Removal of diazinon pesticide from aqueous solutions using MCM-41 type materials: isotherms,kinetics and thermodynamics

In this research, ordered mesoporous silica, including MCM-41, was synthesized via sol–gel process and a propyl methacrylate-modified ordered mesoporous silica (MPS-MCM-41) was successfully synthesized via a postsynthesis grafting process. Then both MCM-41 and MPS-MCM-41 were characterized using FTIR, XRD, SEM and BET techniques. The synthesized materials were utilized as adsorbent for removal of diazinon pesticide from aqueous solutions. The effects of pH, contact time, adsorbent dose, initial concentration and temperature have been evaluated using removal efficiencies. Also, the kinetic, thermodynamic and isotherm models of diazinon adsorption were studied for the both MCM-41 and MPS-MCM-41. The results showed that the maximum adsorption capacities are 142 and 254 mg g^?1 for the MCM-41 and MPS-MCM-41, respectively, at the initial concentration of 50 mg L^?1, temperature of 298 K and adsorbent dose of 0.1 g L^?1. The highest percentages of diazinon removal are 56.4 and 87.2 (at adsorbent dose of 2 g L^?1 and the temperature of 318 K) for the MCM-41 and MPS-MCM-41, respectively. The Freundlich and Langmuir models are more compatible for describing equilibrium data of the diazinon adsorption capacity on the MCM-41 and MPS-MCM-41, respectively. Thermodynamic study indicated that the adsorption process of diazinon onto MCM-41 and MPS-MCM-41 is exothermic and has a spontaneous nature. The higher adsorption capacity and higher spontaneous nature of MPS-MCM-41 in comparison with MCM-41 might be due to the presence of the both hydrogen bonding and hydrophobic interaction between surface functional groups of MPS-MCM-41 (hydroxyl and propyl methacrylate) and diazinon functional groups.     

Impact melting of the Cachari eucrite 3.0 Gy ago

Both the host phase and glass veins of the Cachari eucrite have been analyzed by microprobe and neutron activation analysis for their chemical compositions and by mass spectrometry for their ³⁹Ar-⁴⁰Ar gas retention ages. Cachari is chemically similar to other non-cumulate eucrites. The vesicular glass veins vary from pure glass, to devitrified glass, to areas that are substantially crystalline. The glassy areas have nearly the same concentrations of major and trace elements as the unmelted portions of Cachari, but some differences, probably due to preferential dissolution, occur along melt contacts. The glass formed by shock melting of Cachari host or of rock identical to it. ³⁹Ar-⁴⁰Ar data for the host and glass suggest distinctly different ages of 3.04 ±.07 Gy and 3.47 ±.04 Gy, respectively. The time of glass formation, which may also be the time of brecciation, is most likely given by the 3.0 Gy age of the host. The higher age for the glass is interpreted to represent incomplete Ar degassing during the 3.0 Gy event due to the greater resistance to Ar diffusion shown by the glass compared to the host. Event ages significantly younger than 4.5 Gy have now been determined for several eucrites and howardites and suggest a long dynamic regolith history for the parent body.     

Symbiosis between the holothurian Scotoplanes sp. A and the lithodid crab Neolithodes diomedeae on a featureless bathyal sediment plain

Vulnerability to predation may be high for many megafaunal taxa in deep‐sea sedimentary habitats where physical heterogeneity is low. During ROV observations in a bathyal sediment plain off Central California, juveniles of the lithodid crab Neolithodes diomedeae were frequently observed on or under the holothurian (sea cucumber) Scotoplanes sp. A, and are hypothesized to benefit from this association as a nursery or refugium from predation. Ninety‐six percent (n = 574 of 599) of the juvenile N. diomedeae observed (density varied from 0.02–0.75/m² among sites and seasons) in the study area were associated with Scotoplanes sp. A. Of the 2596 Scotoplanes sp. A observed (density varied from 0.48 to 25.90/m²), 22% were attended by at least one juvenile crab, and rarely two crabs (n = 4). Solitary N. diomedeae were rarely observed. This decapod–holothurian symbiosis appears to be largely commensal, with juvenile crabs (carapace width = 0.03–0.31 ×  holothurian length) observed on or beneath Scotoplanes sp. A in a habitat with few refugia from epibenthic predators. Other hypotheses may explain or enhance the potential benefits of the association for N. diomedeae, such as elevated food availability due to the activities of Scotoplanes sp. A. The relationship may be mutualistic if there is a benefit for the holothurian, including the removal of epizoic parasites. Ultimately, the nursery or other effects on the population dynamics of N. diomedeae may be minimal in low‐relief, sediment‐dominated habitats, as very few sub‐adult crabs were observed in the study area and were likely consumed upon outgrowing their refugia. While sedimentary habitats may be a sink for N. diomedeae populations, growth of juvenile crabs during their association with Scotoplanes sp. A should increase energy flow to its predator populations. This association has not been reported previously but may be expected in sediment‐dominated habitats where these species overlap.     

Seismic scattering and shallow structure of the moon in oceanus procellarum

Long, reverberating trains of seismic waves produced by impacts and moonquakes may be interpreted in terms of scattering in a surface layer overlying a non-scattering elastic medium. Model seismic experiments are used to qualitatively demonstrate the correctness of the interpretation. Three types of seismograms are found, near impact, far impact and moonquake. Only near impact and moonquake seismograms contain independent information. Details are given in the paper of the modelling of the scattering processes by the theory of diffusion.Interpretation of moonquake and artificial impact seismograms in two frequency bands from the Apollo 12 site indicates that the scattering layer is 25 km thick, with a Q of 5000. The mean distance between scatterers is approximately 5 km at 25 km depth and approximately 2 km at 14 km depth; the density of scatterers appears to be high near the surface, decreasing with depth. This may indicate that the scatterers are associated with cratering, or are cracks that anneal with depth. Most of the scattered energy is in the form of scattered surface waves.Communication presented at the Lunar Science Institute Conference on Geophysical and Geochemical Exploration of the Moon and Planets, January 10–12, 1973.     

Chesapeake Bay Plume Morphology and the Effects on Nutrient Dynamics and Primary Productivity in the Coastal Zone

To determine the effects of the Chesapeake Bay outflow plume on the coastal ocean, nutrient concentrations and climatology were evaluated in conjunction with nitrogen (N) and carbon (C) uptake rates during a 3-year field study. Sixteen cruises included all seasons and captured high- and low-flow freshwater input scenarios. Event-scale disturbances in freshwater flow and wind speed and direction strongly influenced the location and type of plume present and thus the biological uptake of N and C. As expected, volumetric primary productivity rates did not always correlate with chlorophyll a concentrations, suggesting that high freshwater flow does not translate into high productivity in the coastal zone; rather, high productivity was observed during periods where recycling processes may have dominated. Results suggest that timing of meteorological events, with respect to upwelling or downwelling favorable conditions, plays a crucial role in determining the impact of the estuarine plume on the coastal ocean.     

Crystallization history of rhyolites at Long Valley, California, inferred from combined U-series and Rb-Sr isotope systematics

In this study, we present ⁸⁷Rb/⁸⁶Sr and ²³⁰Th/²³⁸U isotope analyses of glasses and phenocrysts from postcaldera rhyolites erupted between 150 to 100 ka from the Long Valley magmatic system. Both isotope systems indicate complex magma evolution with preeruptive mineral crystallization and magma fractionation, followed by extended storage in a silicic magma reservoir. Glass analyses yield a Rb-Sr isochron of 257 ± 39 ka, which can be explained by a feldspar-fractionation event ∼150 ky before eruption. Individual feldspar-glass pairs confirm this age result. A mineral ²³⁰Th-²³⁸U isochron in a low-silica rhyolite from the Deer Mountain Dome defines an age of 236 ± 1 ka, but the glass and whole rock do not lie on the isochron. U-Th fractionation of the rocks is controlled by the accessory minerals zircon and probably allanite, which crystallized at 250 ± 3 ka and 187 ± 9 ka, respectively. All major mineral phases contain accessory mineral phases; therefore, the mineral isochron represents a mixture of zircon and allanite populations. A precision of ±1 ka for the mixing array implies that the minor phases must have crystallized within this timescale. Longer periods of crystal growth would cause the mixing array to be less well defined. U-series data from other low- and high-silica rhyolites indicate younger accessory mineral crystallization events at ∼200 and 140 ka, probably related to the thermal evolution of the magma reservoir. These crystallization events are, however, only documented by the accessory minerals and had no further influence on bulk magma compositions. We interpret the indistinguishable age results from both isotope systems (∼250 ka) to record the fractionation of small magma batches by filter pressing from a much larger underlying magma volume, followed by physical isolation and extended storage at the top of the magma reservoir for up to 150 ky.     

Ordered mixed-layer structures in the Mighei carbonaceous chondrite matrix

High resolution transmission electron microscopy of the Mighei carbonaceous chondrite matrix has revealed the presence of a new mixed layer structure material. This mixed-layer material consists of an ordered arrangement of serpentine-type (S) and brucite-type (B) layers in the sequence … SBBSBB. … Electron diffraction and imaging techniques show that the basal periodicity is ~ 17 Å. Discrete crystals of SBB-type material are typically curved, of small size (<1 μm) and show structural variations similar to the serpentine group minerals. Mixed-layer material also occurs in association with planar serpentine. Characteristics of SBB-type material are not consistent with known terrestrial mixed-layer clay minerals. Evidence for formation by a condensation event or by subsequent alteration of preexisting material is not yet apparent.     

Magma plumbing beneath Anak Krakatau volcano, Indonesia: evidence for multiple magma storage regions

Understanding magma plumbing is essential for predicting the behaviour of explosive volcanoes. We investigate magma plumbing at the highly active Anak Krakatau volcano (Indonesia), situated on the rim of the 1883 Krakatau caldera by employing a suite of thermobarometric models. These include clinopyroxene-melt thermobarometry, plagioclase-melt thermobarometry, clinopyroxene composition barometry and olivine-melt thermometry. Petrological studies have previously identified shallow magma storage in the region of 2–8 km beneath Krakatau, while existing seismic evidence points towards mid- to deep-crustal storage zone(s), at 9 and 22 km, respectively. Our results show that clinopyroxene in Anak Krakatau lavas crystallized at a depth of 7–12 km, while plagioclase records both shallow crustal (3–7 km) and sub-Moho (23–28 km) levels of crystallization. These magma storage regions coincide with well-constrained major lithological boundaries in the crust, implying that magma ascent and storage at Anak Krakatau is strongly controlled by crustal properties. A tandem seismic tomography survey independently identified a separate upper crustal (<7 km) and a lower to mid-crustal magma storage region (>7 km). Both petrological and seismic methods are sensitive in detecting magma bodies in the crust, but suffer from various limitations. Combined geophysical and petrological surveys, in turn, offer increased potential for a comprehensive characterization of magma plumbing at active volcanic complexes.