Estimation of optical properties of arctic haze using a numerical model

Abstract

The optical parameters of Arctic haze, such as the scattering and the absorption coefficients and the asymmetry factor, have been estimated using a theoretical haze model. The Aden and Kerker solution for spherical nuclei coated with a spherical shell was employed to account for the observed sulphuric acid coating on Arctic aerosols. Six original aerosol materials are considered; four are natural and two are anthropogenic in origin (sulphuric acid and soot). The relative humidity is varied between 0 and 99% and the effects of anthropogenic substances are examined. Carbonaceous material can increase the absorption coefficient by up to a factor 5 in the visible range, while sulphuric acid significantly increases the growth of particles and affects all of the optical parameters. The haze model is found to be consistent with available measurements of aerosol characteristics and optical parameters. The haze model is then used to convert a vertical profile of the extinction coefficient to a profile of particle concentration.     

Metamorphosed calcium‐aluminum‐rich inclusions in CK carbonaceous chondrites

CK chondrites are the only group of carbonaceous chondrites with petrologic types ranging from 3 to 6. Although CKs are described as calcium‐aluminum‐rich inclusion (CAI)‐poor objects, the abundance of CAIs in the 18 CK3–6 we analyzed ranges from zero to approximately 16.4%. During thermal metamorphism, some of the fine‐grained CAIs recrystallized as irregular assemblages of plagioclase + Ca‐rich pyroxene ± olivine ± Ca‐poor pyroxene ± magnetite. Coarse‐grained CAIs display zoned spinel, fassaite destabilization, and secondary grossular and spinel. Secondary anorthite, grossular, Ca‐rich pyroxene, and spinel derive from the destabilization of melilite, which is lacking in all CAIs investigated. The Al‐Mg isotopic systematics measured in fine‐ and coarse‐grained CAIs from Tanezrouft (Tnz) 057 was affected by Mg redistribution. The partial equilibration of Al‐Mg isotopic signatures obtained in the core of a coarse‐grained CAI (CG1‐CAI) in Tnz 057 may indicate a lower peak temperature for Mg diffusion of approximately 540–580 °C, while grossular present in the core of this CAI indicates a higher temperature of around 800 °C for the metamorphic event on the parent body of Tnz 057. Excluding metamorphic features, the similarity in nature and abundance of CAIs in CK and CV chondrites confirms that CVs and CKs form a continuous metamorphic series from type 3 to 6.     

Is a regional flood signal reproducible from lake sediments?

The evolution of flood activity with global warming remains uncertain. To better assess flood–climate relationships, lake sediments are increasingly being investigated because they could provide regional flood histories long enough to cover past climate changes. However, site‐specific sedimentary processes may bias flood reconstructions. The aim of this article is to investigate these effects through the reconstruction of two distinct flood records from independent, neighbouring sedimentary basins of the same lake (Lake Allos in the Mediterranean French Alps), i.e. under the same climate conditions. Understanding of sedimentary processes is crucial in order to adapt the sampling strategy and the flood‐intensity proxy to each sedimentary system and, thereby, reconstruct a complete and reliable flood history. Thanks to this detailed approach, the main trends of the regional flood variability can be reproduced; i.e. periods of high flood‐frequency, ranges of flood‐frequency values and timing of the most intense events. In detail, some differences appeared associated to the various stream capacities to erode and transport flood sediments to the lake system, implying variable sensitivity of sedimentary systems in recording floods. Comparing regional flood records based on independent sedimentary systems from similar environments could thus be a complementary approach to assessing past flood intensity. Such an approach could open particularly interesting perspectives because reconstructing the long‐term evolution of flood intensity is a key challenge in the geosciences.     

Rhythmic pelagic successions and terrestrial orbital variations. The example of the Lower Cretaceous from Angles (SE France)

An harmonic analysis of limestone bed and marl interbed thicknesses of pelagic Berriasian-Barremian interval from the Angles area (SE France) shows that marly parts of the succession contain frequencies significantly different from calcareous ones. Some of the resulting periods are in the Milankovitch frequency band but many others are different from those predicted by the orbital theory.     

Propagating error in land-cover-change analyses: impact of temporal dependence under increased thematic complexity

We examined the impact of temporal dependence between patterns of error in classified time-series imagery through a simulation modeling approach. This research extended the land-cover-change simulation model we previously developed to investigate: (1) the assumption of temporal independence between patterns of error in classified time-series imagery; and (2) the interaction of patterns of change and patterns of error in a post-classification change analysis. In this research, the thematic complexity of the classified land-cover maps was increased by increasing the number of simulated land-cover classes. Simulating maps with increased categorical resolution permitted the incorporation of: (1) higher-order, more complex spatial and temporal interactions between land-cover classes; and (2) patterns of error that better reproduce the complex error interactions that often occur in time-series classified imagery. The overall modeling framework was divided into two primary components: (1) generation of a map representing true change; and (2) generation of a suite of change maps that had been perturbed by specific patterns of error. All component maps in the model were produced using simulated annealing, which enabled us to create a series of map realizations with user-defined spatial and temporal patterns. Comparing the true map of change to the error-perturbed maps of change using accuracy assessment statistics showed that increasing the temporal dependence between classification errors did not improve the accuracy of resulting maps of change when the categorical scale of the land-cover classified maps was increased. The increased structural complexity within the time series of maps effectively inhibited the impact of temporal dependence. However, results demonstrated that there are interactions between patterns of error and patterns of change in a post-classification change analysis. These interactions played a major role in determining the accuracy associated with the maps of change.