The effect of chlorine and chlorine dioxide on pathogenic free‐living amoebae (PFLA) in simulated natural conditions: The presence of bacteria and organic matter

Bacteria and bovine faecal matter were introduced into cultures of pathogenic free‐living amoebae, with chlorine or chlorine dioxide. The bacteria and faeces were to simulate natural conditions for a more exacting test of disinfectant demand when compared to axenic conditions. Both chlorine and chlorine dioxide were effective disinfectants under all conditions tested. Axenically and monoxenically cultured amoebae were used, the latter exerted a greater disinfectant demand.     

Experimental formation of massive hydrate deposits from accumulation of CH4 gas bubbles within synthetic and natural sediments

In order for methane to be economically produced from the seafloor, prediction and detection of massive hydrate deposits will be necessary. In many cases, hydrate samples recovered from seafloor sediments appear as veins or nodules, suggesting that there are strong geologic controls on where hydrate is likely to accumulate. Experiments have been conducted examining massive hydrate accumulation from methane gas bubbles within natural and synthetic sediments in a large volume pressure vessel through temperature and pressure data, as well as visual observations. Observations of hydrate growth suggest that accumulation of gas bubbles within void spaces and at sediment interfaces likely results in the formation of massive hydrate deposits. Methane hydrate was first observed as a thin film forming at the gas/water interface of methane bubbles trapped within sediment void spaces. As bubbles accumulated, massive hydrate growth occurred. These experiments suggest that in systems containing free methane gas, bubble pathways and accumulation points likely control the location and habit of massive hydrate deposits.     

The karst contagion model: Synopsis and environmental implications

The contagion model of karst terrane evolution focuses on the environmental implications for a large karst depression population on the Pennyroyal Plain (southern Kentucky) and the adjacent Western Highland Rim (Tennessee) immediately south of the Mammoth Cave Plateau. In karst terranes where the contagion model applies, there is a well-defined infrastructure comprised of hydrologic, structural geologic and geomorphic interacting elements that result in clustered depressions underlain by a radial conduit system. Clusters tend to be randomly distributed and typically contain a parent depression surrounded by numerous daughters.Groundwater flow is assumed to be turbulent and confined largely to conduits that are 3-dimensionally configured between clusters in a dendritic to trellis network. Parent depressions serve as conduit nodes for collecting groundwater migrating from beneath daughter depressions.Flow velocities in the 3-dimensional cluster-cell conduits exceed those in granular media by several orders of magnitude making pathogen and chemical contaminant migration rapid. Groundwater quality assessment in karst conduit hydrogeologic settings is difficult because monitoring wells are inappropriate. Monitoring wells may have a low probability of intercepting a major conduit and therefore the sampling regime must take into consideration the pulse discharge of pollutants in karst conduits. Representative water quality data must come from springs located near the local base level.     

Assessing spatial and attribute errors in large national datasets for population distribution models: a case study of Philadelphia county schools

Geospatial technologies and digital data have developed and disseminated rapidly in conjunction with increasing computing efficiency and Internet availability. The ability to store and transmit large datasets has encouraged the development of national infrastructure datasets in geospatial formats. National datasets are used by numerous agencies for analysis and modeling purposes because these datasets are standardized and considered to be of acceptable accuracy for national scale applications. At Oak Ridge National Laboratory a population model has been developed that incorporates national schools data as one of the model inputs. This paper evaluates spatial and attribute inaccuracies present within two national school datasets, Tele Atlas North America and National Center of Education Statistics (NCES). Schools are an important component of the population model, because they are spatially dense clusters of vulnerable populations. It is therefore essential to validate the quality of school input data. Schools were also chosen since a validated schools dataset was produced in geospatial format for Philadelphia County; thereby enabling a comparison between a local dataset and the national datasets. Analyses found the national datasets are not standardized and incomplete, containing 76 to 90 percent of existing schools. The temporal accuracy of updating annual enrollment values resulted in 89 percent inaccuracy for 2003. Spatial rectification was required for 87 percent of NCES points, of which 58 percent of the errors were attributed to the geocoding process. Lastly, it was found that by combining the two national datasets, the resultant dataset provided a more useful and accurate solution.     

Modeling doline populations with logistic growth functions

Initiation and evolution of a large karst depression population consisting of parent and daughter dolines were spatially and temporally modeled using logistic growth functions. Logistic growth models are well suited for analyzing doline population initiation and evolution because they reflect the density‐dependent growth mechanisms present in the evolution of karst depressions. Seven assumptions based upon previous studies were refined into mathematical statements and tested using more than 2000 dolines from a subpopulation of both parent and daughter karst depressions on the Western Highland Rim and Pennyroyal Plain of Tennessee and Kentucky. Logistic growth models quantify the initiation and evolution of doline populations and interface well with recent models describing the evolution of three‐dimensional conduit systems. Logistic growth models should apply to modeling other doline populations in karst terranes with hydraulically efficient, three‐dimensional conduit systems. Copyright © 2006 John Wiley & Sons, Ltd.     

Mineral chemistry of a zircon-bearing, composite, veined and metasomatised upper-mantle peridotite xenolith from kimberlite

Zircon-bearing veins in a harzburgite xenolith from kimberlite have imposed Ca-metasomatism on the harzburgite wall rock, in addition to adding K, Fe, Ti and OH. The zircon, previously dated to have an age similar to that of the xenolith-hosting kimberlite, shows higher Y, Nb, Ba, REE, Th and U contents than other mantle-derived zircons. Peripheral alteration of the zircon to baddeleyite and zirconolite, and alteration of vein ilmenite to perovskite suggest reaction with an evolving carbonatitic kimberlite melt. The high Cr₂O₃ content (0.77 wt%) of the zirconolite extends the compositional range of terrestrial zirconolite.     

Potassium loss during metasomatic alteration of mica pyroxenite from Oldoinyo Lengai,northern Tanzania: contrasts with fenitization

Mica pyroxenite xenoliths, occurring as the cores of nephelinite and ijolite bombs in the pyroclastic deposits of the active volcano Oldoinyo Lengai, have undergone metasomatism in which K was lost and Fe²⁺ and Ti gained. This is unlike the alkali and ferric iron addition that typifies most examples of metastomatism adjacent to peralkaline igneous rocks in carbonatite complexes.