Shear wave crustal velocity model of the Western Bohemian Massif from Love wave phase velocity dispersion

We propose a new quantitative determination of shear wave velocities for distinct geological units in the Bohemian Massif, Czech Republic (Central Europe). The phase velocities of fundamental Love wave modes are measured along two long profiles (~200 km) crossing three major geological units and one rift-like structure of the studied region. We have developed a modified version of the classical multiple filtering technique for the frequency-time analysis and we apply it to two-station phase velocity estimation. Tests of both the analysis and inversion are provided. Seismograms of three Aegean Sea earthquakes are analyzed. One of the two profiles is further divided into four shorter sub-profiles. The long profiles yield smooth dispersion curves; while the curves of the sub-profiles have complicated shapes. Dispersion curve undulations are interpreted as period-dependent apparent velocity anomalies caused both by different backazimuths of surface wave propagation and by surface wave mode coupling. An appropriate backazimuth of propagation is found for each period, and the dispersion curves are corrected for this true propagation direction. Both the curves for the long and short profiles are inverted for a 1D shear wave velocity model of the crust. Subsurface shear wave velocities are found to be around 2.9 km/s for all four studied sub-profiles. Two of the profiles crossing the older Moldanubian and Teplá-Barrandian units are characterized by higher velocities of 3.8 km/s in the upper crust while for the Saxothuringian unit we find the velocity slightly lower, around 3.6 km/s at the same depths. We obtain an indication of a shear wave low velocity zone above Moho in the Moldanubian and Teplá-Barrandian units. The area of the Eger Rift (Teplá-Barrandian–Saxothuringian unit contact) is significantly different from all other three units. Low upper crust velocities suggest sedimentary and volcanic filling of the rift as well as fluid activity causing the earthquake swarms. Higher velocities in the lower crust together with weak or even missing Moho implies the upper mantle updoming.     

Acigöl rhyolite field,central Anatolia (part II): geochemical and isotopic (Sr–Nd–Pb, δ<Superscript>18</Superscript>O) constraints on volcanism involving two high-silica rhyolite suites

The Acigöl rhyolite field erupted the most recent high-silica rhyolites within the Cappadocian Volcanic Province of central Anatolia, Turkey. It comprises two sequences of domes and pyroclastic rocks with eruption ages of ~150–200 ka (eastern group) and ~20–25 ka (western group). Compositionally, the eastern rhyolite group lavas are less evolved (SiO₂ = 74–76 wt%), whereas the western group has higher silica abundance (SiO₂ = ~77 wt%) with extremely depleted feldspar-compatible trace elements. Within each group, compositional variability is small and ¹⁴³Nd/¹⁴⁴Nd (0.51257–0.51265) and Pb isotope compositions (²⁰⁶Pb/²⁰⁴Pb = 18.87–18.88, ²⁰⁷Pb/²⁰⁴Pb = 15.65–15.67 and ²⁰⁸Pb/²⁰⁴Pb = 38.94–38.98) are homogeneous. The western group rhyolites have δ¹⁸O(zircon) overlapping mantle values (5.7 ± 0.2‰), whereas eastern group rhyolites are enriched in δ¹⁸O by ~0.5‰, consistent with a tendency to lower εNd values. By contrast, western group rhyolites have markedly more radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7065–0.7091) compared to those of the eastern group (0.7059–0.7065). The presence of angular granitic xenoliths and a correlation between hydration (based on loss on ignition data) and ⁸⁷Sr/⁸⁶Sr in the western lavas, however, indicates that Sr was added during the eruption or post-eruption alteration. Isotope constraints preclude the possibility that the rhyolite magmas formed by partial melting of any known regional crystalline basement rocks. Basalts and andesites erupted in the periphery of the Acigöl field are characterised by ⁸⁷Sr/⁸⁶Sr ratios between 0.7040 and 0.7053, ¹⁴³Nd/¹⁴⁴Nd = 0.51259–0.51300, ²⁰⁶Pb/²⁰⁴Pb = 18.85–18.87, ²⁰⁷Pb/²⁰⁴Pb = 15.646–15.655, ²⁰⁸Pb/²⁰⁴Pb = 38.90–38.97. The isotopic and trace element data favour an origin of the rhyolites by mixing of basaltic/andesitic magmas with minor amounts of crustal melts and followed by extensive fractional crystallization.     

Barium-rich fluids and melts in a subduction environment (La Corea and Sierra del Convento mélanges,eastern Cuba)

Whole-rock compositions of muscovite-bearing amphibolite, trondhjemite, pegmatite and quartz-muscovite rocks from Sierra del Convento and La Corea mélanges (eastern Cuba), as well as mineralogy, record complex circulation of Ba-rich fluids and melts in the subduction environment. Partial melting of fluid-fluxed, MORB-derived amphibolite produced trondhjemite magmas that crystallized at depth, in some cases evolving into pegmatites. Qtz-Ms rocks probably crystallized from primary fluids derived from subducted sediments. All these rocks have elevated concentrations of large-ion lithophile elements, especially Ba (up to 11,810 ppm), presumably released from slab sediments by fluids and/or melts. Fluid–rock interaction produced crystallization of phengite in parental amphibolites. The phengite crystallized in all types of rocks is rich in Ba, with concentric zoning, characterized by Ba-rich cores and Ba-poor rims, indicating a compatible behaviour of Ba in the studied systems. Zoning in phengite is governed primarily by the celadonite (tschermak) exchange vector ((Mg,Fe)Si-(Al)_-2), with more moderate contributions of the celsian (BaAl-(KSi)_-1) and paragonite (NaK_-1) exchange vectors. Late remobilization of Ba at relatively low temperature formed retrograde celsian. The compatible behaviour of Ba in the studied rocks strengthens the importance of the stability of phengite for the transfer of LIL elements from the subduction to the volcanic arc environments.     

Uranium speciation and stability after reductive immobilization in aquifer sediments

It has generally been assumed that the bioreduction of hexavalent uranium in groundwater systems will result in the precipitation of immobile uraninite (UO₂). In order to explore the form and stability of uranium immobilized under these conditions, we introduced lactate (15 mM for 3 months) into flow-through columns containing sediments derived from a former uranium-processing site at Old Rifle, CO. This resulted in metal-reducing conditions as evidenced by concurrent uranium uptake and iron release. Despite initial augmentation with Shewanella oneidensis, bacteria belonging to the phylum Firmicutes dominated the biostimulated columns. The immobilization of uranium (∼1 mmol U per kg sediment) enabled analysis by X-ray absorption spectroscopy (XAS). Tetravalent uranium associated with these sediments did not have spectroscopic signatures representative of U-U shells or crystalline UO₂. Analysis by microfocused XAS revealed concentrated micrometer regions of solid U(IV) that had spectroscopic signatures consistent with bulk analyses and a poor proximal correlation (μm scale resolution) between U and Fe. A plausible explanation, supported by biogeochemical conditions and spectral interpretations, is uranium association with phosphoryl moieties found in biomass; hence implicating direct enzymatic uranium reduction. After the immobilization phase, two months of in situ exposure to oxic influent did not result in substantial uranium remobilization. Ex situ flow-through experiments demonstrated more rapid uranium mobilization than observed in column oxidation studies and indicated that sediment-associated U(IV) is more mobile than biogenic UO₂. This work suggests that in situ uranium bioimmobilization studies and subsurface modeling parameters should be expanded to account for non-uraninite U(IV) species associated with biomass.     

Leaching of metals from copper smelter flue dust (Mufulira,Zambian Copperbelt)

The leaching behaviour of electrostatic precipitator dust from the Mufulira Cu smelter (Copperbelt, Zambia) was studied using a 48-h pH-static leaching experiment (CEN/TS 14997). The release of metals (Cd, Co, Cu, Ni, Pb and Zn) and changes in mineralogical composition using X-ray diffraction and PHREEQC-2 modelling were investigated in the pH range of 3–7. The highest concentrations of metals were released at pH 3–4.5, which encompasses the natural pH of the dust suspension (～4.3). About 40% of the total Cu was leached at pH 3, yielding 107 g/kg. Chalcanthite (CuSO₄·5H₂O), magnetite (Fe₃O₄) and delafossite (CuFeO₂) represented the principal phases of the studied dust. In contact with water, chalcanthite was dissolved and hydrated Cu sulphates precipitated at pH 4–7. Gypsum (CaSO₄·2H₂O) and secondary Fe or Al phases were observed in the leached residues. Serious environmental impact due to leaching may occur in dust-contaminated soil systems in the vicinity of the smelting plants.     

Structure and stratigraphy of the Teplá–Barrandian Neoproterozoic,Bohemian Massif: A new plate-tectonic reinterpretation

The Teplá–Barrandian unit (TBU) of the Bohemian Massif exposes a section across the once extensive Avalonian–Cadomian belt, which bordered the northern active margin of Gondwana during late Neoproterozoic. This paper synthesizes the state-of-the-art knowledge on the Cadomian basement of the TBU to redefine its principal component units, to revise an outdated stratigraphic scheme, and to interpret this scheme in terms of a recent plate-tectonic model for the Cadomian orogeny in the Bohemian Massif. The main emphasis of this paper is on an area between two newly defined fronts of the Variscan pervasive deformation to the NW and SE of the Barrandian Lower Paleozoic overlap successions. This area has escaped the pervasive Variscan (late Devonian to early Carboniferous) ductile reworking and a section through the Cadomian orogen is here superbly preserved.The NW segment of the TBU consists of three juxtaposed allochthonous belts of unknown stratigraphic relation (the Kralovice–Rakovník, Radnice–Kralupy, and Zbiroh–?árka belts), differing in lithology, complex internal strain patterns, and containing sedimentary and tectonic mélanges with blocks of diverse ocean floor (meta-)basalts. We summarize these three belts under a new term the Blovice complex, which we believe represents a part of an accretionary wedge of the Cadomian orogen.The SE segment of the TBU exposes the narrow Pi?ín belt, which is probably a continuation of the Blovice complex from beneath the Barrandian Lower Paleozoic, and a volcanic arc sequence (the Davle Group). Their stratigraphic relation is unknown. Flysch units (the ?těchovice Group and Svrchnice Formation) overlay the arc volcanics, and both units contain material derived from volcanic arc. The former was also sourced from the NW segment, whereas the latter contains an increased amount of passive margin continental material. In contrast to the Blovice complex, the flysch experienced only weak Cadomian deformation.The new lithotectonic zonation fits the following tectonic scenario for the Cadomian evolution of the TBU well. The S- to SE-directed Cadomian subduction beneath the TBU led to the involvement of turbidites, chaotic deposits, and 605 ± 39 Ma ocean floor in the accretionary wedge represented by the Blovice complex. The accretionary wedge formation mostly overlapped temporally with the growth of the volcanic arc (the Davle Group) at ~ 620–560 Ma. Upon cessation of the arc igneous activity, the rear of the wedge and some elevated portions of the arc were eroded to supply the deep-water flysch sequences of the ?těchovice Group, whereas the comparable Svrchnice Formation (~ 560 to < 544 Ma) was deposited in a southeasterly remnant basin close to the continental margin. The Cadomian orogeny in the TBU was terminated at ~ 550–540 Ma by slab breakoff, by final attachment of the most outboard ~ 540 Ma oceanic crust, and by intrusion of ~ 544–524 Ma boninite dikes marking the transition from the destructive to transform margin during the early/middle Cambrian.     

Recent plumbing system of the Krakatau volcano revealed by teleseismic earthquake distribution

Spatial and temporal analysis of global seismological data 1964–2005 reveals a distinct teleseismic earthquake activity producing a columnar-like formation in the continental wedge between the Krakatau volcano at the surface and the subducting slab of the Indo-Australian plate. These earthquakes occur continuously in time, are in the body-wave (m _b) magnitude range 4.5–5.3 and in the depth range 1–100 km. The Krakatau earthquake cluster is vertical and elongated in the azimuth N30°E, suggesting existence of a deep-rooted fault zone cutting the Sunda Strait in the SSW-NNE direction. Possible continuation of the fault zone in the SW direction was activated by an intensive 2002/2003 aftershock sequence, elongated in the azimuth of N55°E. Beneath the Krakatau earthquake cluster, an aseismic gap exists in the Wadati-Benioff zone of the subducting plate at the depths 100–120 km. We interpret this aseismic gap as a consequence of partial melting inhibiting stress concentration necessary to generate stronger earthquakes, whereas the numerous earthquakes observed in the overlying lithospheric wedge beneath the volcano probably reflect magma ascent in the recent plumbing system of the Krakatau volcano. Focal depth of the deepest events (~100 km) of the Krakatau cluster constrains the location of the primary magma generation to greater depths. The ascending magmatic fluids stress fault segments within the Sunda Strait fault zone and change their friction parameters inducing the observed tectonic earthquakes beneath Krakatau.     

Modeling rhamnolipids production by Pseudomonas aeruginosa from immiscible carbon source in a batch system

A mathematical model to predict the rhamnolipids production by Pseudomonas aeruginosa from oleic acid in a two phase liquid-liquid batch reaction system, was developed in this study. The model was based on two theoretical assumptions: 1) the convective oleic acid mass transfer is coupled to a bioreaction in the aqueous liquid bulk, and 2) the volume of the immiscible oleic acid drops and the saturation concentration at the interface are a function of rhamnolipids production. The model was able to accurately predict the experimental growth of the Pseudomonas aeruginosa strain, and the rhamnolipids production data with oleic acid as carbon source. This mathematical approach indicated a high correspondence between the saturation dimensionless profiles of oleic acid at the interface and the experimental profiles of surface tension difference. This modeling approach may constitute a useful tool in the design and scaling-up of bioreactors applied to the production of biosurfactants with immiscible carbon sources.     

Comparison of quantitative petrographic, stable isotope and cathodoluminescence data for fingerprinting Czech marbles

Various marbles from both historic quarries and historical artefacts of the Czech Republic were examined in order to make determinations of their provenance. The methodology used was based upon a combination of petrographic image analysis (PIA) of thin sections, stable isotope geochemistry of carbonates, and cathodoluminescence. Multivariate statistical methods (i.e. cluster analysis and discriminant analysis) confirmed the geoscientific relevance of the marble’s different characteristics with a high degree of consistency as well as the enhanced significance of stable C and O isotopes in correlation with the petrographic data. The qualitative cathodoluminescence data provided a useful additional tool to help recognise the fingerprinting of marbles with similar petrographic and/or geochemical characteristics.