A review of pollutants in the sea-surface microlayer (SML): a unique habitat for marine organisms

Boundary layers between different environmental compartments represent critical interfaces for biological, chemical and physical processes. The sea-surface microlayer (uppermost 1-1000 microm layer) forms the boundary layer interface between the atmosphere and ocean. Environmental processes are controlled by the SML, and it is known to play a key role in the global distribution of anthropogenic pollutants. Due to its unique chemical composition, the upper organic film of the SML represents both a sink and a source for a range of pollutants including chlorinated hydrocarbons, organotin compounds, petroleum hydrocarbons, polycyclic aromatic hydrocarbons (PAH) and heavy metals. These pollutants can be enriched in the SML by up to 500 times relative to concentrations occurring in the underlying bulk water column. The SML is also a unique ecosystem, serving as an important habitat for fish eggs and larvae. Concentration ranges and enrichment factors of pollutants in the SML in different areas of the world's oceans have been critically reviewed, together with available toxicity data for marine biota found within the SML. Overall, the SML is highly contaminated in many urban and industrialized areas of the world, resulting in severe ecotoxicological impacts. Such impacts may lead to drastic effects on the marine food web and to fishery recruitment in coastal waters. Studies of the toxicity of fish eggs and larvae exposed to the SML contaminants have shown that the SML in polluted areas leads to significantly higher rates of mortality and abnormality of fish embryos and larvae.     

The effect of horizontal resolution on simulation of very extreme US precipitation events in a global atmosphere model

We investigate the ability of a global atmospheric general circulation model (AGCM) to reproduce observed 20 year return values of the annual maximum daily precipitation totals over the continental United States as a function of horizontal resolution. We find that at the high resolutions enabled by contemporary supercomputers, the AGCM can produce values of comparable magnitude to high quality observations. However, at the resolutions typical of the coupled general circulation models used in the Fourth Assessment Report of the Intergovernmental Panel on Climate Change, the precipitation return values are severely underestimated.     

Scaling of tropical rainfall as observed by TRMM precipitation radar

We used a three-year (1998–2000) dataset of TRMM Precipitation Radar observations to investigate the scaling properties of spatial rainfall fields. This dataset allows consideration of spatial scales ranging from about 4.3 km to 138 km and short temporal scales corresponding to the sensor overpasses. The focus is on the marginal spatial moment scaling, which allows estimation of the scaling parameters from a single scene of data. Here we present a global perspective of the scaling properties of tropical rainfall in terms of its spatial variability, atmospheric forcing, predictability, and applicability. Our results reveal the following: 1) the scaling parameters exhibit strong variability associated with land/ocean contrast and mean precipitation at the synoptic scale; 2) there exists a one-to-one relationship between the scaling parameters and the large-scale spatial average rain rate of a universal functional form; 3) the majority of the scenes are consistent with the hypothesis of scale invariance at the moment orders of 0 and 2; 4) relatively there are more scale-invariant rain scenes over land than over ocean; and 5) for the scenes that are non-scale-invariant, deviation from scale-invariance mainly arises from the increasingly intermittent behavior of rainfall as spatial scale decreases. These results have important implications for the development and calibration of downscaling procedures designed to reproduce rainfall properties at different spatial scales and lead to a better understanding of the nature of tropical rainfall at various spatial resolutions.     

Carbon catalysed hydrogen exchange in petroleum source rocks

Exchange of carbon bound hydrogen has been observed when alkenes, saturated and aromatic hydrocarbons are heated at moderate temperatures on carbonaceous surfaces (activated carbon and coal). Isomerisation of alkenes and the formation of hydrogenated/dehydrogenated products from the saturated and aromatic reactants resulted. A suite of crude oils from the Carnarvon Basin (Western Australia) have been analysed with a view to comparing their relative abundances of structurally similar hydrocarbons. The consistent relationships between hydrocarbons in crude oils that are chemically related via hydrogenation/dehydrogenation reactions suggest that a hydrogen exchange process similar to that demonstrated in laboratory experiments occurs during crude oil formation in sedimentary rocks.     

BIFoR FACE: Water–soil–vegetation–atmosphere data from a temperate deciduous forest catchment,including under elevated CO2

The ecosystem services provided by forests modulate runoff generation processes, nutrient cycling and water and energy exchange between soils, vegetation and atmosphere. Increasing atmospheric CO₂ affects many linked aspects of forest and catchment function in ways we do not adequately understand. Global levels of atmospheric CO₂ will be around 40% higher in 2050 than current levels, yet estimates of how water and solute fluxes in forested catchments will respond to increased CO₂ are highly uncertain. The Free Air CO₂ Enrichment (FACE) facility of the University of Birmingham's Institute of Forest Research (BIFoR) is the only FACE in mature deciduous forest. The site specializes in fundamental studies of the response of whole ecosystem patches of mature, deciduous, temperate woodland to elevated CO₂ (eCO₂). Here, we describe a dataset of hydrological parameters – seven weather parameters at each of three heights and four locations, shallow soil moisture and temperature, stream hydrology and CO₂ enrichment – retrieved at high frequency from the BIFoR FACE catchment.     

XUV Photometer System (XPS): Improved Solar Irradiance Algorithm Using CHIANTI Spectral Models

Solar soft X-ray (XUV) radiation is highly variable on all time scales and strongly affects Earth’s ionosphere and upper atmosphere; consequently, the solar XUV irradiance is important for atmospheric studies and for space weather applications. Although there have been several recent measurements of the solar XUV irradiance, detailed understanding of the solar XUV irradiance, especially its variability during flares, has been hampered by the broad bands measured in the XUV range. In particular, the simple conversion of the XUV photometer signal into irradiance, in which a static solar spectrum is assumed, overestimates the flare variations by more than a factor of two as compared to the atmospheric response to the flares. To address this deficiency in the simple conversion, an improved algorithm using CHIANTI spectral models has been developed to process the XUV Photometer System (XPS) measurements with its broadband photometers. Model spectra representative of quiet Sun, active region, and flares are combined to match the signals from the XPS and produce spectra from 0.1 to 40 nm in 0.1-nm intervals for the XPS Level 4 data product. The two XPS instruments are aboard NASA’s Solar Radiation and Climate Experiment (SORCE) and Thermosphere, Ionosphere, Mesosphere, Energetics, and Dynamics (TIMED) satellites. In addition, the XPS responsivities have been updated for the latest XPS data processing version. The new XPS results are consistent with daily variations from the previous simple conversion technique used for XPS and are also consistent with spectral measurements made at wavelengths longer than 27 nm. Most importantly, the XPS flare variations are reduced by factors of 2 – 4 at wavelengths shorter than 14 nm and are more consistent, for the first time, with atmospheric response to solar flares. Along with the details of the new XPS algorithm, several comparisons to dayglow and photoelectron measurements and model results are also presented to help verify the accuracy of the new XUV irradiance spectra.     

Deep crustal structure and rheology of the Gascoyne volcanic margin,western Australia

Interpretation of deep seismic reflection data across the Gascoyne Margin reveals six distinct seismic facies units related to the tectono-magmatic breakup history. On the outer Exmouth Plateau four large scale units are identified: (1) an extensively block-faulted upper crust; (2) a middle-crustal unit of discontinuous, undulatory reflectors; (3) a reflection-free deep crustal unit; and (4) a lower-crustal band of low-frequency, high-amplitude reflectors. Two additional units are found near the continent-ocean boundary (COB); (5) seaward-dipping reflectors (SDR); and (6) landward-dipping reflectors in the lower crust below the SDR. The lower-crustal high-reflectivity band, located near the top of a high-velocity unit (V_p > 7 kms^–1), is interpreted as magmatic underplating. There is a spatial correlation between the underplated area and the presence of extensive upper-crustal block-faulting and intrusive rocks in the shallow crust. The undulatory middle-crustal reflector unit is also only identified in the outer plateau area, and is interpreted as a zone in which the upper-crustal faults terminate. The inner parts of the margin consist of a deep basin showing little upper-crustal faulting and no evidence of middle crustal deformation or underplating. Theoretical modeling of the effect of rifting and magmatic underplating on crustal strength profiles suggests that the brittle-ductile transition may migrate at least 5 km upwards during several million years after the underplating event. Based on the seismic interpretation and crustal strength modeling we propose that the seismic structure of the outer Exmouth Plateau is severely modified by a transient change in the crustal rheological structure associated with magmatic underplating.     

Water temperature dynamics in High Arctic river basins

Despite the high sensitivity of polar regions to climate change and the strong influence of temperature upon ecosystem processes, contemporary understanding of water temperature dynamics in Arctic river systems is limited. This research gap was addressed by exploring high‐resolution water column thermal regimes for glacier‐fed and non‐glacial rivers at eight sites across Svalbard during the 2010 melt season. Mean water column temperatures in glacier‐fed rivers (0.3–3.2 °C) were lowest and least variable near the glacier terminus but increased downstream (0.7–2.3 °C km^–1). Non‐glacial rivers, where discharge was sourced primarily from snowmelt runoff, were warmer (mean: 2.9–5.7 °C) and more variable, indicating increased water residence times in shallow alluvial zones and increased potential for atmospheric influence. Mean summer water temperature and the magnitude of daily thermal variation were similar to those of some Alaskan Arctic rivers but low at all sites when compared with alpine glacierized environments at lower latitudes. Thermal regimes were correlated strongly (p < 0.01) with incoming short‐wave radiation, air temperature, and river discharge. Principal drivers of thermal variability were inferred to be (i) water source (i.e. glacier melt, snowmelt, groundwater); (ii) exposure time to the atmosphere; (iii) prevailing meteorological conditions; (iv) river discharge; (v) runoff interaction with permafrost and buried ice; and (vi) basin‐specific geomorphological features (e.g. channel morphology). These results provide insight into the potential changes in high‐latitude river systems in the context of projected warming in polar regions. We hypothesize that warmer and more variable temperature regimes may prevail in the future as the proportion of bulk discharge sourced from glacial meltwater declines and rivers undergo a progressive shift towards snow water and groundwater sources. Importantly, such changes could have implications for aquatic species diversity and abundance and influence rates of ecosystem functioning in high‐latitude river systems. Copyright © 2012 John Wiley & Sons, Ltd.     

Hurricane effects on subtropical pine rocklands of the Florida Keys

We investigate the effects of Hurricane Wilma??s storm surge (23?C24 October 2005) on the dominant tree Pinus elliottii var densa (South Florida slash pine) and rare plant species in subtropical pine rocklands of the Lower Florida Keys. We examine the role of elevation on species abundance in 1995 (Hurricane Betsy in 1965), 2005 (Hurricane Georges in 1998), and 2008 (Hurricane Wilma in 2005) to investigate if hurricanes influence abundance by eliminating plants at lower elevation on Big Pine Key, the largest island in the Lower Florida Keys. We compare densities before and after Hurricane Wilma over the 2005?C2008 sampling period and examine the role of elevation on changes in pine and rare species densities three years after Hurricane Wilma. We use elevation to assess the impact of hurricanes because elevation determined whether a location was influenced by storm surge (maximum surge of 2 m) in the Lower Florida Keys, where pine rocklands occur at a maximum elevation of 3 m. In 1995 (30 years after a major storm), elevation did not explain the abundance of South Florida slash pine or Chamaecrista lineata, but explained significant variation in abundance of Chamaesyce deltoidea. The latter two species are rare herbaceous plants restricted to pine rocklands. In 2008, 3 years after Hurricane Wilma, the positive relationship between elevation and abundance was strongest for South Florida slash pine, C. deltoidea, and C. lineata. Effects of Hurricane Wilma were not significant for rare species with wider distribution, occurring in plant communities adjacent to pine rocklands and in disturbed rocklands. Our results suggest that hurricanes drive population dynamics of South Florida slash pine and rare species that occur exclusively in pine rocklands at higher elevations. Rare species restricted to pine rocklands showed dramatic declines after Hurricane Wilma and were eliminated at elevations <0.5 m. Widely distributed rare species did not show significant changes in density after Hurricane Wilma. Abundance increased with elevation for South Florida slash pine and C. lineata after the hurricane. In an environment influenced by sea level rise, concrete plans to conserve pine ecosystems are warranted. Results from this study will help define conservation strategies by strengthening predictive understanding of plant responses to disturbance in the backdrop of sea level rise.