Accumulation of petroleum hydrocarbons and heavy metals in clams （Ruditapes philippinarum） in Jiaozhou Bay, China

Accumulation and distributions of aliphatic and polyaromatic hydrocarbons (PAHs) and heavy metals were measured in tissues of the clam Ruditapes philippinarum collected from 5 sites in Jiaozhou Bay, Qingdao, China. The concentrations of total aliphatic hydrocarbon and PAHs ranged from 570 to 2 574 ng/gdw (gram dry weight) and from 276 to 939 ng/gdw, in the most and least polluted sites, respectively. The bio-accumulation of hydrocarbons and PAHs in the clams appeared to be selective. Aliphatic hydrocarbons were predominantly represented by short chain (<nC₂₃) n-alkanes, suggesting that petroleum hydrocarbons were likely the major contamination source. The selective uptake of 3 and 4 ring PAHs, such as naphthalene, fluorene, phenanthrene, fluoranthene and pyrene, by the clams was probably related to the physiological and bio-kinetic processes that were energetically favorable for uptake of compounds with fewer rings. Accumulation of the metals Cd, Cu, Zn, Pb, Cr, Hg, and As in the clam tissues also showed high variability, ranging from 0.043 to 87 μg/gdw. Among the 7 detected metals, Zn, Cd, Cu, and As had a particularly high potential of accumulation in R. philippinarum. In general, a positive correlation was found between the tissue concentrations and sediment concentrations of hydrocarbons and of some metals. Our study suggests that moderate contamination with polyaromatic hydrocarbons, and low to moderate contamination with metals, currently exists for clam R. philippinarum in Jiaozhou Bay, in comparison with other regional studies. A long-term monitoring program is certainly needed for assessment of the potential ecological influence and toxicity of these contaminants of R. philippinarum in Jiaozhou Bay.     

威宁宣威组底部硅质页岩Rb-Sr古混合线年龄及其地质意义

在滇黔相邻地区,二叠纪宣威组下部发育一层硅质页岩和碳质页岩。页岩层位稳定、分布广泛,与下伏峨眉山玄武岩组上部凝灰岩层呈假整合接触关系。用迭代法恢复硅质页岩的Rb-Sr同位素古混合线,得到硅质页岩的年龄为(255±12)Ma。这个年龄不仅支持地层古地磁研究结果,而且符合地层年代学研究结果,表明Rb-Sr同位素古混合线年代学方法在中生代地层能够适用。这个年龄与普遍认为的峨眉山玄武岩主喷发期258Ma从时代关系上相符,而且有效地约束了峨眉山玄武岩喷发的上限。     

四川大梁子铅锌矿床闪锌矿中镉富集规律及其意义

扬子地块西南缘铅锌矿床富集区是我国重要的铅锌矿产资源基地。四川会东大梁子铅锌矿床为区内的典型矿床,矿床具多阶段成因特征,矿物的穿插关系清晰,能准确地识别出矿物的形成顺序。闪锌矿为主要矿石矿物。依据矿物形成顺序,划分出三种具有显著不同标型特征的闪锌矿:黑色闪锌矿     

同位素水化学指示的新疆孔雀河流域地下水与地表水关系

地下水是孔雀河流域农业灌溉的主要水源之一,其对本地区经济发展的支撑作用日益增强.为实现孔雀河流域水资源合理开发和生态保护,采用环境同位素和水化学方法,研究了孔雀河流域地下水与地表水关系.结果表明:地下水的主要补给来源为河水.含水层成因类型和现代河道分布共同控制着孔雀河流域地下咸淡水的空间分布格局;氢氧稳定同位素对不同水...     

西北太平洋热带气旋路径的历史模拟

基于IBTrACS提供的热带气旋最佳路径数据集,在统计分析历史热带气旋的发生年频次、发生位置、路径移动及强度变化等的基础上,建立了西北太平洋热带气旋轨迹合成模型。模型包括生成模型、移动模型、消亡模型及强度模型4个部分,并从地理轨迹密度、年登陆率、登陆风速分布三个方面,对模拟的气旋路径与历史气旋路径进行比较,以验证模型的准确性和可靠性。结果表明,构建的西北太平洋热带气旋全路径统计模拟模型稳健可靠,可进一步应用于研究区热带气旋的定量精细化的风险评估,能提高气旋风险灾害评估的可信度。     

Minimal cut-based recursive decomposition algorithm for seismic reliability evaluation of lifeline networks

In this paper, a new probabilistic analytical approach, the minimal cut-based recursive decomposition algorithm (MCRDA), is presented to evaluate the seismic reliability of large-scale lifeline systems. Based on the minimal cut searching algorithm, the approach calculates the disjoint minimal cuts one by one using the basic procedure of the recursive decomposition method. At the same time, the process obtains the disjoint minimal paths of the system. In order to improve the computation efficiency, probabilistic inequality is used to calculate a solution that satisfies the prescribed error bound. A series of case studies show that MCRDA converges rapidly when the edges of the systems have low reliabilities. Therefore, the approach can be used to evaluate large-scale lifeline systems subjected to strong seismic wave excitation.     

塔里木盆地喀什凹陷克拉托天然气来源分析及聚气特征

塔里木西南喀什凹陷的克拉托天然气主要表现为原油的溶解气或者湿气,甲烷含量为74.59%~85.58%,克4井和克30井天然气则为较干的湿气。克拉托天然气的δ¹³C₁值为-41.2‰~-40.6‰,δ¹³C₂值为-30.0‰~-27.4‰。气源对比表明克拉托天然气主要源自具有混源母质特征的中侏罗统湖相烃源岩,不同于源自石炭系烃源岩的阿克莫木天然气。喀什凹陷的中-下侏罗统烃源岩主要是由于新近系的巨厚沉积才从未成熟—低成熟阶段进入成熟—高成熟阶段,生成的油气在克拉托背斜圈闭中聚集,虽也属晚期成藏,却具有连续聚气的特征。上新世末期,喀什凹陷的周缘开始抬升,早期油气藏受到破坏,形成了现今的地表油气苗或油砂。     

滇东北DD1井五峰组—龙马溪组地层界线划分及沉积环境演变

DD1井上奥陶统临湘组泥灰岩之上发育大套粉砂质泥岩,笔石化石缺乏,也未发现观音桥段含赫南特贝灰岩标志层,O-S界线通过生物地层和岩石地层方法难以确定.微量、稀土元素分析表明,粉砂质泥岩中部(1288.3 m)的Th、Sr、Y、Th/U以及Cen、Eun、δCe、δEu曲线均呈现尖锐的异常峰,该处∑REE含量显著高于上下...     

长白山火山活动历史、岩浆演化与喷发机制探讨

广义的长白山火山在我国境内包括著名的天池火山、望天鹅火山、图们江火山和龙岗火山,是我国最大的第四纪火山岩分布区。图们江火山和望天鹅火山活动都始于上新世,喷发活动分别介于上新世—中更新世（5.5~0.19 Ma）和上新世—早更新世（4.77 ~2.12 Ma）。天池火山和龙岗火山属于第四纪火山,喷发活动从早更新世（~2 Ma）持续到全新世。图们江火山岩为溢流式喷发的拉斑玄武岩,望天鹅火山、天池火山和龙岗火山母岩浆都是钾质粗面玄武岩,但经历了不同的演化过程。天池火山和望天鹅火山都经历了钾质粗面玄武岩造盾、粗面岩造锥和晚期碱性酸性岩浆（碱流岩和碱性流纹岩）的喷发;龙岗火山来自地幔的钾质粗面玄武岩浆则未经演化和混染直接喷出地表。图们江火山岩以溢流式喷发的拉斑玄武岩为主,少量玄武质粗安岩等。天池火山造盾之后,地壳岩浆房和地幔岩浆房具互动式喷发特点,来自地幔的钾质粗面玄武岩浆一方面在天池火山锥体内外形成诸多小火山渣锥,另一方面持续补给地壳岩浆房发生岩浆分离结晶作用和混合作用,分别导致双峰式火山岩分布特征和触发千年大喷发。火山岩微量元素和Sr-Nd-Pb同位素示踪揭示,长白山东（图们江火山、望天鹅火山和天池火山）、西（龙岗火山）两区显示地幔非均一性,东区岩浆源区具有软流圈地幔与富集岩石圈地幔混合特征,西区岩浆源区具有相对亏损的较原始地幔特征。西太平洋板块俯冲—东北亚大陆弧后引张是长白山火山活动的动力学机制。     

基于多元线性回归分析的页岩气有利区评价新方法 ——以上扬子地区五峰组—龙马溪组海相页岩为例

本文以四川盆地及其周缘五峰组—龙马溪组页岩气评价为例,总结了页岩气有利区优选的储层参数、保存参数和压力系数等参数,量化了各关键参数平面分布,运用多元线性回归分析方法计算了参数权重,通过多参数加权叠加公式建立了多元线性回归模型:有利区=-0.317+0.75×埋深+0.285×TOC+0.148×RO+0.093×孔隙度...