Modelling the impact of tectonics,surface conditions and sea surface temperatures on Saharan and sub-Saharan climate evolution

Using an Atmospheric Global Circulation Model, we assess the relevance of selected atmospheric mechanisms for climate evolution of Saharan and sub-Saharan regions since the Miocene. First, we test the influence of the East-African Rift System uplift on atmospheric dynamics. Although the uplift played an important role in triggering East-African rainfall, no significant impact over central and western Africa has been detected. We also analyse the feedbacks of a giant lake on the climate of Chad basin. First results infer a negative feedback of the giant lake on the water balance, as convection is weakened by the cold water surface and as water evaporated from the lake does not feed the basin hydrological cycle. Lastly, we suggest that colder than present sea surface temperatures over the Gulf of Guinea reinforce the West-African monsoon, by enhancing the moisture advection engine via stronger thermal contrast between the ocean and the continent.     

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Some characteristics of an S-component of solar radiation identified on November 1966 eclipse at 4.28-cm wavelength

A strong S-component of solar radiation was identified during the total solar eclipse of November 12, 1966. Its characteristics, as measured at 4.28 cm, were studied in terms of flux and polarization, and its spectral features were derived by the use of data from other observatories. The whole source presented approximately the typical characteristics suggested by some authors in the last few years, and further it has been shown that it could be resolved into at least two enhanced regions, one showing unpolarized radiation with a brightness temperature T _b 1.2 × 10⁶ °K, and the other showing 50% of left-handed circularly polarized radiation, with T _b 0.7 × 10⁶ °K. The source's overall characteristics favour the presence of non-thermal absorption at the emitting regions.     

Fast and direct nonparametric procedures in the L-moment homogeneity test

Regional frequency analysis is an important tool to properly estimate hydrological characteristics at ungauged or partially gauged sites in order to prevent hydrological disasters. The delineation of homogeneous groups of sites is an important first step in order to transfer information and obtain accurate quantile estimates at the target site. The Hosking–Wallis homogeneity test is usually used to test the homogeneity of the selected sites. Despite its usefulness and good power, it presents some drawbacks including the subjective choice of a parametric distribution for the data and a poorly justified rejection threshold. The present paper addresses these drawbacks by integrating nonparametric procedures in the L-moment homogeneity test. To assess the rejection threshold, three resampling methods (permutation, bootstrap and Pólya resampling) are considered. Results indicate that permutation and bootstrap methods perform better than the parametric Hosking–Wallis test in terms of power as well as in time and procedure simplicity. A real-world case study shows that the nonparametric tests agree with the HW test concerning the homogeneity of the volume and the bivariate case while they disagree for the peak case, but that the assumptions of the HW test are not well respected.     

Assessment of the effects of hydrocarbon contamination on the sedimentary bacterial communities and determination of the polar lipid fraction purity: Relevance of intact phospholipid analysis

This in situ study reports on the relevance of intact phospholipids as new biomarkers and highlights the limits of the classical fatty acid analysis after the hydrolysis of the polar lipid fraction. The analysis of polar lipid fractions revealed significant contributions of marine macrophytes with either non-phospholipid compounds (sulfoquinovosyl diacylglycerol) or with both non-bacterial phospholipid classes (phosphatidylcholine) and non-bacterial phospholipid molecular species (some molecular species of phosphatidylglycerol). The analysis of intact phospholipids showed also the predominance of gram-negative bacteria in sediments whereas the analysis of fatty acids alone cannot confirm such information. Lastly, as regard to the effects of petroleum hydrocarbons on the sedimentary bacterial communities, we observed a higher degree of saturation of the fatty acyl chains of the phospholipids extracted from sediment exposed to a massive and chronic crude oil contamination. Such a result was interpreted as an adaptive response resulting in higher membrane rigidity of the bacterial communities.     

Forecasting ocean wave energy: The ECMWF wave model and time series methods

Recently, the technology has been developed to make wave farms commercially viable. Since electricity is perishable, utilities will be interested in forecasting ocean wave energy. The horizons involved in short-term management of power grids range from as little as a few hours to as long as several days. In selecting a method, the forecaster has a choice between physics-based models and statistical techniques. A further idea is to combine both types of models. This paper analyzes the forecasting properties of a well-known physics-based model, the European Center for Medium-Range Weather Forecasts (ECMWF) Wave Model, and two statistical techniques, time-varying parameter regressions and neural networks. Thirteen data sets at locations in the Atlantic and Pacific Oceans and the Gulf of Mexico are tested. The quantities to be predicted are the significant wave height, the wave period, and the wave energy flux. In the initial tests, the ECMWF model and the statistical models are compared directly. The statistical models do better at short horizons, producing more accurate forecasts in the 1-5 h range. The ECMWF model is superior at longer horizons. The convergence point, at which the two methods achieve comparable degrees of accuracy, is in the area of 6 h. By implication, the physics-based model captures the underlying signals at lower frequencies, while the statistical models capture relationships over shorter intervals. Further tests are run in which the forecasts from the ECMWF model are used as inputs in regressions and neural networks. The combined models yield more accurate forecasts than either one individually.     

Organo- and lithofacies of glacial-interglacial deposits in the Norwegian-Greenland Sea: Responses to paleoceanographic and paleoclimatic changes

Based on a multiparameter approach a combined litho- and organofacies concept was developed for glacial and interglacial sediment sections along an E-W transect through the central part of the Norwegian-Greenland Sea (NGS).

Modern and past surface water regimes are clearly displayed by specific litho- and organofacies patterns. Interglacial conditions reveal specific Atlantic water associated lithofacies (A and B3) in the eastern and central sector of the Norwegian-Greenland Sea (NGS). Corresponding interglacial organofacies in general are not well correlated to lithofacies due to strong diagenetic degradation of labile, e.g. autochthonous organic matter (OM). While in near-surface sediments a marine-dominated organofacies (I-1) is preserved under Atlantic water masses, this correlation is not evident for lower Holocene and Isotope Stage 5 deposits. However, during Isotopic Event 5.5.1 increased proportions of marine OM are recorded in a high accumulating core on the Vøring Plateau. Glaciomarine background lithofacies (B and C) indicate minor input of ice rafted debris (IRD) and seasonal variable sea-ice cover. Corresponding organofacies (II-1, non-oxidized and II-2, oxidized) are dominated by allochthonous OM. Most spectacular are glacial diamictons (Lithofacies E and F) evidencing short-term sediment pulses due to a sudden disintegration of far advanced tide water ice margins on the outer shelves. These diamictons bear specific organofacies (III-1 and III-2) with a clear predominance of terrigenous and reworked OM.

Some of the diamictons seem to occur contemporaneous with the so called “Heinrich-layers” H1 and H2, suggesting a common trigger-mechanism for the almost simultaneous disintegration of huge continental ice masses along the shelves of North America and the eastern margin of the NGS.

Application of a combined organo- and lithofacies concept provides essential information on spatial and temporal variations of water mass characteristics, the oceanic effects of ice sheet dynamics and circulation models.     

Colloidal Stability and Toxicity of Gold Nanoparticles and Gold Chloride on <Emphasis Type="Italic">Chlamydomonas reinhardtii</Emphasis>

Here we have examined interactions of gold nanoparticles differing in primary particle size and coating with the green algae Chlamydomonas reinhardtii as function of the colloidal stability of the particles in the experimental media used for toxicity studies. Interactions of dissolved Au³⁺ ions with algae were also examined. Included endpoints were photosynthetic yield and algal growth. Morphological and structural effects were examined microscopically and by flow cytometry. The results indicate no significant toxicity of gold nanoparticles to C. reinhardtii. Analysis of published data suggests toxicity of gold nanoparticles on algal growth to relate rather to particular coatings than to the gold core.     

Evaluation of the accuracy of the EIGEN-1S and -2 CHAMP-derived gravity field models by satellite crossover altimetry

Since the advent of CHAMP, the first in a series of low-altitude satellites being almost continuously and precisely tracked by GPS, a new generation of long-wavelength gravitational geopotential models can be derived. The accuracy evaluation of these models depends to a large extent on the comparison with external data of comparable quality. Here, two CHAMP-derived models, EIGEN-1S and EIGEN-2, are tested with independent long-term-averaged single satellite crossover (SSC) sea heights from three altimetric satellites (ERS-1, ERS-2 and Geosat). The analyses show that long-term averages of crossover residuals still are powerful data to test CHAMP gravity field models. The new models are tested in the spatial domain with the aid of ERS-1/-2 and Geosat SSCs, and in the spectral domain with latitude-lumped coefficient (LLC) corrections derived from the SSCs. The LLC corrections allow a representation of the satellite-orbit-specific error spectra per order of the models spherical harmonic coefficients. These observed LLC corrections are compared to the LLC projections from the models variance–covariance matrix. The excessively large LLC errors at order 2 found in the case of EIGEN-2 with the ERS data are discussed. The degree-dependent scaling factors for the variance-covariance matrices of EIGEN-1S and –2, applied to obtain more realistic error estimates of the solved-for coefficients, are compatible with the results found here.     

Late-Quaternary supply of terrigenous organic matter to the Congo deep-sea fan (ODP site 1075): implications for equatorial African paleoclimate

Late-Quaternary sections (about 1 Ma) from the Congo deep-sea fan (ODP Leg 175, site 1075) were used to reconstruct the terrigenous organic matter supply to the easternmost equatorial Atlantic Ocean. Variations in quantity and quality of the riverine organic matter reflect the interaction between the paleoclimatic development within the continental catchment area and the paleoceanographic conditions in the Congo river plume. To characterize the delivery of organic matter from terrigenous and marine sources, we used elemental and bulk carbon isotopic analyses, Rock-Eval pyrolysis, lignin chemistry, and organic petrology. High-amplitude fluctuations occurring about every 15-25 ka reveal a mainly precessional control on organic sedimentation. Results from Rock-Eval pyrolysis indicate a mixed kerogen type III/II, as would be anticipated in front of a major river. Fluctuations in T_max from Rock-Eval pyrolysis demonstrate pronounced cyclic changes in the delivery of low- and high-mature organic matter. Contribution of the low-mature organic fraction was strongest during warm climates supporting enhanced marine production offshore of the Congo. Organic petrological observations confirm the existence of abundant terrigenous plant tissues, both non-oxidized (vitrinite) and oxidized (inertinite). Charcoal-like organic matter (fusinite) is attributed to periods of increased bush fires in the continental hinterland, and implies more arid climatic conditions. Results from ratios of specific phenolic lignin components suggest that terrigenous organic matter in Late-Quaternary sections of site 1075 mainly derives from non-woody angiosperm tissue, i.e., grasses and leaves. Correlation between the amount of specific lignin phenols and the bulk '¹³C_org signature fosters the conclusion that an appreciable amount of the terrigenous organic fraction derives from C4 plant matter. This may cause an underestimation of the terrigenous proportion of bulk organic matter when assessments are based on bulk carbon isotopic signatures alone.