altantic rift extended into the Arctic region in the Early Tertiary. The data suggest that the Makarov Basin did not form before the onset of rifting in the Artic.     

When is it sensible not to use XML?

This paper considers the problem of comparing the read time for a file containing an array of one-half million one-byte data values using a direct read time with the time required to read an equivalent XML file. The XML file uses a variable-length string encoding of the identifiers associated with each of the byte values. The XML file is about 180 times larger than the original file of byte values. Because the XML file is much larger and because the XML parsing requires substantially more computational work, reading the XML file on a Windows-based PC takes about 3,700 times longer than the direct read. The experimental study shows that the XML read time increases linearly with the size of the file. Given the increased read time and the increased probability of programming errors for the XML encoding, it appears that in cases where data archives are providing simple binary or text files of data that may be readily understood and read with short programs, then XML may not be an optimal choice for serving users or for preserving data.