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51.
Lei Chen Jian-Wei Li R. O. Rye W. M. Benzel H. A. Lowers Ming-Zhong He 《Mineralogy and Petrology》2013,107(4):487-499
Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K2O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K0.29Na0.19Pb0.31Fe2.66Al0.22(SO4)1.65(PO4)0.31(AsO4)0.04(OH)7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO4 at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO4)2 and minor hematite. The decomposition products of NaFe(SO4)2 are hematite and Na2SO4. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site. 相似文献
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We reported recently some rapid changes of sunspot structure in white-light(WL) associated with major flares.We extend the study to smaller events and present here results of a statistical study of this phenomenon.In total,we investigate 403 events from 1998 May 9 to 2004 July 17,including 40 X-class,174 M-class,and 189 C-class flares.By monitoring the structure of the flaring active regions using the WL observations from the Transition Region and Coronal Explorer(TRACE),we find that segments in the outer sunspot structure decayed rapidly right after many flares;and that,on the other hand,the central part of sunspots near the flare-associated magnetic neutral line became darkened.These rapid and permanent changes are evidenced in the time profiles of WL mean intensity and are not likely resulted from the flare emissions.Our study further shows that the outer sunspot structure decay as well as the central structure darkening are more likely to be detected in larger solar flares.For X-class flares,over 40% events show distinct sunspot structure change.For M-and C-class flares,this percentage drops to 17% and 10%,respectively.The results of this statistical study support our previously proposed reconnection picture,i.e.,the flare-related magnetic fields evolve from a highly inclined to a more vertical configuration. 相似文献
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A reasonable warmer winter index (IWWI) in the framework of the three equiprobability categories (i.e. warmer, normal and colder categories) is proposed based on the winter temperature data observed at 565 stations in China during 1956-2005, where IWWI is defined as the ratio of the station number of warmer category over the total number of stations. The results suggest that the trend of IWWI was consistent with that of the winter temperature on decadal time scale, and their rates of change were 10%/10 a and 0.4 ℃/10 a, respectively. It is found that only 13 warmer winter events in total were detected by IWWI over the past 50 years, and 85% of them occurred after 1986. 相似文献
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对2013年河北省中南部的石家庄、保定、沧州、衡水、邢台和邯郸6个地市市区各站点逐小时PM10和PM2.5监测资料及相应气象资料分析结果表明:6个地市中邢台年污染日数最多,对应其年平均风速最小;沧州的最少,年平均风速最大。各地市各个级别污染日数不同,五、六级重污染天气均集中在10月—次年3月。首要污染物主要是PM10和PM2.5,但比例不尽相同。特殊的地理位置、污染源差异和气象条件的差异造成各地市污染日数、级别的差异。6个地市污染天气过程时段大都相同,区域性污染明显。各地市PM10和PM2.5浓度平均最大值均出现在冬季,PM10浓度平均最小值均出现在夏季,各市PM2.5浓度平均最小值出现的季节不同。6个地市PM10和PM2.5浓度值的月变化趋势相似。不同季节各地市PM10和PM2.5浓度日变化趋势不同,极值出现的时间也各不相同,极值出现的时间与气象条件和人类活动关系密切。秋、冬季各地市PM10和PM2.5浓度日较差多大于春、夏季的。各地市PM10和PM2.5浓度日均值与当地的日均气温、风速、能见度呈负相关关系,与相对湿度呈正相关关系且相关性比较显著。 相似文献
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挤土效应是所有挤土类桩面临的共同问题,它可能造成临近建筑物破坏,地下管线断裂,道路隆起以及工程质量事故。依据挤土类桩挤土效应的形成机理,结合工程实例,提出了减少挤土效应的措施,如预钻排水孔、开挖防挤沟、设置观测点、控制压桩速度等措施,并根据施工地区不同的环境条件提出了合理的压桩顺序。 相似文献
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