Search for effects of comet S-L 9 fragment impacts on low radio frequency emission from Jupiter

Decametric radio observations of Jupiter were made before, during, and after the impacts of the fragments of the comet S-L 9 with the planet, from the University of Florida Radio Observatory, the Maipu Radio Astronomy Observatory of the University of Chile, and the Owens Valley Radio Observatory of the California Institute of Technology. The decametric radiation was monitored at frequencies from 16.7 to 32 MHz. The minimum detectable flux densities were on the order of 30 kJy, except for that of the large 26.3 MHz array in Florida, which was about 1 kJy. There was no significant enhancement or suppression of the decametric L-burst or S-burst emission with respect to normal activity patterns that might be attributed to the fragment entries. However, a burst of left-hand elliptically polarized radiation having a considerably longer duration than an L-burst was observed almost simultaneously with the impact of the large fragment Q2, and another with right-hand elliptical polarization was observed simultaneously with Q1. We consider the possibility that these two bursts were emitted just above the local electron cyclotron frequencies from the southern and northern ends, respectively, of magnetic flux tubes that had been excited in some way by the proximity of fragments Q2 and Q1.In addition to the monitoring of the decametric radiation, a search was conducted for possible comet-enhanced Jovian synchrotron radiation at 45 MHz using a large dipole antenna array at the observatory in Chile. This frequency is above the cutoff of the decametric radiation, but is considerably below the lowest frequency at which the synchrotron emission has previously been detected. The minimum detectable flux density with the 45 MHz antenna was about 5 Jy. No synchrotron emission at all was found before, during, or after the entry of the comet fragments.     

Twentieth century north atlantic climate change. Part I: assessing determinism

Boreal winter North Atlantic climate change since 1950 is well described by a trend in the leading spatial structure of variability, known as the North Atlantic Oscillation (NAO). Through diagnoses of ensembles of atmospheric general circulation model (AGCM) experiments, we demonstrate that this climate change is a response to the temporal history of sea surface temperatures (SSTs). Specifically, 58 of 67 multi-model ensemble members (87%), forced with observed global SSTs since 1950, simulate a positive trend in a winter index of the NAO, and the spatial pattern of the multi-model ensemble mean trend agrees with that observed. An ensemble of AGCM simulations with only tropical SST forcing further suggests that variations in these SSTs are of primary importance. The probability distribution function (PDF) of 50-year NAO index trends from the forced simulations are, moreover, appreciably different from the PDF of a control simulation with no interannual SST variability, although chaotic atmospheric variations are shown to yield substantial 50-year trends. Our results thus advance the view that the observed linear trend in the winter NAO index is a combination of a strong tropically forced signal and an appreciable noise component of the same phase. The changes in tropical rainfall of greatest relevance include increased rainfall over the equatorial Indian Ocean, a change that has likely occurred in nature and is physically consistent with the observed, significant warming trend of the underlying sea surface.     

Theoretical studies on metal thioarsenites and thioantimonides: synergistic interactions between transition metals and heavy metalloids

Recently we established that the ternary complex, CuAsS(SH)(OH) has an unusually high stability and makes a large contribution to the total concentrations of both Cu and As in sulfidic solutions equilibrated with Cu and As sulfide minerals. This ternary complex has an unusual structure, containing a bond which is formally Cu(I)–As(III), along with a broken As–S bond. We have now found that complexes with similar structures exist for Au⁺ and Tl⁺ coordinated to AsS(SH)(OH)^-. However, such a direct metal–metalloid bond is not a requirement for stability. In fact, TlAsS(SH)(OH) is unstable while AuAsS(SH)(OH) is highly stable (compared to the aquo ion). Zn²⁺, Cd²⁺, Hg²⁺ and Pb²⁺ also form bonds to the As of AsS(SH)(OH), but without breaking any As–S bonds, and HgAsS(SH)(OH)⁺ and PbAsS(SH)(OH)⁺ are particularly stable complexes. Calculated structures are shown for these complexes, gas-phase energies are calculated, and formation constants in aqueous solution are estimated. The SbS(SH)(OH)^- ion forms analogous complexes, with similar stabilities. However, the Au⁺ complex of SbS(SH)(OH)^- is slightly less stable than the Cu⁺ complex, opposite to the order found for the AsS(SH)(OH)^- ligand. The Au⁺ and AuSH complexes of AsSSHOH^- or AsS(SH)₂ ^- may be implicated in "invisible gold" in arsenian pyrites. Vibrational frequencies are given for the AuAsS(SH)₃ ^- complex and the XANES energies of this complex and Au(SH)₂ ^- are compared. The existence of such strong complexes may explain the many correlations observed between the concentrations of coinage metals and metalloids.     

The self-organization of step-pools in mountain streams

Spontaneous, autogenic self-organization has been described in numerous geomorphic systems, but it has not been investigated in detail with respect to coarse bedforms in general or step-pools in particular. In this paper, we review the spatial organization of step-pool systems and present example evidence of step-pool development as an autogenic self-organization process. We then outline the mathematical language for defining spatially divergent self-organization and test these ideas using two unique field examples from Oregon (Andrews Experimental Forest) and California (Baxter Creek), where step-pools developed from planar beds in artificially manipulated channels. Results show that step-pool development is consistent with a spatially divergent self-organization phenomenon. Entropy increases as initially undifferentiated planar channels diverge into steps and pools, then declines when a series of steps and pools of consistent size and spacing is established, signifying stability in the system. The self-organization process is accompanied by increasing flow resistance and decreasing slope (through increasing the “vertical sinuosity” of the step-pool profile and creation of low- or negative gradient pool areas), suggesting a minimization of stream power. The self-adjustment of the step-pool bed profile over time represents another manifestation of a general process that results in rhythmic patterns on the surface of Earth.     

The perfect landscape

The “perfect storm” metaphor describes the improbable coincidence of several different forces or factors to produce an unusual outcome. The perfect landscape is conceptualized as a result of the combined, interacting effects of multiple environmental controls and forcings to produce an outcome that is highly improbable, in the sense of the likelihood of duplication at any other place or time. Geomorphic systems have multiple environmental controls and forcings, and degrees of freedom in responding to them. This allows for many possible landscapes and system states. Further, some controls and forcings are causally contingent. These contingencies are specific to time and place. Dynamical instability in many geomorphic systems creates and enhances some of this contingency by causing the effects of minor initial variations and small disturbances to persist, and grow disproportionately large, over time. The joint probability of any particular set of global controls is low, as the individual probabilities are < 1, and the probability of any set of local, contingent controls is even lower. Thus, the probability of existence of any landscape or earth surface system state at a particular place and time is negligibly small: all landscapes are perfect. Recognition of the perfection of landscapes leads away from a worldview holding that landforms and landscapes are the inevitable outcomes of deterministic laws, such that only one outcome is possible for a given set of laws and initial conditions. A perfect landscape perspective leads toward a worldview that landforms and landscapes are circumstantial, contingent results of deterministic laws operating in a specific environmental context, such that multiple outcomes are possible.     

Differential productions of rural gentrification: illustrations from North and South Norfolk

This paper focuses attention on the making of space for rural gentrification, both discursively and materially. The paper emphasises the differential constructions of gentrification within urban and rural studies. Connections are drawn between production-side theories of gentrification, notions of the ‘post-productivist countryside’ and studies that have related rural demographic change and gentrification with planning and property relations. Drawing on these three sets of ideas, the paper explores gentrification in rural Norfolk. It is argued that the contemporary geography of rural gentrification may in part reflect historic structures of landownership as well as settlement classifications associated with the land-use planning system. Country and District level analysis is followed up by detailed study of gentrification of two villages in Norfolk, which highlights how gentrified rural spaces may be produced in rather different way and through different agencies, and as a result takes different forms.     

Rates of oxygen exchange between the Al2O8Al28(OH)56(H2O)26(aq) (Al30) molecule and aqueous solution

Rates of steady exchange of oxygens between bulk solution and the largest known aluminum polyoxocation: Al₂O₈Al₂₈(OH)₅₆(H₂O)₂₆¹⁸⁺(aq) (Al₃₀) are reported at pH≈4.7 and 32-40°C. The Al₃₀ molecule is a useful model for geochemists because it is ≈2 nm in length, comparable to the smallest colloidal solids, and it has structural complexity greater than the surfaces of most aluminum (hydr)oxide minerals. The Al₃₀ molecule has 15 distinct hydroxyl sites and eight symmetrically distinct bound waters. Among the hydroxyl bridges are two sets of μ₃-OH, which are not present in any of the other aluminum polyoxocations that have yet been studied by NMR methods. Rates of isotopic equilibration of the μ₂-OH and μ₃-OH hydroxyls and bound water molecules fall within the same range as we have determined for other aluminum solutes, although it is impossible to determine rate laws for exchange at the large number of individual oxygen sites. After injection of ¹⁷O-enriched water, growth of the ¹⁷O-NMR peak near 37 ppm, which is assigned to μ₂-OH and μ₃-OH hydroxyl bridges, indicates that these bridges equilibrate within two weeks at temperatures near 35°C. The peak at +22 ppm in the ¹⁷O-NMR spectra, assigned to bound water molecules (η-OH₂), varies in width with temperature in a similar fashion as for other aluminum solutes, suggesting that most of the η-OH₂ sites exchange with bulk solution at rates that fall within the range observed for other aluminum complexes. Signal from one anomalous group of four η-OH₂ sites is not observed, indicating that these sites exchange at least a factor of ten more rapidly than the other η-OH₂ sites on the Al₃₀.