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791.
Wei Dang Jin-Chuan Zhang Xuan Tang Xiao-Liang Wei Zhong-Ming Li Cheng-Hu Wang Qian Chen Chong Liu 《地学前缘(英文版)》2018,9(2):559-575
Measuring gas content is an essential step in estimating the commerciality of gas reserves. In this study,eight shale core samples from the Mouye-1 well were measured using a homemade patented gas desorption apparatus to determine their gas contents. Due to the air contamination that is introduced into the desorption canister, a mathematical method was devised to correct the gas quantity and quality.Compared to the chemical compositions of desorbed gas, the chemical compositions of residual gas are somewhat different. In residual gas, carbon dioxide and nitrogen record a slight increase, and propane is first observed. This phenomenon may be related to the exposure time during the transportation of shale samples from the drilling site to the laboratory, as well as the differences in the mass, size and adsorptivity of different gas molecules. In addition to a series of conventional methods, including the USBM direct method and the Amoco Curve Fit(ACF) method, which were used here for lost gas content estimation, a Modified Curve Fit(MCF) method, based on the 'bidisperse' diffusion model, was established to estimate lost gas content. By fitting the ACF and MCF models to gas desorption data, we determined that the MCF method could reasonably describe the gas desorption data over the entire time period, whereas the ACF method failed. The failure of the ACF method to describe the gas desorption process may be related to its restrictive assumption of a single pore size within shale samples. In comparison to the indirect method, this study demonstrates that none of the three methods studied in this investigation(USBM, ACF and MCF) could individually estimate the lost gas contents of all shale samples and that the proportion of free gas relative to total gas has a significant effect on the estimation accuracy of the selected method. When the ratio of free gas to total gas is lower than 45%, the USBM method is the best for estimating the lost gas content, whereas when the ratio ranges from 45% to 75% or is more than 75%, the ACF and MCF methods, are the best options respectively. 相似文献
792.
Tao Chen Christoph Clauser Gabriele Marquart Karen Willbrand Thomas Hiller 《Hydrogeology Journal》2018,26(6):1903-1916
Upscaling permeability of grid blocks is crucial for groundwater models. A novel upscaling method for three-dimensional fractured porous rocks is presented. The objective of the study was to compare this method with the commonly used Oda upscaling method and the volume averaging method. First, the multiple boundary method and its computational framework were defined for three-dimensional stochastic fracture networks. Then, the different upscaling methods were compared for a set of rotated fractures, for tortuous fractures, and for two discrete fracture networks. The results computed by the multiple boundary method are comparable with those of the other two methods and fit best the analytical solution for a set of rotated fractures. The errors in flow rate of the equivalent fracture model decrease when using the multiple boundary method. Furthermore, the errors of the equivalent fracture models increase from well-connected fracture networks to poorly connected ones. Finally, the diagonal components of the equivalent permeability tensors tend to follow a normal or log-normal distribution for the well-connected fracture network model with infinite fracture size. By contrast, they exhibit a power-law distribution for the poorly connected fracture network with multiple scale fractures. The study demonstrates the accuracy and the flexibility of the multiple boundary upscaling concept. This makes it attractive for being incorporated into any existing flow-based upscaling procedures, which helps in reducing the uncertainty of groundwater models. 相似文献
793.
Wave–current interaction (WCI) is important in modulating hydrodynamics and water mixing in estuaries, and thereby the transport of water-borne materials. However, the effects of WCI on salt transport and salt intrusion in estuaries during storm events have been rarely examined. In the present study, we use a coupled atmosphere–ocean–wave–sediment transport (COAWST) modeling system to investigate the effects of WCI on salt intrusion in the highly stratified Modaomen Estuary during Typhoon Hagupit (2008). The model is validated by the measured wave, water elevation, and surface salinity data, and several diagnostic model experiments are conducted. WCI increases the storm surge by 0.8 m at the peak surge (25% of the total surge height). The wave-breaking-induced momentum flux and the Stokes drift increase the magnitude of the landward flow by 0.3 m s?1 (30% of the total landward flow). In addition, the waves increase water mixing by 2–4 times compared with that without waves. Hence, WCI significantly increases the landward advective salt transport and decreases the steady shear transport. The net effect of the WCI is a significant increase of salt import and salt intrusion during the typhoon event. However, in the aftermath of the storm, the imported salt water is rapidly flushed out by the increased river discharge, and the estuary regains its stratification within one day. 相似文献
794.
The mean velocity of debris flow is one of the most important parameters in the design of mitigation structures and in quantitative risk analysis. This study develops a model to predict the mean debris flow velocity observed in the field by applying the incomplete similarity argument. An equation for estimating the Darcy-Weisbach resistance coefficient for debris flows with a volumetric sediment concentration larger than 0.19 is accordingly derived using 128 sets of observation data from nine Chinese gullies, in which both the effect of the volumetric sediment concentration and channel slope on resistance are considered. The derived equation is then verified and compared against five previously published equations by using 61 sets of published observation data from six gullies located in four countries. The applications of the proposed equation are discussed, and the improvements made using the proposed equation are clearly very significant when compared with the previously published equations. 相似文献
795.
C.-S. Chiou H.-W. Chen Z.-T. Chen 《International Journal of Environmental Science and Technology》2018,15(9):1879-1886
The extensive use of Rhodamine B (RhB) for textile, paper, pigment, food, cosmetic, and drug manufacturing and its indiscriminate disposal leads to serious human, biological, and environmental hazards. A magnetic adsorbent with silicate and phenyl polymers (Ph/SiO2/Fe3O4) has been prepared to absorb RhB. The morphology and structure of the adsorbents have been characterized by TGA, XRD, FTIR, and adsorption–desorption measurement. The results revealed that Ph/SiO2/Fe3O4 exhibited a paramagnetic behavior and could easily and quickly be separated from a suspension. The RhB adsorption behavior was almost pH independent due to the adsorption between the phenyl ring of Ph/SiO2/Fe3O4 and RhB by π–π electron-donor–acceptor interactions. The adsorption behavior of RhB adsorption was in good agreement with the Langmuir adsorption isotherm, and the maximum adsorption capacity was 142.186 mg g?1. Good desorption performance of Ph/SiO2/Fe3O4 showed that this novel magnetic adsorbent cannot only be activated by ethanol extraction process but also reuse by the recovery of magnetic force. 相似文献
796.
Lulu Zhang Fang Wu Yafei Zheng Lihong Chen Jie Zhang Xu Li 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2018,12(3):169-182
Multiple types of responses, such as displacements, ground water level, pore water pressures, water contents, etc., are usually measured in comprehensive monitoring programmes for rainfall-induced landslide prevention. In this study, a probabilistic calibration method for coupled hydro-mechanical modelling of slope stability is presented with integration of multiple types of measurements. A numerical example of a soil slope under rainfall infiltration is illustrated to compare the effects of single and multiple types of responses on parameter estimation and model calibration. The results show that the soil parameters can be estimated with less uncertainty and total uncertainty bounds are narrower with multiple types of responses than with a single type of response. Model calibration based on multiple types of responses can compromise different responses and hence the means and standard deviations of model error are the smallest. A feasible correlation coefficient between soil modulus and permeability can be obtained from model calibration with multiple types of responses and single type of response as long as the responses include displacement data. 相似文献
797.
Gang Deng Kui Cao Rui Chen Xingxing Zhang Qi Yin Hao Zhou 《Environmental Earth Sciences》2018,77(1):25
Internal erosion is the most common reason which induces failure of embankment dams besides overtopping. Relatively large leakage is frequently concentrated at defects of impervious element, and this will lead to eventual failure. The amount of leakage depends not only on integrity of impervious element, but also on dam height, shape of valley, shape of impervious element and water level in reservoir. The integrity of impervious element, which represents the relative level of seepage safety, is not easy to be determined quantitatively. A simple method for generalization of steady seepage state of embankment dams with thin impervious element is proposed in this paper. The apparent overall value of permeability coefficient for impervious element can be obtained by this method with reasonable accuracy and efficiency. A defect parameter of impervious element is defined as an index to characterize seepage safety of embankment dams. It equals the ratio of the apparent overall value of permeability coefficient to the measured value in laboratory for intact materials. Subsequently, seepage safety of three dams is evaluated and the evolution of defect level of impervious element of dams is investigated. It is proved that the newly proposed method in this paper is feasible in the evaluation of relative seepage safety level of embankment dams with thin impervious element. 相似文献
798.
Zizhan Hu Xuguang Tang Chen Zheng Menglin Guan Jingwei Shen 《Environmental Earth Sciences》2018,77(14):540
Due to its negative impact on the living environment of human beings, ambient air pollution has become a global challenge to human health. In this study, surface observations of six criteria air pollutants, including PM2.5, PM10, SO2, NO2, CO and O3, were collected to investigate the spatial and temporal variation in the Beijing–Tianjin–Hebei (BTH) region during 2013–2016 and to explore the relationships between atmospheric pollutants and meteorological variables using quantile regression model (QRM) and multiple linear regression model (MLRM). The results show that BTH region has experienced significant air pollution, and the southern part generally has more severe conditions. The annual average indicates clear decreasing trends of the particulate matters, SO2 and CO concentrations over the last 4 years and slight increasing trends of NO2 and O3 in several cities. The seasonal and monthly characteristics indicate that the concentrations of five species reach their maxima in the winter and their minima in the summer, whereas O3 has the opposite behaviour. Finally, the pseudo R2 values show that the QRMs have the best performance in the winter, followed by spring, fall, and summer. Specifically, all the meteorological factors have significant impacts on air pollution but change with pollutants and seasons. The MLRM results are generally consistent with the QRM results in all seasons, and the inconsistencies are more common in the fall and winter. The results of this research provide foundational knowledge for predicting the response of air quality to climate change in the BTH region. 相似文献
799.
In this study, the time-dependent damage process of granite is investigated utilizing two numerical simulation schemes based on continuous method and discontinuous method. Numerical creep tests are carried out with both simulation schemes and mechanical responses and fracture patterns of rock specimens are analyzed. The calibrated numerical models can successfully reflect the typical creep stages observed in the laboratory. The predicted lifetime is in accordance with the laboratory test data. Comparisons are made between the two simulation schemes. It is found that both schemes have unique features that can promote a genuine reflection of the time-dependent damage process of the brittle rocks. 相似文献
800.
Juanle Wang Eryang Chen Ge Li Lu Zhang Xiaoming Cao Yongjie Zhang Yujie Wang 《Environmental Earth Sciences》2018,77(16):590
Concentrations of suspended solids in lakes can affect the latter’s primary productivity and reflect changes in sediment deposition. Determining the temporal and spatial distribution of suspended solid concentrations has important significance in lake water environmental management; this is particularly urgent for Poyang Lake, the largest freshwater lake in China. In this study, suspended solid concentration inversion models for Poyang Lake were created using a semi-empirical method with regression analysis between continuously measured suspended solid concentration data and multi-band moderate-resolution imaging spectroradiometer images for spring, summer, autumn, and winter from 2009 to 2012. The coefficient of determination (R2) is from 0.6 to 0.9 and the average relative error for the accuracy verification was between 10 and 30%. The seasonal distributions of suspended solid concentrations in Poyang Lake from 2000 to 2013 were then obtained using optimal reversal models. The results showed that the seasonal variation in suspended solid concentrations had a “W” shape in which high spring and autumn and low summer and winter values. The suspended solid concentrations increased annually from 2000 to 2013 and were mainly distributed in the northern and central portions of the lake, with lower values along the shorelines. Further analysis indicated that the large difference in water level between the wet and dry seasons is an important factor in explaining these seasonal variations. Moreover, the suspended solid concentrations were poorly correlated with water temperature and chlorophyll-a concentration but more highly correlated with the deferred chlorophyll-a concentration. 相似文献