Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.     

The possible formation of a hydrogen coma around comets at large heliocentric distances

An observational test--the detection of a hydrogen coma around comets at large heliocentric distances--is proposed for determining whether comets were formed by the agglomeration of unaltered, ice-coated, interstellar grains. Laboratory experiments showed that amorphous water ice traps H2, D2, and Ne below 20 K and does not release them completely until the ice is heated to 150 K. Gas/ice ratios as high as 0.63 are obtainable. Thus, if the ice-coated interstellar grains were not heated above approximately 110 K, prior to their agglomeration into cometary nuclei, the inward propagating heat waves should release from the comets a continuous flux of molecular hydrogen. This flux would exceed that of water molecules at approximately 3 AU preperihelion and approximately 4 AU postperihelion.     

Variations in the HCN/HNC abundance ratio in the Orion molecular cloud

We have used observations of the rare isotopes of HCN and HNC to determine the relative abundance of these two chemical isomers along the central ridge of the Orion molecular cloud. The abundance ratio [HCN]/[HNC] decreases by more than an order of magnitude from the relatively warm plateau and hot core sources toward the KL nebula to the colder, more quiescent clouds to the north and south. Even in the cooler regions, however, the ratio is an order of magnitude larger than that found in previous investigations of cold dark clouds. We determine the kinetic temperature in the regions we have studied from new observations of methylacetylene (CH3CCH), together with other recent estimates of the gas temperature near KL. The results suggest that the warmer portions of the cloud are dominated by different chemical pathways than those in the general interstellar cloud material.     

徐州土壤多环芳烃的环境地球化学迁移特征

选择江苏徐州黄棕壤进行不同深度层位多环芳烃含量的定量分析,研究并探讨了多环芳烃在土壤深度剖面中的地球化学迁移特征。研究结果显示,多环芳烃在徐州土壤剖面中主要集中在地表0~20 cm内。其中低环多环芳烃化合物的迁移能力较强,4~6环等高环化合物相对较难迁移,主要残留于地表生态系统环境中。     

Geological research at the Natural History Museum of Moscow University, 1759-1930 （in Russian）

In 2006, the Moscow publishing house Nauka （Science） published a 246-page book by Zoya A. Bessudnova entitled Geological Research at the Natural History. Museum of Moscow University, 1759-1930 as No. 32 in its series ＂Sketches on the History of Geological Knowledge＇. The author is a geologist and Senior Researcher in the Department for the History of Geology of the Vernadsky State Geological Museum of the Russian Academy of Sciences, and a member of the International Commission on the History of Geological Sci- ences （INHIGEO）.     

渤海生产力研究——Ⅰ.叶绿素a的分布特征与季节变化

本文阐述了1982—1983年在渤海综合调查中所作的叶绿素a调查,分析研究了叶绿素a时空变化与环境因子的关系.结果表明,渤海水域叶绿素a的数量分布具有明显的时空变化特征,叶绿素a的变化范围为0.2—8.0mg/m3,其季节变化呈双峰状,高峰期在初春3月,次高峰在秋季9,10月间,初夏6月为低值期,冬季12,1月为一年中的最低期,叶绿素a的垂直分布变化不甚明显,春季叶绿素a最大值出现在5m以上水层中,夏、秋季最大值位于5—10m的水层中,冬季水体中叶绿素a的分布较为均匀,初步得出渤海水域叶绿素a分布的季节变化规律.     

Total content and chemical speciation of arsenic in the polychaete Sabella spallanzanii

An unusual feature has been observed in polychaetes regarding their capacity to accumulate high levels of relatively toxic forms of arsenic in specific tissues. Basal levels of arsenic and distribution of its compounds were investigated in tissues of the Mediterranean polychaete Sabella spallanzanii. Particularly high concentrations were measured in the branchial crown (1036+/-136 microg/g d.w.) and chemical speciation revealed that the predominant form was the relatively toxic dimethylarsinate (DMA). These data suggest a potential role of As as anti-predatory strategy in polychaetes.     

长江入海沉积物的输送及其入海后的运移

前言 长江和黄河是世界著名的多沙河流，每年入海泥沙分别为5亿吨和11亿吨，分别占世界的第四位和第二位。千万年来由她们发育了广大的冲积平原，浩浩荡荡东流入海，形成东中国海大陆架沉积物的主要来源。研究长江和黄河沉积物搬运入海的沉积动力过程，不仅对东海大陆架的了解和开发有重要意义，也给陆上经济发展提供科学依据。     

超高分辨率地层灰度曲线扫描与处理

用visal BASIC语言开发的在windows环境下的灰芳扫描软件，根据记录的海洋沉积物岩心的高分辨率数字图像进行岩心图像灰度曲线的数据获取；用计算机进行了岩心灰度曲线的辅助处理，得出不同尺度岩心灰度的变化曲线；根据不同尺芳岩心灰度的变化情况，进行了超高分辨率的地层分析的初探。