Constraints on the structure and dynamics of the β-cristobalite polymorphs of SiO2 and AlPO4 from 31P, 27Al and 29Si NMR spectroscopy to 770 K

Nuclear magnetic resonance spectroscopic data are presented for the cristobalite polymorphs of AlPO₄ and SiO₂ from RT to 770 K, through their respective α-β transitions. The nuclear magnetic resonance (NMR) data include chemical shifts for ³¹P, ²⁷Al, and ²⁹Si, ²⁷Al quadrupole coupling parameters, and ³¹P and ²⁷Al spin-lattice relaxation rates. Also presented are electron diffraction patterns of β-cristobalite AlPO₄ that show diffuse scattering similar to that reported previously for SiO₂. For the α-phases of both AlPO₄ and SiO₂, the chemical shifts decrease approximately linearly with increasing temperature from RT to T_c and discontinuously by -2 to -3 ppm from α to β. This result is consistent with a small, continuous increase in the mean T-O-T angle (〈θ〉) of the α-phases with increasing T and an increase of 〈θ〉 by about 4° across the α-β transition for both cristobalite and its AlPO₄ analogue. Based on the ²⁹Si chemical shifts, the mean Si-O-Si angle for β-cristobalite is 152.7±1° near T_c. For AlPO₄-cristobalite, the ²⁷Al nuclear quadrupole coupling constant (C_Q) decreases approximately linearly from 1.2 MHz at RT to 0.94 MHz near T_c (493±10 K). At the α-β transition the ²⁷Al C_Q approaches zero, in agreement with the cubic average structure observed by diffraction. The satellite transitions retain a small frequency distribution above the α-β transition from electric field gradients attributed to defects. The short-range cubic symmetry of the Al-site and non-linear Al-O-P angle support a dynamically disordered model of the β-cristobalite structure. Complete averaging of the ²⁷Al quadrupole coupling in the β-phase indicates that the lifetime of any short-range ordered domains must be shorter than about 1 μs.     

The impact of horizontal resolution on moist processes in the ECMWF model

Summer and winter climates simulated with the ECMWF (cycle 33) model at spectral scales T21, T42, T63 and T106 are analyzed to determine the impact of changes in horizontal resolution on atmospheric water vapor, clouds, convection, and precipitation. Qualitative changes in many moist processes occur in the transition from T21 to T42, especially in the tropics; at higher resolutions mostly incremental variations from patterns established at T42 result. Large-scale tropical moist processes are simulated more realistically at T21 than at finer resolutions, possibly reflecting a mismatch between the finer-scale dynamics and the scales at which the underlying assumptions of the physical parameterizations apply. Global precipitation increases monotonically with resolution, as a consequence of increasing convection. Global cloud cover, however, decreases in the transition from T21 to T42 due to drying of the tropics, but then increases slightly at finer resolutions. These small global increases are an outcome of compensating changes in different regions: decreases in cloud cover due to drying of the atmosphere at low latitudes are offset by high-latitude increases resulting from enhanced relative humidity associated with an intensifying atmospheric cold bias at finer resolutions.     

Geography fieldwork in a 'risk society'

The recent decline in fieldwork provision in UK schools has partly been attributed to false perceptions of risk among teachers. This paper examines a case study based on geography teachers' perceptions from six state secondary schools in a northern English city. The research shows that owing to the inherent subjectivity of risk perception, these teachers' perceptions of fieldwork risk cannot be dismissed as false. Furthermore, it is argued that owing to the implicit, but powerful, spatialities of teachers' imaginations of fieldwork, these teachers will first need to re-evaluate the role and value of fieldwork before they are willing to re-enter the field.     

'Black skins–white masks': Postcolonial reflections on 'race', gender and second generation return migration to the Caribbean

This paper illustrates the opportunities afforded by the adoption of postcolonial discourse in development geography, drawing specifically on issues of transnationalism, hybridity and inbetweeness. The utility of such notions and associated approaches is illustrated by the authors' current research on the migration of young, second generation and foreign-born 'Bajan-Brits' to the small Caribbean island nation of Barbados, the homeland of their parents. Focussing on issues of 'race' and gender, the paper examines the experiences of return migration among this cohort from an interpretative perspective framed within postcolonial discourse. It argues that notwithstanding the considerable sociocultural problems of adjustment encountered, these Bajan-Brit 'returnees' may be seen as occupying positions of relative economic privilege. Theirs is a liminal space derived by virtue of having been born and/or raised in the UK and being of the black 'race'. Accordingly, they are demonstrated to be both advantaged and disadvantaged; both transnational and national; and black but, in some senses, symbolically white.     

Weathering Pits as Indicators of the Relative Age of Granite Surfaces in the Cairngorm Mountains, Scotland

Weathering pits 1–140 cm deep occur on granite surfaces in the Cairngorms associated with a range of landforms, including tors, glacially exposed slabs, large erratics and blockfields. Pit depth is positively correlated with cosmogenic exposure age, and both measures show consistent relationships on individual rock landforms. Rates of pit deepening are non‐linear and a best fit is provided by the sigmoidal function D = b1 + exp(b2+b3/t). The deepest pits occur on unmodified tor summits, where ¹⁰Be exposure ages indicate that surfaces have been exposed to weathering for a minimum of 52–297 ka. Glacially exposed surfaces with pits 10–46 cm deep have given ¹⁰Be exposure durations of 21–79 ka, indicating exposure by glacial erosion before the last glacial cycle. The combination of cosmogenic exposure ages with weathering pit depths greatly extends the area over which inferences can be made regarding the ages of granite surfaces in the Cairngorms. Well‐developed weathering pits on glacially exposed surfaces in other granite areas are potential indicators of glacial erosion before the Last Glacial Maximum.     

Perfection and complexity in the lower Brazos River

The “perfect landscape” concept is based on the notion that any specific geomorphic system represents the combined, interacting effects of a set of generally applicable global laws and a set of geographically and historically contingent local controls. Because the joint probability of any specific combination of local and global controls is low, and the local controls are inherently idiosyncratic, the probability of existence of any given landscape is vanishingly small. A perfect landscape approach to geomorphic complexity views landscapes as circumstantial, contingent outcomes of deterministic laws operating in a specific environmental and historical context. Thus, explaining evolution of complex landscapes requires the integration of global and local approaches. Because perfection in this sense is the most important and pervasive form of complexity, the study of geomorphic complexity is not restricted to nonlinear dynamics, self-organization, or any other aspects of complexity theory. Beyond what can be achieved via complexity theory, the details of historical and geographic contexts must be addressed. One way to approach this is via synoptic analyses, where the relevant global laws are applied in specific situational contexts. A study of non-acute tributary junctions in the lower Brazos River, Texas illustrates this strategy. The application of generalizations about tributary junction angles, and of relevant theories, does not explain the unexpectedly high occurrence or the specific instances of barbed or straight junctions in the study area. At least five different causes for the development of straight or obtuse junction angles are evident in the lower Brazos. The dominant mechanism, however, is associated with river bank erosion and lateral channel migration which encroaches on upstream-oriented reaches of meandering tributaries. Because the tributaries are generally strongly incised in response to Holocene incision of the Brazos, the junctions are not readily reoriented to the expected acute angle. The findings are interpreted in the context of nonlinear divergent evolution, geographical and historical contingency, synoptic frameworks for generalizing results, and applicability of the dominant processes concept in geomorphology.     

Gas segregation in dykes and sills

Many basaltic volcanoes emit a substantial amount of gas over long periods of time while erupting relatively little degassed lava, implying that gas segregation must have occurred in the magmatic system. The geometry and degree of connectivity of the plumbing system of a volcano control the movement of magma in that system and could therefore provide an important control on gas segregation in basaltic magmas. We investigate gas segregation by means of analogue experiments and analytical modelling in a simple geometry consisting of a vertical conduit connected to a horizontal intrusion. In the experiments, degassing is simulated by electrolysis, producing micrometric bubbles in viscous mixtures of water and golden syrup. The presence of exsolved bubbles induces a buoyancy-driven exchange flow between the conduit and the intrusion that leads to gas segregation. Bubbles segregate from the fluid by rising and accumulating as foam at the top of the intrusion, coupled with the accumulation of denser degassed fluid at the base of the intrusion. Steady-state influx of bubbly fluid from the conduit into the intrusion is balanced by outward flux of lighter foam and denser degassed fluid. The length and time scales of this gas segregation are controlled by the rise of bubbles in the horizontal intrusion. Comparison of the gas segregation time scale with that of the cooling and solidification of the intrusion suggests that gas segregation is more efficient in sills (intrusions in a horizontal plane with typical width:length aspect ratio 1:100) than in horizontally-propagating dykes (intrusions in a vertical plane with typical aspect ratio 1:1000), and that this process could be efficient in intermediate as well as basaltic magmas. Our investigation shows that non-vertical elements of the plumbing systems act as strong gas segregators. Gas segregation has also implications for the generation of gas-rich and gas-poor magmas at persistently active basaltic volcanoes. For low magma supply rates, very efficient gas segregation is expected, which induces episodic degassing activity that erupts relatively gas-poor magmas. For higher magma supply rates, gas segregation is expected to be less effective, which leads to stronger explosions that erupt gas-rich as well as gas-poor magmas. These general physical principles can be applied to Stromboli volcano and are shown to be consistent with independent field data. Gas segregation at Stromboli is thought likely to occur in a shallow reservoir of sill-like geometry at 3.5 km depth with exsolved gas bubbles 0.1–1 mm in diameter. Transition between eruptions of gas-poor, high crystallinity magmas and violent explosions that erupt gas-rich, low crystallinity magmas are calculated to occur at a critical magma supply rate of 0.1–1 m³ s^− 1.     

Residence time of alluvium in an aggrading fluvial system

Relationships between the surface area and age of alluvial deposits were used to estimate the residence time of alluvium in the 2205 km² Waipaoa River basin, New Zealand. The contemporary Waipaoa River is an efficient transporter of sediment to the continental shelf, but the basin has been characterized by rapid channel and valley aggradation in the historic period, and by extensive mid‐ to late Holocene alluvial storage in the lower reaches. The area‐weighted mean age of alluvial deposits in the lower part of the river basin is ～4400 yr. These deposits comprise terrace remnants isolated by downcutting, and Holocene to Recent sediments that are potentially remobilizable by the modern river. Even though the amount of storage is small relative to downstream transport, the majority of the potentially remobilizable alluvium is likely to remain in storage for >100 yr, and its half‐life (time for 50 per cent removal) is >2000 yr. Within the confines of the flfloodplain, the apparent ‘loss’ of older deposits is due primarily to burial, but losses of the most recent deposits are due almost entirely to remobilization (30–40 per cent), with the remainder preserved in the alluvial record for at least 10⁴ yr. Most of this sediment is likely to remain in storage until there is a shift to a degradational state. Copyright © 2006 John Wiley & Sons, Ltd.     

Hydrologic control of waveforms on small meandering rivers

Small river channels within the Humber Basin of Southern Ontario exhibit irregular meandering patterns; however, contemporary river hydrology appears capable of controlling the scale of regular waveform development. Recent changes in river planform are assessed through a bi‐temporal comparison of channel planform using orthorectified aerial photography and statistical analysis of curvature series based on autocorrelation and spectral analysis. Calculated meander wavelengths are acceptable given traditional relationships between wavelength and mean annual flood discharge. It is also evident that changes in stream power are highly correlated with changes in the dominant wavelengths between channel reaches in this study. Gradual development of small scale waveforms following a rare hydrological and geomorphological event in 1954 further confirms that these forms can be attributed to the typical discharge regime. This paper argues that the scaling of wavelengths with discharge can be considered a strong factor controlling planform evolution on some small meandering river systems, despite manifest irregular planforms. Copyright © 2007 John Wiley & Sons, Ltd.