Periodic Hartree-Fock study of minerals: Tetracoordinated silica polymorphs

Periodic Hartree-Fock STO-3G calculations have been performed on several tetracoordinated silica polymorphs: low and high quartz, low and idealized high cristobalite and prototype tridymite. The optimized structural parameters are in overall good agreement with experimental data. In the particular case of -quartz, the SiO₄ tetrahedra are found to be irregular. The optimized values of the two different SiO bond lengths are respectively 1.608 Å and 1.613 Å. The potential energy versus tilt angle curves suggest a picture of the high temperature phases in terms of delocalized oxygen atoms which is consistent with a disordered structure. Finally, the bonding in silica polymorphs is discussed from electron density maps and Mulliken population analysis.     

Changes in the Period of Negative Superhumps of Type SU UMa Dwarf Novae. II. NY Her (2017 and 2020)

Astrophysics - Photometric studies of the type SU UMa dwarf nova NY Her were made during 2017 and 2020 at the Crimean Astrophysical Observatory and at the Sanglokh Observatory over a total of 77...     

Detailed mineralogical-geochemical study of a large spinel Lherzolite xenolith in alkali basalt of Shavaryn Tsaram paleovolcano,Mongolia

Mineralogical-geochemical data obtained on a large xenolith of spinel lherzolite from basanites of Shavaryn Tsaram volcano (Middle Pleistocene) provide evidence that the xenolith was affected by heat and fluid that came from the basalt melt and induced geochemical heterogeneity of the xenolith. Olivine crystals from the central portion of the xenolith contain much more CaO than this mineral from the peripheral zones of the xenolith as well as in xenocrystals of the host basalts. The large xenolith was unevenly annealed by the host basalt melt, and this predetermined the heterogeneous diffusion-controlled “purification” of olivine crystals from their CaO admixture. The xenolith is heterogeneously enriched in LREE and some trace elements (Zr, Hf, Nb, Th, and U), and their distribution demonstrates unclearly pronounced concentric zoning: these elements enriched the outer portions of the xenolith. The enrichment of the xenolith in LREE and other mobile trace elements is explained by their occurrence not only as structurally bound (isomorphic) components in minerals but also in the form of nonstructural admixtures (contaminant), as minute grains of compounds hosted in the interstitial space and tiny cracks cutting mineral grains. The enrichment of the xenolith in these admixtures proceeded via their infiltration-controlled introduction with fluid from the basalt along minute cracks.     

Performance of sand and shredded rubber tire mixture as a natural base isolator for earthquake protection

The performance of a well-designed layer of sand, and composites like layer of sand mixed with shredded rubber tire(RSM) as low cost base isolators, is studied in shake table tests in the laboratory. The building foundation is modeled by a 200 mm by 200 mm and 40 mm thick rigid plexi-glass block. The block is placed in the middle of a 1m by 1m tank filled with sand. The selected base isolator is placed between the block and the sand foundation. Accelerometers are placed on top of the footing and foundation sand layer. The displacement of the footing is also measured by LVDT. The whole setup is mounted on a shake table and subjected to sinusoidal motions with varying amplitude and frequency. Sand is found to be effective only at very high amplitude( 0.65 g) of motions. The performance of a composite consisting of sand and 50% shredded rubber tire placed under the footing is found to be most promising as a low-cost effective base isolator.     

Experimental investigation of atmospheric dispersion over the Swiss Plain — Experiment “SIESTA”

Between November 15 and 30, 1985, an international mesoscale transport experiment was performed on the Swiss Plain. Seven meteorological groups from Denmark, Germany, Italy and Switzerland measured diffusion properties of near neutral planetary boundary layers during six completely overcast days: four Bise (north-east wind) situations, one transitional situation and one west-wind situation. Diffusion was measured using SF₆ as tracer, which was released at the meteotower of the Gösgen nuclear power plant at 6 m above ground level. One hundred automatic samplers plus a mobile gas chromatograph were used to measure the concentration fields at distances up to 90 km downwind. Meteorological parameters were observed using radar-tracked constant-level balloons, tethered balloon soundings, sonic anemometers, an acoustic sounder and several meteorological ground stations, including a 110 m mast. All data were collected on a magnetic tape with free access to interested persons.The aim of the experiments was to obtain knowledge about the general nature of the turbulence, advection and atmospheric dispersion during neutral weak-wind situations over complex terrain. The collected data set will be useful for testing mesoscale transport and diffusion models. The results clearly show the channelling effect of the Jura mountains and the hilly prealpine region. An interesting result is that the SF₆ plumes showed intensive horizontal spread but only limited diffusion in the vertical direction.     

Transformation of Lambert Conic Conformal Coordinates from a Global Datum to a Local Datum

This paper treats the problem of how to transform from global datum, for example, from the International Terrestrial Reference System (ITRS), to a local datum, for example, regional or national, for the practical case of the Lambert projection of the sphere or the ellipsoid-of-revolution to the cone. We design the two projection constants n(ϕ₁, ϕ₂) and m(ϕ₁) for the Universal Lambert Conic projection of the ellipsoid-of-revolution. The task to transform from a global datum with respect to the ellipsoid-of-revolution E_A,B² to local datum with respect to the alternative ellipsoid-of-revolution E_a,b², without local ellipsoidal height, is solved by an extended numerical example. Ideas in this paper could be of interest to those working with maps and coordinates transformation from global geodetic datum to local geodetic datum and vice versa, under the Universal Lambert Conic projection, and applicable to precise positioning and navigation, boundary demarcation and determination in the marine environment.     

Spectra of the Black-Sea tsunamis

We perform the analysis of the time spectra of four tsunamis generated in the Black Sea by the earthquakes of 26.07.1927, 11.09.1927, 26.12.1939, and 12.07.1966. For the analysis of the spectra, we used digitized marigrams obtained for 12 points of the Black-Sea coast. The obtained spectra are, as a rule, multimode and have 1–4 spectral maxima. One maximum corresponds to the periods typical of tsunami waves and the other maxima correspond to the oscillations of the sea level with lower frequencies. It seems likely that the events of tsunami are accompanied by low-frequency oscillations of the level caused by the atmospheric forcing, seiches, or other factors. In numerous cases, the oscillations from the predominant energy range lie outside the characteristic range of periods of the tsunami waves. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 5, pp. 21–30, September–October, 2007.