Elpasolite from hyperalkaline pegmatite of the Khibiny pluton, Kola Peninsula. Symmetry of elpasolite

Elpasolite, K₂NaAlF₆, has been found for the first time in a pegmatite related to peralkaline foid syenite at Mt. Koashva, Khibiny alkaline pluton, Kola Peninsula, Russia, as pale pink octahedral crystals up to 2 mm in size within cavities in the natrolite core of pegmatite in association with amicite, sodalite, aegirine, pectolite, catapleiite, sitinakite, lemmleinite-K, and vinogradovite. The chemical composition determined with an electron microprobe is as follows, wt %: 31.53 K; 9.22 Na; 11.20 Al; 47.21 F; total is 99.16. The empirical formula is K_1.96Na_0.98Al_1.01F_6.05. The infrared spectrum is given. The crystal structure has been refined to R = 0.030, space group Fm $ \bar 3 Elpasolite, K₂NaAlF₆, has been found for the first time in a pegmatite related to peralkaline foid syenite at Mt. Koashva, Khibiny alkaline pluton, Kola Peninsula, Russia, as pale pink octahedral crystals up to 2 mm in size within cavities in the natrolite core of pegmatite in association with amicite, sodalite, aegirine, pectolite, catapleiite, sitinakite, lemmleinite-K, and vinogradovite. The chemical composition determined with an electron microprobe is as follows, wt %: 31.53 K; 9.22 Na; 11.20 Al; 47.21 F; total is 99.16. The empirical formula is K_1.96Na_0.98Al_1.01F_6.05. The infrared spectrum is given. The crystal structure has been refined to R = 0.030, space group Fm m, a = 8.092 ?. The result of a special X-ray powder diffraction study confirmed the suggestion made by Morss (1974) that reflections violating space group Fm m in some published X-ray powder patterns of natural elpasolite are Kβ-lines. Original Russian Text ? I.V. Pekov, N.V. Chukanov, N.N. Kononkova, N.V. Zubkova, M.Kh. Rabadanov, D.Yu. Pushcharovsky, 2007, published in Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 2007, No. 6, pp. 76–84.     

Climatic changes and alluvial-sedimentation settings in southeastern Transbaikalia in the Middle-Late Holocene (by the example of the Ilya floodplain)

Climatic changes in southeastern Transbaikalia in the Middle and Late Holocene and their influence on alluvial sedimentation environments are reconstructed from the results of study of the Ilya floodplain sediments (Alkhanai National Park). At the beginning of the Subboreal period, the regional climate became more arid, which led to a significant increase in steppe species communities in the landscapes. Intense climate aridization also took place at the beginning and at the end of the Subatlantic period of the Holocene. The alluvial-sedimentation rate increased during the weakening of aridization and decreased during cooling and the intensification of aridization. The obtained regional data are compared with data on the adjacent areas and the global climatic changes in the Northern Hemisphere.     

Intrayear irregularities of the Earth’s rotation

The methods of celestial mechanics can be used to construct a mathematical model for the perturbed rotational motions of the deformable Earth that can adequately describe the astrometric measurements of the International Earth Rotation Service (IERS). This model describes the gravitational and tidal influences of the Sun and Moon. Fine resonant interactions of long-period zonal tides (annual, semiannual, monthly, and biweekly) with the diurnal and semidiurnal tides are revealed. These interactions can be reliably confirmed via a spectral analysis of the IERS data. Numerical modeling of tidal irregularities of the Earth’s axial rotation was carried out, focusing on the analysis and forecasting of variations of the day length occurring within short time intervals of a year or shorter (intrayear variations).     

天然气溶解过程中组分分馏模型及其应用

天然气不同组分在水中溶解度的差异,导致溶解相与残留游离相天然气组分组成不同,即发生组分的溶解分馏效应。溶解分馏效应在天然气水溶运移、溶解散失等过程中均有发生。揭示天然气组分的溶解分馏规律、建立定量分馏模型,有助于天然气气源对比和成藏过程示踪。以Henry定律为依据,对不同组分溶解特征分析,提出了溶解度分数的概念,并建立了溶解分馏模型。根据该模型和各组分的溶解度分数和天然气溶解量,可计算各组分的溶解分馏量,恢复天然气初始组成特征。计算表明,威远震旦系气藏初期的天然气组成为:CH4为72.70%,C2H6为0.09%,CO2为22.41%,N2为4.07%,干燥系数(C1/C1-5)为99.876%。溶解作用使天然气中CO2含量显著降低,烃类气体含量增加,而天然气干燥系数降低。结果有助于天然气成因判识和气源对比等。     

GIS在四川城市环境地质调查评价中的应用

将GIS应用于四川城市环境地质调查评价,建立一套完整的标准,指导全省21城市的数据库建设工作。在数据库的基础上利用MAPGIS二次开发平台,集成四川城市环境地质问题调查评价信息系统,供地方政府和各级管理机构使用。     

地铁隧道结构变形监测信息管理系统的开发

地铁隧道结构变形监测的特殊性、周期性和长期性,使其信息量非常庞大.信息管理是地铁隧道结构变形监测中一项重要的工作,现有的管理方式效率很低.为了高效、准确地管理监测信息,及时分析预报地铁隧道结构的稳定状况,本文结合南京地铁运营期隧道结构变形监测实例,开发了一套具有变形监测资料存储、预处理、管理分析、可视化分析、预测预报及限值预警等功能的信息管理系统,保证了准确及时快速的数据处理和信息反馈,具有良好的运用和推广前景.     

Estimation of hydraulic permeability considering the micro morphology of rocks of the borehole YAXCOPOIL-1 (Impact crater Chicxulub,Mexico)

Internal surface, formation factor, Nuclear Magnetic Resonance (NMR)-T2 relaxation times and pore radius distributions were measured on representative core samples for the estimation of hydraulic permeability. Permeability is estimated using various versions of the classic Kozeny–Carman-equation (K–C) and a further development of K–C, the fractal PaRiS-model, taking into account the internal surface. In addition to grain and pore size distribution, directly connected to permeability, internal surface reflects the internal structure (“micro morphology”). Lithologies could be grouped with respect to differences in internal surface. Most melt rich impact breccia lithologies exhibit large internal surfaces, while Tertiary post-impact sediments and Cretaceous lithologies in displaced megablocks display smaller internal surfaces. Investigations with scanning electron microscopy confirm the correlation between internal surface and micro morphology. In addition to different versions of K–C, estimations by means of NMR, pore radius distributions and some gas permeability measurements serve for cross-checking and calibration. In general, the different estimations from the independent methods and the measurements are in satisfactory accordance. For Tertiary limestones and Suevites bulk with very high porosities (up to 35%) permeabilites between 10⁻¹⁴ and 10⁻¹⁶ m² are found, whereas in lower Suevite, Cretaceous anhydrites and dolomites, bulk permeabilites are between 10⁻¹⁵ and 10⁻²³ m².     

应用探地雷达探测活动断层

在浅覆盖区采用探地雷达探测地震活动断层。通过实验确定出最佳的采集参数和数据处理流程,在雷达剖面上,能够清晰地显示出断层上部的形态特征、上断点埋深和岩土分层。结合钻孔资料,利用雷达剖面上对第四系覆盖的分层结果和上断点所在的层位可以分析和评价断层的活动性。     

鄂尔多斯盆地黄陵、东胜地区地温场对比

鄂尔多斯盆地黄陵、东胜铀矿区分别处于盆地南部渭北隆起的北侧边缘和盆地北部伊盟隆起的东部,赋矿层位都是中侏罗统直罗组。盆地南、北铀矿区在现今地温场及古地温场都存在明显差异,南部现今大地热值及热演化程度明显高于北部。对于下侏罗统延安组和石炭—二叠系煤层,黄陵地区镜质体反射率都高于东胜地区。通过镜质体反射率资料得出同一埋深的一套地层经历的最大古地温和对应的古地温梯度也有南部高于北部的现象。由于早白垩世后期盆地普遍整体抬升使得现今地温相对古地温降低,南部黄陵地区抬升剥蚀量大于北部东胜地区,导致古、今地温差异也大于后者。盆地南部庆阳—富县一带局部构造热运动,导致南部异常地温场的形成,使得南部热演化程度高于北部。