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981.
The primary phases and minerals of the Plombières dumps include typical smelting furnace products such as metallic Fe, Pb, Cu, Zn, Fe-Zn alloys, carbides, phosphides, sulfides of Fe, Zn, Pb, Cu, Mn (alabandite), and FeAs. Spinels, mainly of Fe and Al, are common constituents of the primary assemblage; substitution by Zn, V, Cr, Ti, Mg, and Ca occurs. Primary phases also include the most common Zn-rich fayalite, Zn-rich Ca-Fe silicates, melilite, corundum, and apatite. Most of the Zn is incorporated in iron silicates, ZnO and ZnS. Lead occurs mainly as PbS, metallic lead, and is also present in coal residues. Cadmium is found mainly in metallic zinc and its alloys and in ZnO. The dumps also contain mining wastes composed of pyrite, melnikovite, and iron oxides produced by natural weathering of Zn-Pb ores. Melnikovite and iron oxides are rich in As, Pb, and Zn and possess an increased content of Tl. Leaching tests carried out on the surfaces of polished sections indicate that acid rain (solutions I and II) will mobilize mainly Zn and Cd and, to a much smaller extent, Pb and Sb. Leaching of metals by sulfate-chloride fluids present in the pore network of dumps (solutions III, IV, and V) depends on the pH, which in the dumps is controlled by the proportion of carbonates to sulfides. The more acid fluids leach both sulfides and silicates. 相似文献
982.
A. P. le Roex Frederick A. Frey Stephen H. Richardson 《Contributions to Mineralogy and Petrology》1996,124(2):167-184
Basaltic lavas from the AMAR Valley and the Narrowgate region of the FAMOUS Valley on the Mid-Atlantic Ridge (36° to 37°?N) range in texture from aphyric to highly plagioclase phyric (>25% large plagioclase phenocrysts). Based on 87Sr/86Sr and 143Nd/144Nd ratios, most of these lavas can be subdivided into two distinct, isotopically homogeneous, groups: Group I has lower 87Sr/86Sr (0.70288±1) and higher 143Nd/144Nd (0.51312±1) ratios; Group II has higher 87Sr/86Sr (0.70296±1) and lower 143Nd/144Nd (0.51309±2) ratios. Most Group II lavas are aphyric, whereas Group I lavas are primarily plagioclase phyric. Lavas from both groups show a wide range in incompatible element abundance ratios (e.g., Zr/Nb =6–29; (La/Sm)n=0.6–1.7). Aphyric lavas have relatively constant Sc (40±1.5?ppm) abundances and CaO/Al2O3 ratios (0.80±0.02). Group I lavas are confined primarily to the AMAR rift valley floor whereas Group II lavas are found along the east and west marginal highs. We interpret the isotopic differences between the two groups as reflecting a temporal change in the upwelling mantle beneath this region of the Mid-Atlantic Ridge which is south of the Azore Islands. For each group, a petrogenetic model consistent with the geochemical data is multi-stage decompression melting of an initially enriched, homogeneous, mantle source region. If the early derived, incompatible-element enriched, melt increments are not always pooled with subsequent increments, the erupted magma batches may have the major element characteristics of melts derived by 10 to 20% melting, but with incompatible element abundance ratios reflecting the change from an enriched to depleted source during the incremental melting process. In this process an initially homogeneous source can generate primary magmas with the required range in incompatible element abundance ratios shown by each group. The nearly constant CaO/Al2O3 ratios and Sc contents of the aphyric lavas with decreasing Mg?? reflects subsequent polybaric fractionation of clinopyroxene, plagioclase and olivine over the pressure interval 8–6?kbar (24–18?km), followed by rapid transport to the surface and eruption. There is no geochemical evidence for a crustal magma chamber beneath this section of the Mid-Atlantic Ridge. 相似文献
983.
Frédérick Delay Hélène Housset-Resche Gilles Porel Ghislain de Marsily 《Mathematical Geology》1996,28(1):45-71
A new method for solving the transport equation based on the management of a large numbe of particles in a discretized 2-D domain is presented. The method uses numerical variables to represent the number of particles in a given mesh and is more complex than the 1-D problem. The first part of the paper focuses on the specific management of particles in a 2-D problem. The method also would be valid for three dimensions as long as the medium can be modeled similar to a layered system. As the particles are no longer tracked individually, the algorithm is fast and does not depend on the number of particles present. The numerical tests show that the method is nearly numerical dispersion free and permits accurate calculations even for simulations of low-concentration transport. Because each mesh is considered as a closed system between two successive time steps, it is easy to add adsorption phenomenon without any problem of numerical stability. The model is tested under conditions that are extremely demanding for its operating mode and gives a good fit to analytical solutions. The conditions in which it can be used to best advantage are discussed. 相似文献
984.
Acid mine drainage (AMD) occurs when sulfide minerals are exposed to an oxidizing environment. Most of the methods for preventing
AMD are either short-term or high cost solutions. Coating with iron phosphate is a new technology for the abatement of AMD.
It involves treating the sulfide with a coating solution composed of H2O2, KH2PO4, and sodium acetate as a buffer agent. The H2O2 oxidizes the sulfide surface and produces Fe3+ so that iron phosphate precipitates as a coating on the sulfide surface. Experiments performed under laboratory conditions
prove that an iron phosphate coating can be established on pyrrhotite surfaces with optimal concentrations of the coating
solution in the range of: 0.2M/0.01M H2O2, 0.2M KH2PO4, and 0.2M sodium acetate NaAc, depending on the experimental scale. Iron phosphate coating may be a long-term solution to
the problem of AMD. The method would be easy to implement; the reagent cost, however, is not low enough, although it is lower
than the conventional treatment with lime.
Received: 30 March 1995 · Accepted: 6 September 1995 相似文献
985.
Asymmetric aggregates of fine-grained leucoxene and quartz are reported from siliceous L-S tectonites deformed by progressive simple shear. The leucoxene fish, morphologically similar to mica fish, consistently yield shear senses in agreement with other kinematic criteria. We interpret the leucoxene as a pre- or early syntectonic alteration product of detrital heavy-minerals in a siliciclastic protolith. The leucoxene fish behave as passive markers, and they record kinematics by modification of pre-existing aggregates rather than syndeformational mineral growth. For siliceous metasedimentary rocks otherwise lacking in micro-kinematic indicators, leucoxene fish may provide an alternative to quartz c-axis analysis. 相似文献
986.
987.
988.
The basic-ultrabasic Treknattan intrusion is an important example of a late intrusion in a solidified, evolved, layered complex and sheds light on possible mechanisms by which such associations may develop. The Treknattan intrusion, emplaced into the basic Fongen-Hyllingen intrusion shortly after the latter had solidified, consists mainly of massive or weakly layered peridotite (olivine ± Cr-spinel cumulate) and troctolite (plagioclase + olivine ± Cr-spinel cumulate). The mineral compositional range partially overlaps the most primitive end of the much larger variation-interval in the Fongen-Hyllingen intrusion. The margin of the Treknattan intrusion is sometimes outlined by massive feldspathic websterite which appears to have formed by reaction between magma and melts of gabbroic country rock. The parental magma appears to have been a relatively water-rich picritic basalt with a possible genetic relationship to the magma parental to the enveloping Fongen-Hyllingen intrusion, both displaying tholeiitic relationship between olivine and Ca-poor pyroxene, and having crystallized from relatively water-rich magmas with an early crystallization order of olivine ± Cr-spinel-plagioclase-Ca-rich pyroxene. The recognition of the Treknattan intrusion as a separate body suggests that the bulk composition of the Fongen-Hyllingen intrusion is dioritic rather than gabbroic as previously thought. 相似文献
989.
990.
Wolfgang H. Berger Memorie K. Yasuda Torsten Bickert Gerold Wefer 《International Journal of Earth Sciences》1996,85(3):466-495
We provide a reconstruction of atmospheric CO2 from deep-sea sediments, for the past 625000 years (Milankovitch chron). Our database consists of a Milankovitch template
of sea-level variation in combination with a unique data set for the deep-sea record for Ontong Java plateau in the western
equatorial Pacific. We redate the Vostok ice-core data of Barnola et al. (1987). To make the reconstructions we employ multiple
regression between deep-sea data, on one hand, and ice-core CO2 data in Antarctica, on the other. The patterns of correlation suggest that the main factors controlling atmospheric CO2 can be described as a combination of sea-level state and sea-level change. For best results squared values of state and change
are used. The square-of-sea-level rule agrees with the concept that shelf processes are important modulators of atmospheric
CO2 (e.g., budgets of shelf organic carbon and shelf carbonate, nitrate reduction). The square-of-change rule implies that, on
short timescales, any major disturbance of the system results in a temporary rise in atmospheric CO2. 相似文献