Adsorption of Copper, Nickel, and Cadmium on Goethite in the Presence of Organic Ligands

Adsorption of copper, cadmium and nickel at low concentrations on goethite was studied in the presence of the simple organic ligands oxalate, salicylate, and pyromellitate. The experimental metal adsorption behavior was compared to calculations with a surface complexation model to evaluate the most important interactions. Oxalate mostly decreased Cu and Ni adsorption at high pH-values by competition between solution and surface complexation but had no effect on Cd adsorption. Cu adsorption in the presence of oxalate below pH 6 could best be described by defining a ternary complex of type A (surface-metal-ligand). Salicylate had only minor effects on metal adsorption. The adsorption of Cu in the presence of salicylate above pH 5 could be explained by a ternary complex of type A. Pyromellitate increased the adsorption of Cu and Cd in the acidic pH-range, likely by formation of ternary surface complexes of type B (surface-ligand-metal).     

An Overview of Dissolved and Suspended Matter Fluxes in the Loire River Basin: Natural and Anthropogenic Inputs

The spatial and temporal distributions of major elements were investigated in the surface waters and in associated suspended matter at two sites of the upper Loire basin (Orleans and Brehemont) between 1995 and 1998.According to geochemical and isotopic patterns, the dissolved load appears to result from a process of mixing rainwater inputs, weathering processes of carbonate and silicate bedrock, and agricultural and urban inputs. Natural inputs influence 60% of water chemical composition at both sites. Annual dissolved fluxes were estimated to be 1300 10³ t/y at Orleans and 1620 10³ t/y at Brehemont. Major elements are transported mainly in the dissolved fraction. After correcting for atmospheric and anthropogenic inputs, the silicate specific export rate was calculated to be 11 t/y/km² throughout the basin and the carbonate specific export rate to be from 47 t/y/km² at Orleans to 23 t/y/km² at Brehemont.The suspended load appears to result from at least two particle reservoirs: a silicate reservoir and a carbonate reservoir. The silicate reservoir has a detrital origin, mainly during periods of high flow, while the carbonate reservoir has a detrital origin during periods of high flow and an authigenic origin during periods of low flow. Of the total annual flow of suspended matter, this authigenic material represents 16% at Orleans, 25% at Brehemont and 37% in the fluvial part of the estuary. After correcting authigenic inputs, the specific export rate due to mechanical weathering was estimated to be 8 t/y/km² throughout the Loire basin.     

Pilot Point Optimization of Mining Boundaries for Lateritic Metal Deposits: Finding the Trade-off Between Dilution and Ore Loss

Natural Resources Research - Geological contacts in lateritic metal deposits (footwall topographies) often delineate the orebody boundaries. Spatial variations seen in such contacts are frequently...     

Geographic structure of European anchovy: A nuclear-DNA study

Atlantic–Mediterranean anchovies were genetically characterized at two polymorphic nuclear loci (intron 6 of two creatine-kinase genes) and compared to reference Engraulis albidus and E. encrasicolus samples from the northern Western Mediterranean to provide new insights into their geographic structure. Northeastern Atlantic anchovy, represented by one sample from the Canary archipelago and one sample from the Alboran Sea, were genetically distinct from Mediterranean E. encrasicolus (Weir and Cockerham's ^θ = 0.027–0.311), indicating geographic isolation from either side of the Almería–Oran oceanographic front. Generally smaller genetic differences were evident among anchovy populations from different sub-basins in the Mediterranean (^θ = − 0.019–0.116), the genetic differences between Black Sea and Ionian Sea/Aegean Sea anchovies being the strongest (^θ = 0.002–0.116). There was no evidence of the presence of E. albidus in our samples outside Camargue (northern shore of the Western Mediterranean). However, a sample from the southern Western Mediterranean appeared to be genetically intermediate between E. albidus and Mediterranean E. encrasicolus, indicating possible hybridization. Anchovy from the Benguela current system off southern Africa possessed allele frequencies characteristic of E. albidus at one locus and Northeastern Atlantic anchovy at the other locus, suggesting past introgression.     

Reconstruction of Horizontal Plasma Motions at the Photosphere from Intensitygrams: A Comparison Between DeepVel,LCT, FLCT,and CST

Direct measurements of plasma motions in the photosphere are limited to the line-of-sight component of the velocity. Several algorithms have therefore been developed to reconstruct the transverse components from observed continuum images or magnetograms. We compare the space and time averages of horizontal velocity fields in the photosphere inferred from pairs of consecutive intensitygrams by the LCT, FLCT, and CST methods and the DeepVel neural network in order to identify the method that is best suited for generating synthetic observations to be used for data assimilation. The Stein and Nordlund (Astrophys. J. Lett.753, L13, 2012) magnetoconvection simulation is used to generate synthetic SDO/HMI intensitygrams and reference flows to train DeepVel. Inferred velocity fields show that DeepVel performs best at subgranular and granular scales and is second only to FLCT at mesogranular and supergranular scales.     

Distribution of the organic matter in the channel-levees systems of the Congo mud-rich deep-sea fan (West Africa). Implication for deep offshore petroleum source rocks and global carbon cycle

The quantity and the source of organic matter preserved in the Recent turbiditic channel-levees systems around 4000 m-depth off the Congo River were determined using bulk geochemical approaches (Rock-Eval, elemental and isotopic analyses) as well as molecular and optical analyses on selected samples. These mud-rich sediments contain high amount of organic matter (3% Corg on average), the origin of which is a mixture of terrestrial higher-plant debris and deeply oxidized phytoplanktonic material. Although the relative contribution of continental source versus marine source of the organic matter cannot be precisely quantified, the continental fraction appears significant (at least 70–80%) especially for such depths and distances from the coast. The organic matter distribution appears very homogeneous at different scales, from the single turbiditic event to the entire levee, and changes in accumulation rates have a little impact on the quantity and quality of preserved organic matter.     

Metamorphism at the northwest contact of the Stanhope Pluton,Quebec Appalachians: Mineral equilibria in interbedded pelite and calc-schist

The interbedding of pelite and calc-schist in part of the contact aureole of a Devonian (biotite K-Ar age 346±4 Ma) granite pluton that straddles the Quebec-Vermont border offers an opportunity to compare metamorphic conditions prevailing in both rock types, and to test for internal consistency among several different geothermometers and geobarometers.Microprobe analyses and recent thermodynamic data are used with simple activity-composition models to estimate P-T-X _fluid conditions near the sillimanite zone. Calculations yield the following results: P=2 to 3 kb, and T =400° to 600° C in the inner one kilometre of the aureole; was around 0.8. Estimates are based on the calc-silicate isobaric invariant assemblages tremolite-K-feldspar-plagioclase-clinozoisite-phlogopite-calcite-quartz and diopside-tremolite-plagiolase-clinozoisite-calcite-quartz, and the paragonite-andalusite-sillimanite-albite-quartz equilibrium. The solid-solid reaction phlogopite+2 diopside + 4 quartz=tremolite+K-feldspar in the calc-schist (combined with the andalusite-sillimanite equilibrium), and phase relations in the granite yield apparently inconsistent results.The implied 6 to 10 km of cover at the time of intrusion may have been provided by subsequently eroded thrust sheets.