Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.     

Zircon U–Pb and Hf isotopic study of gneissic rocks from the Chinese Altai: Progressive accretionary history in the early to middle Palaeozoic

Gneissic rocks in the Chinese Altai Mountains have been interpreted as either Paleozoic metasedimentary rocks or Precambrian basement. This study reports geochemical and geochronological data for banded paragneisses and associated gneissic granitoids collected along a NE–SW traverse in the northwestern Chinese Altai. Petrological and geochemical data suggest that the protoliths of the banded gneisses were possibly immature sediments with significant volcanic input and that the gneissic granitoids were derived from I-type granites formed in a subduction environment. Three types of morphological features can be recognized in zircons from the banded gneisses and are interpreted to correlate with different sources. Zircons from five samples of banded paragneiss cluster predominantly between 466 and 528 Ma, some give Neoproterozoic ages, and a few yield discordant Paleoproterozoic to Archean ages. Zircon Hf isotopic compositions indicate that both juvenile/mantle and crust materials were involved in the generation of the source rocks from which these zircons were derived. In contrast, zircons occur ubiquitously as elongated euhedral prismatic crystals in the four samples of the gneissic granitoids, and define single populations for each sample with mean ages between 380 and 453 Ma. The general absence of Precambrian inheritance and positive zircon ?Hf values for these granitoids suggest insignificant crustal contribution to the generation of the precursor magmas. Our data can be interpreted in terms of a progressive accretionary history in early to middle Palaeozoic times, and the Chinese Altai may possibly represent a magmatic arc built on a continental margin dominated by Neoproterozoic rocks.     

Atmospheric mercury near Salmon Falls Creek Reservoir in southern Idaho

Gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) were measured over 2-week seasonal field campaigns near Salmon Falls Creek Reservoir in south-central Idaho from the summer of 2005 through the fall of 2006 and over the entire summer of 2006 using automated Tekran Hg analyzers. GEM, RGM, and particulate Hg (HgP) were also measured at a secondary site 90 km to the west in southwestern Idaho during the summer of 2006. The study was performed to characterize Hg air concentrations in the southern Idaho area for the first time, estimate Hg dry deposition rates, and investigate the source of observed elevated concentrations. High seasonal variability was observed with the highest GEM (1.91 ± 0.9 ng m⁻³) and RGM (8.1 ± 5.6 pg m⁻³) concentrations occurring in the summer and lower values in the winter (1.32 ± 0.3 ng m⁻³, 3.2 ± 2.9 pg m⁻³ for GEM, RGM, respectively). The summer-average HgP concentrations were generally below detection limit (0.6 ± 1 pg m⁻³). Seasonally averaged deposition velocities calculated using a resistance model were 0.034 ± 0.032, 0.043 ± 0.040, 0.00084 ± 0.0017 and 0.00036 ± 0.0011 cm s⁻¹ for GEM (spring, summer, fall and winter, respectively) and 0.50 ± 0.39, 0.40 ± 0.31, 0.51 ± 0.43 and 0.76 ± 0.57 cm s⁻¹ for RGM. The total annual RGM + GEM dry deposition estimate was calculated to be 11.9 ± 3.3 μg m⁻², or about 2/3 of the total (wet + dry) deposition estimate for the area. Periodic elevated short-term GEM (2.2–12 ng m⁻³) and RGM (50–150 pg m⁻³) events were observed primarily during the warm seasons. Back-trajectory modeling and PSCF analysis indicate predominant source directions to the SE (western Utah, northeastern Nevada) and SW (north-central Nevada) with fewer inputs from the NW (southeastern Oregon and southwestern Idaho).     

新疆北部库尔提蛇绿岩中角闪片岩的原岩恢复及其成因

库尔提角闪片岩产于库尔提蛇绿岩南部岩片中,与斜长花岗岩呈互层产出。这套角闪片岩的不相容微量元素组分显示了大洋中脊和岛弧玄武岩的双重特征,主要表现为大离子亲石元素(LILE)富集,高场强元素(HFSE)亏损以及平坦到亏损的轻稀土(LREE)配分模式。原岩恢复的结果表明,该角闪片岩的原岩为亚碱性的拉斑玄武岩类。库尔提角闪片岩亏损的LREE、高ε_(Nd)(t),以及关键元素比值(Th/Nb,La/Yb和Th/Yb)呈正相关都表明,其源区可能以MORB地幔为主,同时还伴有少量弧组分。因此,我们认为其形成于弧后盆地环境,同时推断该区弧后盆地存在一个二阶段的熔融演化模式:第一阶段,大约在晚古生代早期,古亚洲洋向西伯利亚板块发生北向俯冲,在会聚板块边界,弧火山岩被从含水的地幔楔中提取出来,留下一个亏损地幔;第二阶段,随着古亚洲洋板块持续消减,在中-晚泥盆世形成了库尔提弧后盆地,下部的亏损地幔发生了小比例的部分熔融形成了这套角闪片岩的原岩。     

中祁连东段什川杂岩基的岩石化学特征及年代学研究

祁连造山带被托菜南山-了高山构造带及宗务隆山-贵得构造带分为北祁连、中祁连及南祁连构造带。什川岩基位于中祁连构造带东部,由闪长岩、斜长花岗岩、二长花岗岩组成;对二长花岗岩进行U-Pb单颗粒锆石微区LA-ICP-MS同位素测定,获得444.6Ma及414.3Ma两组加权平均年龄,前者代表岩石的形成年龄,后者代表构造热事件年龄。二长花岗岩主量元素W(SiO_2)=68.66%～80.77%,w(K_2O)/w(Na_2O)>1和A/CNK介于0.95～1.21间,总体为钾质钙碱性过铝质花岗岩。岩石富集LILE元素(K、Th、Rb、Ba等),亏损HFSE元素(Ta、Nb、Y等);稀土元素总量较高(∑REE多介于109.05×10~(-6)～322.66×10~(-6)),轻重稀土强烈分馏(∑LREE/∑HREE介于7.92～31.68),稀土元素分配模式为轻稀土富集型,具中等-强Eu负异常(δEu=0.26～0.58)。岩石矿物组合及岩石地球化学特征共同表明,什川岩基为中上地壳泥砂质岩石部分熔融而成,形成温度较低,为加厚地壳拆沉熔融成因。这为祁连造山带构造演化及其深部动力学机制研究提供了新的资料。     

基于呼叫中心的防伪识别系统的设计与实现

呼叫中心系统是综合利用先进的通信及计算机技术,对信息和物资流程优化处理和管理,集中实现沟通、服务和生产指挥的系统.介绍了呼叫中心系统的历史、发展过程、意义等,阐明了论文的研究背景和主要的研究工作.论述了呼叫中心的基本原理,以及本系统总体方案的确定和相关技术,并详细阐述了系统的具体实现方法.本系统结合实际需求,采用板卡实现方案,有效地提高了系统的性能价格比,解决了呼叫中心在电话防伪识别系统中所涉及的相关问题.通过实践运行该电话防伪识别系统,证实了该系统的实用性和有效性.     

天津地面沉降区土水比论述

天津市地面沉降分布广,沉降速率大。本文针对当前地面沉降研究和防治过程中所遇到的勘查资料严重缺乏、禁采难以全面实现等难题,提出了土水比指标量。通过概念分析和对多年数据的分析,认为土水比可以检验地下水开采量数据的统计精度,指示地下水资源补给及土层释水条件,并表明沉降的严重程度,反映地下水资源的保障程度。建议在沉降防治工作中,以土水比作为指标,通过相关分析模型来制定压采量。     

浙江省长兴县煤山剖面二叠—三叠系过渡地层中的黑碳记录及其地质意义

首次报道了浙江煤山二叠-三叠系界线地层中黑碳的含量及其碳同住素的变化特征。黑碳含量在26层存在一个明显的峰值,含量高达0．51％。黑碳与总有机碳比值从25层底部开始持续升高,在26层达到最高,稳定在0．40以上。黑碳的碳同位素在24层和25层之间有一个陡然的降低,降低幅度达2‰,在25和26层中则存在一个幅度达3‰的缓慢降低,总降低幅度达5‰。黑碳是动植物和化石燃料燃烧的天然记录,浙江煤山二叠-三叠系界线附近黑碳特征反映了二叠纪末期陆地生态系统发生了突然的衰退,发生了强烈的天然大火。根据事件层大火燃烧的长期性或频繁的特征,以及黑碳同位素大幅度陡然降低和缓慢降低,认为燃烧源除了陆地植被外,还有其他富含轻碳的化石燃料,即大火的燃烧源除了植被外,还可能有煤和甲烷水合物等。浙江煤山剖面的黑碳记录,反映了二叠-三叠纪之交地球陆地环境的剧烈变化,有助于理解和揭示生物大灭绝的过程和原因。     

小波分析在天然伽玛测井地质解释中的应用

在分析天然伽玛测井数据的信息特点和小波多分辨率分析原理的基础上,用小波多分辨率分析天然伽玛测井数据,消除其中的统计涨落等噪声干扰及提取天然伽玛放射性强度在不同沉积岩地层中分界标志特征和不同岩性中的变化特征,以提高应用天然伽玛测井资料进行地层划分及岩性识别的准确性和有效性.     

贵州修文小山坝铝土矿中镓等伴生元素分布规律研究

通过ICP-MS等分析方法对贵州小山坝铝土矿中伴生元素的研究,发现该矿床TiO2、Ga、Ge、Sc、Nb、Li和REE等有用伴生元素在铝土矿矿体中均有较高富集,其含量大多接近或超过了工业综合利用标准,具有较大的经济价值,特别是矿区富铁铝土矿石中Ga和Sc等含量异常高.贵州铝土矿资源丰富,其伴生元素在铝土矿冶炼过程中所产生的赤泥中更为富集,因此,贵州铝土矿综合利用前景十分巨大,这些元素潜在的经济价值,在某种程度上,甚至会超过主导产品氧化铝的价值.开展铝土矿中镓等伴生有用元素的分布及赋存状态的研究,对于镓等稀散元素在特殊地质地球化学环境中超常富集机制、矿产资源综合价值的重新认识评估和矿产资源的综合利用将十分重要,不仅可为铝工业注入新的活力,增加新的经济增长点,而且还可以解决大量赤泥堆放和利用问题,同时获得较大的社会效益与环境效益.