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41.
The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S2 generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S2 generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S2 generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen. 相似文献
42.
Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which
makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization
of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary
to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms
for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model
appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the
random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions
correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they
are layer specific and include uncertainty caused by using variance estimates. 相似文献
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44.
Prakash M. Ramchandran Radhika Ramchandran K. Sen Gupta S. M. Patil P. N. Jadhav 《Boundary-Layer Meteorology》2002,104(3):445-461
The central path of the total solar eclipse (TSE) of 11 August 1999 mostly passedthrough a region of active monsoon in India, with the eclipse ending around localsunset. Measurements in the surface layer (SL) were carried out close to the eclipseaxis at Akola (20°42' N, 77°2' E) in central India. The globalradiation flux reaching the surface vanishes around totality at 1803:24 (LT), followedby a small recovery before again dipping to zero at sunset. The temperatures in the SL, and subsoil at 50-mm depth, show a local minimum with a lag of about 10 min after the second contact, whereas the lag appears to vanish when the temperature series is detrended. The SL exhibits near-neutral, though generally stable, conditions from about 1500 hr itself due to heavy cloud cover followed by the eclipse-induced cooling of the surface. The wind component across the eclipse axis vanishes at totality, the wind vector aligning with the azimuth of the traversing moon shadow. The deceleration of the mean flow can be due to the combined effect of the colder surface and downward heat flux, where the locally altered horizontal temperature gradients may cause, as in this instance, the cessation of the cross flow.The oscillations in temperature and wind that show significant peaks, around 90–100 min as well as the semi-period of the eclipse near 60 min, persist for several hours past the eclipse event. A fresh analysis of the published data on the TSE of 7 March 1970 shows spectral peaks in the temperature nearly coincident with those already reported from the surface pressure records. The oscillations in the SL fields during the two TSE events are very similar implying that the source mechanism is also likely to be the same in both the cases. 相似文献
45.
新时期我国区域经济地理学发展问题初探 总被引:4,自引:0,他引:4
我国新时期的区域经济地理学在取得全面发展的同时,在理论体系,研究方法和实践领域等方面还需要进一步的发展,文章根据学习和实践区域经济地理学的体会,初步提出基础理论和应用理论,思维方法和技术方法等方面发展见解,并指出区域创新系统和国际经济技术合作等学科应注意拓展的重要实践领域,最后提出我国区域经济地理学科发展的建议。 相似文献
46.
47.
成都市民消费结构与休闲活动关系研究 总被引:6,自引:0,他引:6
城市居民消费水平,消费结构会影响其休闲消费能力,消费意愿,消费方式,消费态度和休闲时空结构,文章以成都市7个城区歌舞,茶棋牌,电影及城市公园休闲活动调查为基础,探讨了城市居民消费结构及其变化与休闲活动特征的关系。研究结果表明,城市居民消费结构的改变对歌舞,茶棋牌娱乐活动影响最大。 相似文献
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49.
区域视觉形象识别系统设计的理论与实践 总被引:6,自引:0,他引:6
目前,全国各地正在兴起区域形象设计与建设的浪潮,但如何把区域形象信息系统地传递出去,这方面的理论研究大大落后于实践。文章就区域形象信息传递的有效工具-区域视觉识别系统设计的主要内容,设计的原则,设计的基本流程等在理论与实践上作了较为详细的探讨,并就区域视觉识别系统设计方案的经济学论证作了一些有益探讨。 相似文献
50.