Water yield issues in the jarrah forest of south-western Australia

The jarrah forest of south-western Australia produces little streamflow from moderate rainfall. Water yield from water supply catchments for Perth, Western Australia, are low, averaging 71 mm (7% of annual rainfall). The low water yields are attributed to the large soil water storage available for continuous use by the forest vegetation. A number of water yield studies in south-western Australia have examined the impact on water yield of land use practices including clearing for agricultural development, forest harvesting and regeneration, forest thinning and bauxite mining. A permanent reduction in forest cover by clearing for agriculture led to permanent increases of water yield of approximately 28% of annual rainfall in a high rainfall catchment. Thinning of a high rainfall catchment led to an increase in water yield of 20% of annual rainfall. However, it is not clear for how long the increased water yield will persist. Forest harvesting and regeneration have led to water yield increases of 16% of annual rainfall. The subsequent recovery of vegetation cover has led to water yields returning to pre-disturbance levels after an estimated 12–15 years. Bauxite mining of a high rainfall catchment led to a water yield increase of 8% of annual rainfall, followed by a return to pre-disturbance water yield after 12 years. The magnitude of specific streamflow generation mechanisms in small catchments subject to forest disturbance vary considerably, typically in a number of distinct stages. The presence of a permanent groundwater discharge area was shown to be instrumental in determining the magnitude of the streamflow response after forest disturbance. The long-term prognosis for water yield from areas subject to forest thinning, harvesting and regeneration, and bauxite mining are uncertain, owing to the complex interrelationship between vegetation cover, tree height and age, and catchment evapotranspiration. Management of the forest for water yield needs to acknowledge this complexity and evaluate forest management strategies both at the large catchment scale and at long time-scales. The extensive network of small catchment experiments, regional studies, process studies and catchment modelling at both the small and large scale, which are carried out in the jarrah forest, are all considered as integral components of the research to develop these management strategies to optimise water yield from the jarrah forest, without forfeiting other forest values.     

Field observations of wave refraction and propagation pathways on coral reef platforms

Field experiments were conducted to investigate the refraction and propagation of ocean waves across two coral reef platforms in the Maldives, central Indian Ocean. A total of seven pressure sensors were deployed on each reef to quantify temporal and spatial variations in wave characteristics across the platform surfaces. Directional wave properties were calculated from high frequency (2 Hz) wave and current records obtained at two locations on each reef and corroborate theoretically predicted propagation pathways derived from an analytical wave refraction model. Results demonstrate that reef geometry critically controls the refraction and propagation behaviour of incident swell across the reef structures. Differences in the magnitude of refraction (approximately 57° and 14°) observed on each reef can be attributed to variations in platform shape and orientation to incident waves. Results demonstrate that reef flat wave patterns define the segmentation of platform surfaces into distinctive high and low wave energy zones. Furthermore, wave focussing has been identified as a major mechanism controlling the transformation of wave energy across the reefs. Results provide the first field‐based validation of wave refraction and convergence on coral reefs and have significant implications for sedimentation processes and the formation of platform deposits. Reef configurations which promote marked wave convergence are more likely to retain sediment on the reef surface, whereas platforms that induce less refraction and changes in the direction of incident waves have a higher potential for the off‐reef evacuation of sediment over leeward reef margins. Results of wave measurements substantiate such projections and provide a first order explanation for the existence and absence of a coral cay on the two study reefs. The study presents empirical evidence of wave refraction and convergence on coral reefs and establishes a baseline for future investigations of hydrodynamic process controls on platform sedimentation and island formation. Copyright © 2012 John Wiley & Sons, Ltd.     

Remote sensing of cloud liquid water

Summary A method is presented to infer cloud liquid water path (LWP in kg/m²) over the ocean from passive microwave measurements of SSM/I. The algorithm to retrieve LWP is based on simulated satellite observations. They are calculated with a radiative transfer model applied to about 3000 radiosonde ascents over the Atlantic Ocean. Since radiosonde observations do not contain direct information about cloud water and ice, these parameters are parameterized based on relative humidity and temperature using modified adiabatic liquid water density profiles. A multiple linear regression is applied to the simulated radiances and the calculated LWP to derive the algorithm. The retrieval accuracy based on the regression analysis including instrumental noise is 0.03 kg/m². Validation of the LWP-algorithm was pursued through a comparison with measurements of a ground-based 33 GHzmicrowave radiometer on board of R.V. Poseidon during the International Cirrus Experiment 1989 at the North Sea (ICE'89). The LWP values agree within the range of uncertainty caused by the different sampling characteristics of the observing systems. The retrieval accuracy for clear-sky cases determined using colocated METEOSAT data over the North Sea is 0.037 kg/m² and confirms the accuracy estimated from regression analysis for the low liquid water cases.The algorithm was used to derive maps of monthly mean LWP over the Atlantic Ocean. As an example the Octobers of the 5 years 1987–1991 were selected to demonstrate the interannual variability of LWP. The results were compared with the cloud water content produced by the climate model ECHAM-T2 from the Max-Planck-Institut Hamburg.Observations during ICE'89 were used to check the accuracy of the applied radiative transfer model. Brightness temperatures were calculated from radiosonde ascents launched during the overpass of DMSP-F8 in cloud-free situations. The channel-dependent differences range from about –2 to 3 K.The possibility to identify different cloud types using microwave and infrared observations was examined. The main conclusion is that simultaneous microwave and infrared measurements enable the separation of dense cirrus and cirrus with underlying water clouds. A classification of clouds with respect to their top heights and LWP was carried out using a combination of SSM/I derived LWP and simultaneously recorded Meteosat IR-data during ICE'89.With 11 Figures     

Mediterranean climate extremes in synoptic downscaling assessments

The behaviour of precipitation and maximum temperature extremes in the Mediterranean area under climate change conditions is analysed in the present study. In this context, the ability of synoptic downscaling techniques in combination with extreme value statistics for dealing with extremes is investigated. Analyses are based upon a set of long-term station time series in the whole Mediterranean area. At first, a station-specific ensemble approach for model validation was developed which includes (1) the downscaling of daily precipitation and maximum temperature values from the large-scale atmospheric circulation via analogue method and (2) the fitting of extremes by generalized Pareto distribution (GPD). Model uncertainties are quantified as confidence intervals derived from the ensemble distributions of GPD-related return values and described by a new metric called “ratio of overlapping”. Model performance for extreme precipitation is highest in winter, whereas the best models for maximum temperature extremes are set up in autumn. Valid models are applied to a 30-year period at the end of the twenty-first century (2070–2099) by means of ECHAM5/MPI-OM general circulation model data for IPCC SRES B1 scenario. The most distinctive future changes are observed in autumn in terms of a strong reduction of precipitation extremes in Northwest Iberia and the Northern Central Mediterranean area as well as a simultaneous distinct increase of maximum temperature extremes in Southwestern Iberia and the Central and Southeastern Mediterranean regions. These signals are checked for changes in the underlying dynamical processes using extreme-related circulation classifications. The most important finding connected to future changes of precipitation extremes in the Northwestern Mediterranean area is a reduction of southerly displaced deep North Atlantic cyclones in 2070–2099 as associated with a strengthened North Atlantic Oscillation. Thus, the here estimated future changes of extreme precipitation are in line with the discourse about the influence of North Atlantic circulation variability on the changing climate in Europe.     

The value of bioenergy in low stabilization scenarios: an assessment using REMIND-MAgPIE

This study investigates the use of bioenergy for achieving stringent climate stabilization targets and it analyzes the economic drivers behind the choice of bioenergy technologies. We apply the integrated assessment framework REMIND-MAgPIE to show that bioenergy, particularly if combined with carbon capture and storage (CCS) is a crucial mitigation option with high deployment levels and high technology value. If CCS is available, bioenergy is exclusively used with CCS. We find that the ability of bioenergy to provide negative emissions gives rise to a strong nexus between biomass prices and carbon prices. Ambitious climate policy could result in bioenergy prices of 70 $/GJ (or even 430 $/GJ if bioenergy potential is limited to 100 EJ/year), which indicates a strong demand for bioenergy. For low stabilization scenarios with BECCS availability, we find that the carbon value of biomass tends to exceed its pure energy value. Therefore, the driving factor behind investments into bioenergy conversion capacities for electricity and hydrogen production are the revenues generated from negative emissions, rather than from energy production. However, in REMIND modern bioenergy is predominantly used to produce low-carbon fuels, since the transport sector has significantly fewer low-carbon alternatives to biofuels than the power sector. Since negative emissions increase the amount of permissible emissions from fossil fuels, given a climate target, bioenergy acts as a complement to fossils rather than a substitute. This makes the short-term and long-term deployment of fossil fuels dependent on the long-term availability of BECCS.     

High-pressure synthesis,long-term stability of single crystals of diboron trioxide,B<Subscript>2</Subscript>O<Subscript>3</Subscript>, and an empirical electronic polarizability of <Superscript>[3]</Superscript>B<Superscript>3+</Superscript>

Single crystals of B₂O₃ are needed for the precise determination of the refractive indices used to calculate the electronic polarizability α of 3-coordinated boron. The α(B) values in turn are used to predict mean refractive indices of borate minerals. Since the contribution of boron to the total polarizability of a mineral is very low, the synthetic compound B₂O₃ represents an ideal model system because of its high molar content of boron. Millimeter-sized crystals were synthesized at 1 GPa in a piston-cylinder apparatus. The samples were heated above the liquidus (800 °C), subsequently cooled at 15 °C/h to 500 °C and finally quenched. The refractive indices were determined by the immersion method using a microrefractometer spindle stage. The refractive indices n _o = 1.653 (3) and n _e = 1.632 (3) correspond to a total polarizability for B₂O₃ of α = 4.877 Å³. These values were used to determine the electronic polarizability of boron of α(B) = 0.16 Å³. Although the surface of the B₂O₃ crystals was coated with a hydrous film immediately after being exposed to air, its bulk crystallinity is retained for a period of at least 2 months.     

Sedimentology of a Late Quaternary lacustrine record from the south-eastern Carpathian Basin

The Upper Pleistocene geoarchives in the south-eastern Carpathian Basin are represented predominantly by loess–palaeosol records. In 2015, a 10 m sediment core composed of clay-rich lacustrine sediments was recovered by vibracoring a dry lake basin located between the Vršac Mountains (Serbia) and the Banat Sands in the south-eastern Carpathian Basin; a location relevant for placing regional archaeological results in a palaeoenvironmental context. Here, we present results from geoelectrical prospection and a lithostratigraphic interpretation of this sequence supported by a detailed granulometric study supplemented by ostracod analysis. An age model based on luminescence dating is discussed against sedimentological proxy data and its implication for palaeoenvironmental change. The cores show a stratigraphy of lighter ochre-coloured and darker greyish sediment, related to the deposition of clay and silt trapped in an aquatic environment. Geophysical measurements show ~20 m thick lacustrine sediments. The grain-size distributions including the variability in fine clay are indicative of a lacustrine environment. Fine particles were brought into the depositional environments by aquatic input and settled from suspension; also, direct dust input is constrained by grain-size results. Riverine input and aeolian dust input interplayed at the locality.     

Study of enzyme-catalysed and noncatalysed interactions between soil humic acid and C-labelled 2-aminobenzothiazole using solid-state C NMR spectroscopy

Chemical interactions between 2-aminobenzothiazole (ABT) and a soil humic acid (HA) extracted from a gleyic planosol were investigated by solid-state ¹³C CP/MAS NMR spectroscopy. Reactions of the HA with ABT ¹³C-labelled at the C-2 position were performed in aqueous solution under noncatalysed and enzyme-catalysed conditions. Without enzymic catalysis the amount of ABT-2-¹³C taken up by soil HA in an oxygen atmosphere was about twice the uptake under argon. In the presence of the oxidative enzyme laccase and air, about three times as much ABT was bound to HA as compared to the uptake in a control experiment with inactivated laccase. The results suggest that oxidation reactions of the humic acid significantly enhance the extent of binding between ABT and HA. The ¹³C NMR spectra of the HA–ABT adducts indicated that in both noncatalysed and enzyme-catalysed reactions ABT may be bound to humic acid by noncovalent as well as covalent bonds.     

Regional review: the hydrology of the Okavango Delta, Botswana—processes, data and modelling

The wetlands of the Okavango Delta accommodate a multitude of ecosystems with a large diversity in fauna and flora. They not only provide the traditional livelihood of the local communities but are also the basis of a tourism industry that generates substantial revenue for the whole of Botswana. For the global community, the wetlands retain a tremendous pool of biodiversity. As the upstream states Angola and Namibia are developing, however, changes in the use of the water of the Okavango River and in the ecological status of the wetlands are to be expected. To predict these impacts, the hydrology of the Delta has to be understood. This article reviews scientific work done for that purpose, focussing on the hydrological modelling of surface water and groundwater. Research providing input data to hydrological models is also presented. It relies heavily on all types of remote sensing. The history of hydrologic models of the Delta is retraced from the early box models to state-of-the-art distributed hydrological models. The knowledge gained from hydrological models and its relevance for the management of the Delta are discussed.