Studies on Intercorrelation between Ions Co-Occurring in Precipitation in the Gdańsk-Sopot-Gdynia Tricity (Poland)

The paper presents monitoring results and environmental pollution assessment for the Gdask-Sopot-Gdynia Tricity (Poland), based onanalysis of precipitation. Precipitation samples were collected over a period of 12 months (January–December 1998) at ten locations in the Tricity. The following selected ions were determined in the samples:SO₄ ^2–, F^–, Cl^–, NO₃ ^–,PO₄ ^3–, NH₄ ⁺, Na⁺,Mg²⁺, Ca²⁺, K⁺. The results were subjected to full statistical evaluation. Values of the parameters determined were correlated with each other. An attempt was made to explain co-occurrences of certain ions and the significance of their mutual effects. Pollutant concentrations and loads in precipitation were also correlated with data on wind direction and temperature in the region.Deposition of pollutants was very high in spring due to the prevailing air circulation patterns and low temperatures. Analysis of the correlations between co-occurring ions confirmed the significant impact of the location (sea coast) on the composition of rain water. Ionic ratios in rainwater were similar to those observed for sea salt samples. In addition, heavy traffic was most probably responsible for high concentrations of various forms of nitrogen and sulphates in the vicinity of major highways.     

Oxfordian magnetostratigraphy of Poland and its correlation to Sub-Mediterranean ammonite zones and marine magnetic anomalies

A nearly continuous magnetostratigraphic polarity pattern was compiled from several ammonite-zoned carbonate successions of southern Poland and from a composite magnetostratigraphy from the Iberian Range of Spain. The array of sections spans the middle two-thirds of the Oxfordian within the Sub-Mediterranean Province (Cordatum through Bifurcatus ammonite zones). The average paleopole calculated from eight of these Polish sections is at 78.5°N, 184.9°E (δp = 2.6°, δm = 3.5°). The Sub-Mediterranean polarity pattern is consistent with an independent polarity pattern derived from the Boreal-realm sections of the British Isles, and improves the inter-correlation between these faunal realms. Cycle stratigraphy published for these ammonite subzones from southern France enabled temporal scaling of the polarity pattern, thereby facilitating correlation to marine magnetic anomalies M28 through M33 as modeled from deep-tow magnetometer surveys in the Western Pacific. The bases of the Middle and Upper Oxfordian substages as defined in the Sub-Mediterranean zonation in Poland correspond approximately to chrons M33 and M29 of that Pacific M-sequence model.     

Arguments for ionic nature of the Carpathian electric conductivity anomaly

This publication is a contribution to discussion on the geometry and petrography of the rock complex responsible for the Carpathian conductivity anomaly. We analysed arguments showing that this anomaly is caused by induction in the sedimentary basin, and make a critical review of various data to find out whether the good conductivity is connected with a rock complex containing graphite or mineralized water. We conclude that a more likely mechanism is the ionic one, i.e., the existence of fluids, although a final decision can only be made on the basis of deep drillings.     

Rock magnetic evidence of inflation of a flood basalt lava flow

The anisotropy of magnetic susceptibility (AMS) of lava flows is an innovative method which has been proved to be directly related to the shear history of lava. One of the advantages of this method is that it can be used in the absence of other morphological features commonly employed to study the mechanism of emplacement of lava flows. This feature of the AMS method makes it very attractive to gain insight into the mechanism of emplacement of massive, relatively featureless, long lava flows such as those forming flood basalt provinces. In this work, we report the results of the measurement of AMS as a function of vertical position within the Birkett lava flow, one of the Columbia River Basalt Group flows. The observed variation of AMS allows us to identify at least 16 discrete events of lava injection and to estimate the thickness of individual injection events. The AMS-estimated thickness of each injection event (in the range of 0.5-4.0 m) coincides with the range inferred for injected lava pulses in modern Hawaiian lava flows. Thus, the evidence provided by the AMS method supports the notion that at least some flood basalt lava flows were emplaced by the same mechanism as many present-day inflated pahoehoe flows. Regarding the orientation of the principal susceptibilities, in the central part of the flow they define a preferred orientation along an E-W trend, whereas in the outer parts of the flow they have a NNE-SSW trend. This difference in the orientation of the principal susceptibilities is interpreted as the result of a change of flow direction of the lava as emplacement progressed. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00445-002-0203-8.     

The fissure swarm of the Askja volcanic system along the divergent plate boundary of N Iceland

Divergent plate boundaries, such as the one crossing Iceland, are characterized by a high density of subparallel volcanic fissures and tectonic fractures, collectively termed rift zones, or fissure swarms when extending from a specific volcano. Volcanic fissures and tectonic fractures in the fissure swarms are formed during rifting events, when magma intrudes fractures to form dikes and even feeds fissure eruptions. We mapped volcanic fissures and tectonic fractures in a part of the divergent plate boundary in northern Iceland. The study area is ~1,800 km², located within and north of the Askja central volcano. The style of fractures changes with distance from Askja. Close to Askja the swarm is dominated by eruptive fissures. The proportion of tectonic fractures gets larger with distance from Askja. This may indicate that magma pressure is generally higher in dikes close to Askja than farther away from it. Volcanic fissures and tectonic fractures are either oriented away from or concentric with the 3–4 identified calderas in Askja. The average azimuth of fissures and fractures in the area deviates significantly from the azimuth perpendicular to the direction of plate velocity. As this deviation decreases gradually northward, we suggest that the effect of the triple junction of the North American, Eurasian and the Hreppar microplate is a likely cause for this deviation. Shallow, tectonic earthquakes in the vicinity of Askja are often located in a relatively unfractured area between the fissure swarms of Askja and Kverkfjöll. These earthquakes are associated with strike-slip faulting according to fault plane solutions. We suggest that the latest magma intrusions into either the Askja or the Kverkfjöll fissure swarms rotated the maximum stress axis from being vertical to horizontal, causing the formation of strike-slip faults instead of the dilatational fractures related to the fissure swarms. The activity in different parts of the Askja fissure swarm is uneven in time and switches between subswarms, as shown by a fissure swarm that is exposed in an early Holocene lava NW of Herðubreið but disappears under a younger (3500–4500 BP) lava flow. We suggest that the location of inflation centres in Askja central volcano controls into which part of the Askja fissure swarm a dike propagates. The size and amount of fractures in the Kollóttadyngja lava shield decrease with increasing elevation. We suggest that this occurred as the depth to the propagating dike(s) was greater under central Kollóttadyngja than under its flanks, due to topography.     

Environmental impact of heavy-metal dispersion in the Huerva River (Iberian Range,NE Spain)

In this study, the methodology of geochemical prospecting has been applied to the study of cadmium, lead, copper and zinc dispersion in the fine sediments of the upper course of the Huerva River (Iberian Range, NE Spain). The survey was organised in two stages: (1) general sampling along the river and its tributary channels, aimed at selecting the sections with the highest contents of the target elements, and (2) detailed study of those sections, aimed at an interpretation of possible positive geochemical anomalies and identification of their sources. The results of this study prove the existence of multiple and complex sources, with a significant influence of sources related to anthropogenic activity. However, the system shows a good ability to depurate itself under current conditions.     

An estuarine benthic index of biotic integrity for the Mid-Atlantic region of the United States. II. Index development

A benthic index of biotic integrity was developed for use in estuaries of the mid-Atlantic region of the United States (Delaware Bay estuary through Albemarle-Pamlico Sound). The index was developed for the Mid-Atlantic Integrated Assessment Program (MAIA) of the U.S. Environmental Protection Agency using procedures similar to those applied previously in Chesapeake Bay and southeastern estuaries, and was based on sampling in July through early October. Data from seven federal and state sampling programs were used to categorize sites as degraded or non-degraded based on dissolved oxygen, sediment contaminant, and sediment toxicity criteria. Various metrics of benthic community structure and function that distinguished between degraded and reference (non-degraded) sites were selected for each of five major habitat types defined by classification analysis of assemblages. Each metric was scored according to thresholds established on the distribution of values at reference sites, so that sites with low scoring metrics would be expected to show signs of degradation. For each habitat, metrics that correctly classified at least 50% of the degraded sites in the calibration data set were selected whenever possible to derive the index. The final index integrated the average score of the combination of metrics that performed best according to several criteria. Selected metrics included measures of productivity (abundance), diversity (number of taxa, Shannon-Wiener diversity, percent dominance), species composition and life history (percent abundance of pollution-indicative taxa, percent abundance of pollution-sensitive taxa, percent abundance of Bivalvia, Tanypodinae-Chironomidae abundance ratio), and trophic composition (percent abundance of deep-deposit feeders). The index correctly classified 82% of all sites in an independent data set. Classification efficiencies of sites were higher in the mesohaline and polyhaline habitats (81–92%) than in the oligohaline (71%) and the tidal freshwater (61%). Although application of the index to low salinity habitats should be done with caution, the MAIA index appeared to be quite reliable with a high likelihood of correctly identifying both degraded and non-degraded conditions. The index is expected to be of great utility in regional assessments as a tool for evaluating the integrity of benthic assemblages and tracking their condition over time.     

Long-term deforestation in NW Spain: linking the Holocene fire history to vegetation change and human activities

The Holocene fire regime is thought to have had a key role in deforestation and shrubland expansion in Galicia (NW Spain) but the contribution of past societies to vegetation burning remains poorly understood. This may be, in part, due to the fact that detailed fire records from areas in close proximity to archaeological sites are scarce. To fill this gap, we performed charcoal analysis in five colluvial soils from an archaeological area (Campo Lameiro) and compared the results to earlier studies from this area and palaeo-ecological literature from NW Spain. This analysis allowed for the reconstruction of the vegetation and fire dynamics in the area during the last ca 11 000 yrs. In the Early Holocene, Fabaceae and Betula sp. were dominant in the charcoal record. Quercus sp. started to replace these species around 10 000 cal BP, forming a deciduous forest that prevailed during the Holocene Thermal Maximum until ～5500 cal BP. Following that, several cycles of potentially fire-induced forest regression with subsequent incomplete recovery eventually led to the formation of an open landscape dominated by shrubs (Erica sp. and Fabaceae). Major episodes of forest regression were (1) ～5500–5000 cal BP, which marks the mid-Holocene cooling after the Holocene Thermal Maximum, but also the period during which agropastoral activities in NW Spain became widespread, and (2) ～2000–1500 cal BP, which corresponds roughly to the end of the Roman Warm Period and the transition from the Roman to the Germanic period. The low degree of chronological precision, which is inherent in fire history reconstructions from colluvial soils, made it impossible to distinguish climatic from human-induced fires. Nonetheless, the abundance of synanthropic pollen indicators (e.g. Plantago lanceolata and Urtica dioica) since at least ～6000 cal BP strongly suggests that humans used fire to generate and maintain pasture.