Late Triassic Biotite Monzogranite from the Western Litang Area,Yidun Terrane,SW China: Petrogenesis and Tectonic Implications

The Late Triassic igneous rocks in the Yidun terrane can provide vital insights into the evolution of Plaeo-Tethys in western China. We present new zircon U-Pb, whole-rock geochemistry, and Sr-Nd-Pb-Hf isotopic data for the Litang biotite monzogranites, Yidun terrane. The biotite monzogranites have a zircon U-Pb age of 206.1±1.0 Ma(MSWD=1.9,n=30), which indicates Late Triassic magmatism. The biotite monzogranites display I-type affinity, high Na_2O(3.38-3.60 wt%) contente,medii SiO_2(67.12-69.13 wt%), and low P_2 O_5 contents(0.10～0.12 wt%). They enriched in Rb,and Ba and depleted in Nb and Ta, with negative Eu anomalies(Eu/Eu*=0.74—0.81). They have evolved Sr-Nd-Pb-Hf isotopic composition, i.e.,(~(87) Sr/~(86 )Sr)i=0.714225 to 0.714763, negative ?_(Nd(t)) values of -2.0 to-2.6 with two-stage Nd model ages ranging from 1.01 to 1.05 Ga, negative ?_(Ht)(t)) values o f-3.4 to-4.1 with two-stage Hf model ages of 1.85 to1.88 Ga, suggesting a matured crustal sources. Their low Al_2O_3/TiO_2 ratios and medium Cao/Na_2O ratios, medium Mg~# and SiO_2 contents, low [molar Al_2O_3/(MgO+FeO~T)] values, and high [molar Cao/(MgO+FeO~T)] values indicate that the Litang biotite monzogranite was formed by partial melting of metabasaltic rocks. Based on the previous studies, we propose that the Litang biotite monzogranite derived from the westward subduction and closure of the Ganzi-Litang ocean during the Late Triassic-The mantle wedge-derived mafic melts provided sufficient heat for partial melting of ancient metabasalt protolith within the middle-lower crust.     

Structural Features and Function of the Karst Critical Zone

正1 Major achievements of IGCP 661 The IGCP661 project"Processes,Cycle,and Sustainability of the Critical Zone in Karst Systems (2017-2021)"has been carried out for two years.Besides five International karst meetings and two training courses for karst that have been held,some scientific achievements include the basic roles of the function and structural evolution of the karst critical zone have been determined.In various types of karst critical zone,the different forms of calcite and HCO_3~-cycling were determined.A     

Petrogenesis and PGE Abundances of High‐Cr and High‐Al Chromitites and Peridotites from the Bulqiza Ultramafic Massif,Eastern Mirdita Ophiolite,Albania

The Bulqiza ultmafic massif, which belongs to the eastern Mirdita ophiolite of northern Albania, is world renowned for its high‐Cr chromite resource. The high‐Cr chromitites commonly host in the mantle section, while high‐Al chromitites also present in massive dunite of the mantle‐crust transition zone (MTZ) in this massif. Chromian‐spinel in the MTZ high‐Al chromitites and MTZ dunites have much lower Cr# values [Cr/(Cr+Al)×100] (47.7–55.1 and 46.5–51.7, respectively) than those of chromian‐spinel in the high‐Cr chromitites (78.2–80.4), harzburgites (72.6–77.9) and mantle dunites (79.4–84.3). The high‐Cr chromitites are rich in IPGE relative to PPGE with 0.10–0.45 PPGE/IPGE ratios, whereas the high‐Al chromitites have higher PPGE/IPGE ratios between 1.20 and 7.80. The partial melting degrees of parental magmas for the high‐Cr chromitites are beyond the critical interval (> 25%) and thus prevented sulfide saturation and diluted Pt and Pd in melts, producing high‐Cr chromitites barren of Pt and Pd. However, the degrees for the high‐Al chromitites just enter the critical interval (20–25%) for the effective extraction of PGE from mantle sulfides, which may account for the enrichments of PPGE in high‐Al chromitites. The parental melts of the high‐Cr chromitites have Al₂O₃ and TiO₂ contents of ～10.6–11.4 wt.% and 0.14–0.31 wt.%, whereas the calculated Al₂O₃ and TiO₂ for the high‐Al chromitites are ～14.9–15.9 wt.% and 0.07–0.61 wt.%, respectively. The calculated melts in equilibrium with the high‐Cr chromitites are boninitic‐like, and those with high‐Al chromitites are MORB‐like but with hydrous, oxidized and TiO₂‐poor affinities. To make a compromise between the inconsistence above, we proposed that coexistence of both types of chromitites in the Bulqiza ultramafic massif may reflect that their magma compositions transited from MORB‐like to boninitic‐like in a proto‐forearc setting during subduction initiation. Key words: Chromian‐spinel, Platinum‐group elements, high‐Cr and high‐Al chromitite, Mirdita ophiolite, Albania.     

西藏拉萨地块盐湖石英闪长岩成因：锆石SHRIMP U- Pb年代学、地球化学及Sr- Nd- Pb- Hf同位素的制约

西藏阿里盐湖地区发育不同类型的火成岩,通常被认为形成于班公湖-怒江特提斯洋南向俯冲板片发生断离的构造背景。本文报道了盐湖石英闪长岩的锆石SHRIMP U-Pb年龄,全岩地球化学以及Sr-Nd-Pb-Hf同位素数据。盐湖石英闪长岩的锆石~(206)Pb/~(238)U加权平均年龄为118.5±1.9Ma,属早白垩世晚期。石英闪长岩样品主量元素表现为富钠的钙碱性岩石系列,A/CNK值介于0.84～0.89之间,属准铝质。微量元素富集Rb、K、Th、U等大离子亲石元素(LILE)和轻稀土元素(LREE),强烈亏损Nb、Ta、Zr、Hf、P、Ti等高场强元素(HFSE)和重稀土元素(HREE),无明显的Eu异常(δEu=0.81～0.98),无白云母和碱性暗色矿物,属准铝质未分异的I型花岗岩。盐湖石英闪长岩的(~(87)Sr/~(86)Sr)_i值为0.7045～0.7048,ε_(Nd)(t)值介于+0.5～+2.1之间,ε_(Hf)(t)值介于+7.9～+13之间,Hf同位素模式年龄t_(DM2)变化于283～674Ma之间。基于同位素以及岩石地球化学数据,表明盐湖石英闪长岩很可能是具亏损地幔印记的新生下地壳在角闪岩相发生部分熔融作用形成的。结合本文以及区域上的研究资料,盐湖石英闪长岩的形成时代和岩石地球化学特征与盐湖复式岩体中的花岗岩存在较大差异,具较低的锆石饱和温度(596～614℃),表明该岩体的形成尚未受到幔源物质上涌带来的热作用影响,很可能形成于板片断离前,班公湖-怒江特提斯洋持续南向俯冲的板片发生折返,俯冲角度变陡的深俯冲背景。     

甘肃白银厂折腰山VMS矿床蚀变带元素迁移及定量计算

折腰山矿床是甘肃省白银厂矿田内最典型的火山成因块状硫化物(VMS)矿床,赋矿围岩主要为奥陶纪石英角斑凝灰岩,属于FⅡ类流纹岩,为弧后环境的产物,在海底对流循环成矿作用过程中,遭受强烈的热液改造,形成了多种类型的蚀变。文章将折腰山矿床蚀变围岩分为弱蚀变带→绢云母硅化带→绿泥石化带→矿化带,利用蚀变趋势图解和质量迁移计算等方法,定量揭示了热液蚀变过程中元素的迁移规律。研究表明:①从弱蚀变带→矿化带,蚀变强度逐渐增大,主量元素P、Mn有一定活动性,二者的迁移量分别为-8.8%～8.8%和-1.8%～9.9%,但迁移趋势不规律;Si迁移量变化范围较大,为-16.2%～83.73%;Na、Ca、Sr大量迁出,其中Na、Ca最大迁出量分别可达-3.11%和-2.71%;Mg、Fe依次迁入,并在绿泥石化带中达到最大值9.49%和69.73%;K在绢云母化带中迁入量出现峰值1.6%,其后逐渐迁出,最大可达-2.22%;Rb的迁移行为与K一致;②高场强元素Nb、Ta、Zr、Hf等在热液蚀变过程中相对保持惰性;Al、Ti及Y表现为弱活动性;③主要成矿元素Cu随蚀变强度的增大,其迁入量有递增的趋势,Pb、Zn在矿化带中迁入,其余各带均为迁出;④热液活动过程中,SiO_2活化再沉淀,形成硅化蚀变;K的迁入形成绢云母化,并消耗了H~+,使热液酸度减小;Mg、Fe的迁入在还原环境下形成绿泥石化,并伴随金属硫化物的沉淀。因此,折腰山矿床中的绿泥石化可能是导致矿质发生沉淀的重要蚀变作用,其在勘查工作中可以作为寻找VMS矿体的重要标志。     

蔗渣生物质炭对喀斯特农田石灰性土壤氮转化过程的短期影响

生物质炭对于土壤中不同形态氮库的含量影响已有较多研究,但对西南喀斯特区石灰性土壤氮素形态,尤其是控制氮素形态的转化过程研究较为缺乏。本研究设置土壤中添加1%(C1)和3%(C2)蔗渣生物质炭2个用量水平,并以不施用蔗渣生物质炭作为对照(CK),共3个处理,通过 15 NH 4 NO 3 和NH^15 4 NO 3 成对标记技术,结合MCMC氮素转化模型研究了不同用量的蔗渣生物质炭对石灰性土壤氮转化过程的短期影响,为该地区蔗渣资源化利用和土壤氮保持提供理论支撑。结果表明,与CK相比,添加蔗渣生物质炭能够快速提高土壤pH和有机碳含量。添加生物质炭并没有显著改变土壤氮的矿化、铵态氮(NH^+ 4 )和硝态氮(NO^- 3 )的微生物同化和异养硝化速率,但NH^+ 4 吸附速率随生物质炭用量的增加而提高,以添加量最高的C2处理最大。添加生物质炭同样提高了土壤NH^+ 4 释放速率,但C1和C2处理的土壤NH^+ 4 释放速率并无显著性差异。与CK和C1处理相比,施用高量蔗渣生物质炭通过抑制自养硝化速率而显著降低了硝态氮净产生速率。这些结果表明,施用高量蔗渣生物质炭于石灰性土壤中可快速实现对NH^+ 4 吸附,降低自养硝化速率,减少NO^- 3 产生,从而降低了其损耗和淋失风险。     

硫酸型酸雨参与碳酸盐岩溶蚀的研究进展

碳酸盐岩的H2CO3溶蚀产生岩溶碳汇,占整个岩石风化碳汇的 94%。西南岩溶区硫酸型酸雨严重,硫酸型酸雨广泛参与碳酸盐岩的溶蚀。H2SO4参与的碳酸盐岩风化是一个大气CO2净释放过程,具有减汇作用巨大。另一方面,岩溶区石灰土壤和地下水具有较高的pH值及盐基饱和度,对H+有巨大的缓冲作用,大气酸沉降在碳酸盐岩地区可能并不会造成地下水的HCO3-和pH降低;相反,较高浓度的SO42-所产生的盐效应和SO2-4与各种阳离子形成的离子对会增大方解石、白云石溶解度,可增强H2CO3对碳酸盐的溶蚀,这可能会使岩溶作用产生更大的碳汇效应。因此,硫酸型酸雨参与碳酸盐岩风化的减汇效应不仅可能被高估,硫酸型酸雨还可能增强碳酸盐岩的H2CO3溶蚀,具有增加岩溶碳汇效应的作用。应结合石灰土壤对大气酸沉降的缓冲容量和阈值及大气酸沉降的H+与土壤中盐基离子的交换量,并综合考虑盐效应、离子对作用、同离子效应,客观评价硫酸型酸雨流经石灰土壤层后对碳酸盐岩溶蚀吸收大气/土壤CO2的影响      

福建重力台网映震效能分析

利用福建重力台网7套gPhone重力仪的连续观测资料,对不同震中距和震级地震的同震响应特征及重力仪映震的最大震中距进行分析。结果表明：1）福建重力台网的映震效能受震级和震中距影响,从映震能力来看,泉州台优于莆田台,厦门台优于福州台,漳州台和龙岩台优于南平台;2）福建重力台网的仪器稳定性好和灵敏度高,与CMG-3ESP 120S地震计相比,重力仪具有较宽的地震频带,其同震响应持续时间与波幅呈高度正相关性;3）福建重力台网仪器映震的最大震中距(Δ)与震级（M_S）存在对应关系,具体公式为M_S=-0.218(logΔ)3+2.056(logΔ)2-4.594logΔ+6.459。     

河北沧县台拱带中、低温地热资源ORC发电与综合梯级利用

京津冀地热资源梯级综合开发利用(献县)科研基地大地构造位置位于华北平原沧县台拱带之献县断凸,利用其地下蓟县系岩溶裂隙热储层热水开展中低温地热发电与综合梯级利用研究。地热发电装机容量280 kW,采用ORC向心透平膨胀技术,系统工质为R245fa。分别于2018年2月4—6日(冬季)、2018年3月6—16日(春季)进行两次试运行,累计发电时长274h,累计发电量36956kWh,平均发电效率9.1%,最高10.4%。发电效率高于我国已有中低温地热发电项目,在目前国际中低温ORC地热发电项目中处于较高水平。试运行期间发电机组整体运行效果较好且运行稳定,冬季地热发电机组运行效果好于春季。科研基地建设完成后,将进行发电、供暖、地热生态园三级利用,按照90～95/25℃的地热水热能潜力,综合发电供暖两级利用计算能源综合利用率将达70%～76%。