Multiyear Observations of Deposition-Mode Ice Nucleating Particles at Two High-Altitude Stations in India

Ice nucleating particle(INP) measurements were made at two high-altitude stations in India. Aerosols collected on filter paper at Girawali Observatory, Inter University Center for Astronomy Astrophysics(IGO), and at the Radio Astronomy Center, Ooty(RAC), were activated in deposition mode using a thermal gradient diffusion chamber to determine the INP concentrations. The measurement campaigns at IGO were conducted during 2011, 2013 and 2014, and at RAC during 2013 and 2014. When the aerosol samples were exposed to an ice supersaturation of between 5% and 23% in the temperature range~(-1)7.6?C to-22?C, the maximum INP number concentration at IGO and RAC was 1.0 L~(-1) and 1.6 L~(-1), respectively.A maximum correlation coefficient of 0.76 was observed between the INP number concentration and ice supersaturation. The airmass trajectories analyzed for the measurement campaigns showed that the Arabian Desert and arid regions were the main INP contributors. Elemental analysis of particles showed the presence of Na, Cl, Si, Al, Fe, Cu, Co, Cd, S, Mn and K, as well as some rare-Earth elements like Mo, Ru, La, Ce, V and Zr. When aerosols in the size range 0.5–20 μm were considered, the fraction that acted as INPs was 1 : 10~4 to 1 : 10~6 at IGO, and 1 : 10~3 to 1 : 10~4 at RAC. The higher ratio of INPs to aerosols at RAC than IGO may be attributable to the presence of rare-Earth elements observed in the aerosol samples at RAC, which were absent at IGO.     

Modeling the effects of controlled drainage at a watershed scale using SWATDRAIN

The recently developed SWATDRAIN model was employed to assess the impact of controlled drainage on the water table dynamics, subsurface drainage, and surface runoff in an agricultural watershed in Ontario, Canada. Controlled drainage was defined with a depth of 1.0 m to restrict flow at the drain outlet to maintain the water table at 0.5 m below the surface level during the winter (November–April) and at 0.6 m during the summer (June–August) months. The effects of the absence, or implementation, of drainage water management were predicted for the 3-year period of 1991–1993. Implementing controlled drainage resulted in a 16 % reduction in the mean annual drain flow, while increasing surface runoff by as much as 71 %. This indicates that overall watershed hydrology could be significantly impacted by the implementation of controlled drainage. This research demonstrates the SWATDRAIN model’s ability to predict the controlled drainage in small agricultural watersheds.     

Geochemical behaviour of LREE,Y and Zr in uranium mineralized and non-mineralized granite from Darshanapur area,in the Gogi-Kurlagere fault zone,Bhima basin,Yadgiri district,Karnataka

Granite core samples (n=14) from the Gogi-Kurlagere fault zone in the central part of the Bhima basin were studied in terms of LREE, Y and Zr mobility during uranium mineralization. LREE, Zr and Y along with LILE (Ba, Rb) and P show behavioral differences in the mineralised and the non-mineralised samples. Average ΣLREE in mineralised granite (240 ppm) is higher than in non-mineralised samples (157 ppm). The average Zr and Y in the mineralised granite are 193 ppm and 17 ppm, while the corresponding abundances of these elements in non-mineralised portion are 148 ppm and 11 ppm respectively. Besides enrichment of U, Th, Ba, Pb and Rb and depletion of Sr are observed in mineralized granite in comparison to non-mineralized granite. Hydrothermal alteration has led to the mobility of these elements, which again dependent on the overall geochemical behavior of the migrating fluid. REE and Y in association with uranyl [(UO₂)²⁺] ion were transported as carbonate complexes like [UO₂(CO₃)₃]^4- and [REE (CO₃)₃]^3- and were later incorporated into favourable structural loci by precipitating minerals like pitchblende and coffinite.     

Transition in Late Quaternary Paleoclimate in Schirmacher Region,East Antarctica as Revealed from Lake Sediments

The lacustrine sediments are one of the best sources to provide information on climate change, specially in peri-glacial climatic region. Schirmacher Oasis, located on the Princess Astrid Coast in Queen Maud Land, is one of the few areas in East Antarctica that provides valuable information on paleoclimate of the region with various depositional features formed due to deglaciation process. This Oasis is dotted with more than 100 lakes of proglacial, land-locked and epi-shelf type. The multi-proxy sedimentological data, generated from the sediment cores from land-locked lakes and grab sample from a proglacial lake, lying in the same drainage line in the central part of Schirmacher region has provided better insight into the paleoclimatic evolution of the region. The immature and chemically unaltered lake sediments have shown restricted drainage pattern. Different phases of warmer and cooler intervals are highlighted by the patterns of fluctuations in different sedimentological and statistical parameters. The dominance of glacial signatures is very clear on the lake sediments as revealed by the surface textures of quartz grains. Physical weathering has mainly controlled the overall sediments and the composition of clay fraction. The clay minerals indicate a gradual shift in the weathering regime and therewith in climate from strongly glacial to fluvioglacial specially around 42 ka. This indicates beginning of warming of the area much before the LGM. But the warm period is not strong enough to alter the overall clay chemistry. Proxy records indicate short-period climatic oscillations during late Quaternary.     

A Petrological and Geochemical Account of Subsurface Noritic Intrusion in the Western Part of Bundelkhand Massif,Shivpuri District,M.P.

Subsurface exploration for uranium in the northwestern part of Bundelkhand massif, near Khor area, Shivpuri dist., M.P., resulted in intercepting a substantial thickness of mafic rock within Bundelkhand granitoid. Intercepts of this mafic rock at various levels in the boreholes, indicate that the rock mainly occurs as dykelike intrusion and fracture-fills within Bundelkhand granite. It is essentially composed of hypersthene and plagioclase, with or without olivine, leading to the characterisation as hypersthene microdolerite, noritic dolerite and norite (±olivine), depending on the grainsize and variation from intergranular to ophitic texture. Chemically, the rock is characterised by av. 49.09% SiO₂, 2.46%TiO₂, 2.33 Fe₂O₃, 9.45% FeO, 5.75% MgO, 8.37% CaO and 0.96% K₂O. The normative composition ranges from 3.53% quartz, 46.86% plagioclase, 12.58% diopside, 19.24% hypersthene. The olivine normative samples show av. 5.65% olivine. Geochemical plots indicate an intra-plate affinity along with oceanic signature, while presence of mineralogical and normative olivine, together with the REE pattern, point towards a lower crustal or mantle source. The mineralogical and normative presence of either quartz or olivine in these mafic rocks implies that it has an intermediate character between the tholeiitic dolerite dykes and the komatiite-type ultramafics reported from Bundelkhand craton. The complex geochemical signature of the rocks also reveals that both intra-continental as well as a mixture of oceanic- to upper mantle signatures are evident. The present study is a first time report of the occurrence of this hitherto unknown noritic body at depth within the Bundelkhand granite, which has no visible surface expression. The findings may strengthen the existing concept of a continuum between Rajasthan craton in the west and Bundelkhand craton in the east, as a single protocontinent.     

Fault rupture directivity of large earthquakes in Himalaya

The paper examines the predominant fault rupture directivity during large earthquakes in different sectors of the Himalaya which influences strong ground motion and damage scenario. The nature of the faulting of earthquakes vis-à-vis their rupture directivity has been discussed. It is found that the rupture directivity near the Indo-Eurasian plate boundary varies from place to place i.e. either along the strike direction of the faults or at right angles to it. The secondary meizoseismal areas as observed for 1505 Dharchula, 1803 Uttarakhand, 1905 Kangra earthquakes in the Himalaya and 2001 Bhuj earthquake in stable continental region suggest that they are a fairly good indicator of predominant rupture directivity since the latter accentuates the site response up to a longer distance. The resulting larger ground motions, therefore, need to be incorporated in the design of engineering structures by suitable modifications in the BIS code.     

Assessment of vulnerability zones for ground water pollution using GIS-DRASTIC-EC model: A field-based approach

Assessment of groundwater vulnerability to pollution is an essential pre-requisite for better planning of an area. We present the groundwater vulnerability assessment in parts of the Yamuna Nagar District, Haryana State, India in an area of about \(800 \hbox { km}^{2}\), considered to be a freshwater zone in the foothills of the Siwalik Hill Ranges. Such areas in the Lower Himalayas form good groundwater recharge zones, and should always be free from contamination. But, the administration has been trying to promote industrialization along these foothill zones without actually assessing the environmental consequences such activities may invite in the future. GIS-DRASTIC model has been used with field based data inputs for studying the vulnerability assessment. But, we find that inclusion electrical conductivity (EC) as a model parameter makes it more robust. Therefore, we rename it as GIS-DRASTIC-EC model. The model identifies three vulnerability zones such as low, moderate and high with an areal extent of 5%, 80% and 15%, respectively. On the basis of major chemical parameters alone, the groundwater in the foothill zones apparently looks safe, but analysis with the help of GIS-DRASTIC-EC model gives a better perspective of the groundwater quality in terms of identifying the vulnerable areas.     

Gypsum–anhydrites in 1.9 Ga Vempalle Formation,Cuddapah basin,India: A note on the Palaeoproterozoic environment and diagenetic condition

The Cuddapah basin consists of generally well-preserved Palaeoproterozoic–Neoproterozoic sedimentary and associated volcanic rocks. The detailed lithological studies of sedimentary rocks of Vempalle Formation from the narrow linear belt of 15 km, in the southern margin, show the occurrence of layered gypsum in the cherty dolostone–shale intercalated facies, red shale and phosphatic dolostone facies of the Vempalle Formation. The petromineralogical studies reveal that gypsum is in close association with anhydrites. Microscopically, three different types of gypsum and anhydrite are identified, viz., lath-shaped, equant-shaped and anhedral-shaped grains. The equant variety corresponds to a granular gypsum, whereas the anhedral grains of gypsum exist as the granular and fibrous variety as seen in the hand specimen. The presence of gypsum/anhydrite has been confirmed by the petromineralogical, X-ray diffraction and chemical analytical data. The phosphatic dolostone is the host rock for stratabound type of uranium deposit at Tummalapalle, Cuddapah district, Andhra Pradesh, which is one of the most unique types of uranium mineralisation in the world. Abundant pseudomorphs of gypsum and anhydrite relicts and discontinuous gypsum layers within these dolostones, nodules of chert and gypsum indicate the interrelationship between the diagenesis and genesis of uranium mineralisation which indicates the carbonate precipitation in the sulphate-rich hypersaline environments.     

Simplified SMA-inspired 1-parameter SCS-CN model for runoff estimation

This study proposes a simplified 1-parameter SCS-CN model (M5) based on Mishra-Singh (2002) model and soil moisture accounting (SMA) procedure for surface runoff estimation and compares its performance with the existing SCS-CN method (SCS, 1956) (M1), Michel 1-P model (Water Resour Res 41:1-6, 2005) (M2), Sahu 1-P model (Hydrol Process 21:2872-2881, 2007) (M3), and Ajmal et al. model (J Hydrol 530:623-633, 2015) (M4) using large rainfall–runoff dataset of 48,763 events from123 USDA-ARS watersheds. The performance of models was evaluated using three statistical error indices such as Nash-Sutcliffe efficiency (NSE), root mean square error (RMSE), percentage bias (PBIAS), and rank and grading system (RGS). Based on the results obtained, the models can be ranked as follows: M5?>?M4?>?M3?>?M1?>?M2, i.e., model M5 outperformed all the remaining four models M1–M4 and hence is recommended for field applications.