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Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for 207Pb/206Pb and 208Pb/206Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for 207Pb/206Pb (208Pb/206Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for 207Pb/206Pb and 208Pb/206Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores. 相似文献
43.
运用光谱分析和GC-MS方法首次从卡氏豆荚软珊瑚Lobophytumcatelai中分离和鉴定出8个化合物:l,十六碳酸;2,异丁基十六碳酸酯;3,鲨肝醇;4十六酸丙酯;5,2,3一二羟基丙基十八酸酯;6,2β,3β-环氧基-5α-雄甾烷-17-醇;7,14-甲基-5α-胆甾-8-稀-3-酮;8,2α,3α一环氧基-5α-雄甾烷-17-醇。 相似文献
44.
叶立勋 《中国海洋大学学报(自然科学版)》1990,(3)
介绍三种通过底栖动物群落结构的变化对有机物污染监测和评价的方法,并分别对澳大利亚塔斯马尼亚州Nubeena鳟鱼养殖场内由高密度网箱养鱼诱发的有机物污染进行了检测。结果表明:距网箱垂线0m处为严重污染区域,10m处为中度污染区域,30m为过渡类型,其有机物对该处底栖生物仍具有害影响,60m处为轻度有机物富集区,但该处有机物对底栖生物的总效应是有益的,60m以外为正常区域。本文还对三种方法的适用性进行了讨论。 相似文献
45.
矿集区预测中的探索式空间分析方法及应用——以中亚铜矿集区预测为例 总被引:1,自引:0,他引:1
随着地理信息科学和计算机技术的发展,计算环境下矿集区预测方法的研究热潮也初现端倪.依据矿集区所包含的理论内涵(矿床密集区、潜力密集区的聚集内涵),提出了应用探索式空间分析法进行矿集区预测的设想,并以北至科克舍套,南至帕米尔高原,西至乌拉尔山,东至新疆边境的中亚区域为研究区,利用探索式空间分析方法从含矿潜力的确定及其空间分布模式的探索入手,对研究区铜矿集区进行了预测,初步圈定了乌拉尔、矿区阿尔泰、北滨巴尔喀什、斋桑、塔尔巴合台等17处铜矿集区.研究成果除包含了研究区已知矿集区外,还有7处新区,反映了探索式空间分析法在矿集区预测中的应用潜力. 相似文献
46.
Geochronological studies on the crust-derived Tianmenshan pluton were undertaken by SHRIMP zircon U-Pb dating and Ar-Ar dating of biotite, muscovite and K-feldspar, giving a petrogenetic age of 167 Ma. Owing to the closure systems in different minerals, the cooling history of the pluton can be determined with an age-temperature diagram. The late hydrothermal event has been recognized, which is related probably with mineralization. In terms of the comparative geochronological and petrologic records, it is concluded that there are some constrains on tectonic evolution and that the formation of the Tianmenshan pluton proceeded in a transition period from Indosinian post-orogeny extension to strong compressive tectonics. And the timing of the hydrothermal event matches the compressive climax of the Yanshanian orogeny. The temporal gap between granite emplacement and wolframite mineralization could last 10-20 Ma owing to the low cooling rate of the pluton. 相似文献
47.
Formation Dynamics and Quantitative Prediction of Hydrocarbons of the Superpressure System in the Dongying Sag 总被引:1,自引:0,他引:1
Based on the theory of formation dynamics of oil/gas pools, the Dongying sag can be divided into three dynamic systems regarding the accumulation of oil and gas: the superpressure closed system, the semi-closed system and the normal pressure open system. Based on the analysis of genesis of superpressure in the superpressure closed system and the rule of hydrocarbon expulsion, it is found that hydrocarbon generation is related to superpressure, which is the main driving factor of hydrocarbon migration. Micro fractures formed by superpressure are the main channels for hydrocarbon migration. There are three dynamic patterns for hydrocarbon expulsion: free water drainage, hydrocarbon accumulation and drainage through micro fissures. In the superpressure closed system, the oil-driving-water process and oil/gas accumulation were completed in lithologic traps by way of such two dynamic patterns as episodic evolution of superpressure systems and episodic pressure release of faults. The oil-bearing capacity of lithologic traps is intimately related to reservoir-forming dynamic force. Quantitative evaluation of dynamic conditions for pool formation can effectively predict the oil-bearing capability of traps. 相似文献
48.
安徽池州铜山铜矿深部找矿实践与启示 总被引:4,自引:0,他引:4
铜山铜矿资源储量日益枯竭。危机矿山接替资源勘查中,采用地质、物探综合手段圈定异常区,经深部钻探验证,取得突破。 相似文献
49.
50.
基于GPS测量数据的GIS数据库更新算法研究 总被引:2,自引:0,他引:2
为了解决土地利用GIS数据库更新中多源数据存在不一致的问题,使土地利用GIS数据库的更新更高效、科学、合理并且美观,从地理信息系统空间数据的更新方式和土地利用数据更新的实际需求出发,以GPS测量数据为更新源,建立GPS测量数据的误差模型,借助地图匹配的算法思想,提出一种GPS/GIS数据融合匹配的方法,在GPS点误差范围内建立误差缓冲区,按照距离最近、走向最接近的原则,把GPS点与GIS数据进行融合匹配,参与GIS数据的拓扑重构,达到GIS数据库的局部区域的快速更新。实验结果证明,本算法能使GPS点匹配简便快捷,提升更新效率。 相似文献