An explicit finite difference model for simulating weakly nonlinear and weakly dispersive waves over slowly varying water depth

In this paper, a modified leap-frog finite difference (FD) scheme is developed to solve Non linear Shallow Water Equations (NSWE). By adjusting the FD mesh system and modifying the leap-frog algorithm, numerical dispersion is manipulated to mimic physical frequency dispersion for water wave propagation. The resulting numerical scheme is suitable for weakly nonlinear and weakly dispersive waves propagating over a slowly varying water depth. Numerical studies demonstrate that the results of the new numerical scheme agree well with those obtained by directly solving Boussinesq-type models for both long distance propagation, shoaling and re-fraction over a slowly varying bathymetry. Most importantly, the new algorithm is much more computationally efficient than existing Boussinesq-type models, making it an excellent alternative tool for simulating tsunami waves when the frequency dispersion needs to be considered.     

Geochemical evolution of uraniferous soda lakes in Eastern Mongolia

Extremely high concentrations of uranium (U) were discovered in shallow, groundwater-fed hyperalkaline soda lakes in Eastern Mongolia. A representative groundwater sample in this area is dilute and alkaline, pH = 7.9, with 10 mM TIC and 5 mM Cl⁻. In contrast, a representative lake water sample is pH ~ 10 with TIC and Cl⁻ each more than 1,000 mM. Groundwater concentrations of U range from 0.03 to 0.43 μM L⁻¹. Lake water U ranges from 0.24 to >62.5 μM, possibly the highest naturally occurring U concentrations ever reported in surface water. Strontium isotopes ⁸⁷Sr/⁸⁶Sr varied in groundwaters from 0.706192 to 0.709776 and in lakes ⁸⁷Sr/⁸⁶Sr varied from 0.708702 to 0.709432. High concentrations of U, Na, Cl⁻, and K correlate to radiogenic Sr in lake waters suggesting that U is sourced from local Cretaceous alkaline rhyolites. Uranium-rich groundwaters are concentrated by evaporation and U(VI) is chelated by CO₃⁻² to form the highly soluble UO₂(CO₃)₃⁻⁴. Modeled evaporation of lakes suggests that a U-mineral phase is likely to precipitate during evaporation.     

Application of primary haemocyte culture of Penaeus monodon in the assessment of cytotoxicity and genotoxicity of heavy metals and pesticides

Lack of shrimp cell lines has hindered the study of pollutants which adversely affects shrimp health and its export value. In this context a primary haemocyte culture developed from Penaeus monodon was employed for assessing the cytotoxicity and genotoxicity of two heavy metal compounds, cadmium chloride and mercuric chloride and two organophosphate insecticides, malathion and monocrotophos. Using MTT assay 12?h IC(50) values calculated were 31.09?±?16.27?μM and 5.52?±?1.16?μM for cadmium chloride and mercuric chloride and 59.94?±?52.30?mg?l(-1) and 186.76?±?77.00?mg?l(-1) for malathion and monocrotophos respectively. Employing Comet assay, DNA damage inflicted by these pollutants on haemocytes were evaluated and the pollutants induced DNA damage in >60% of the cells. The study suggested that haemocyte culture could be used as a tool for quantifying cytotoxicity and genotoxicity of aquaculture drugs, management chemicals and pollutants.     

A high-pressure neutron diffraction study of the ferroelastic phase transition in RbCaF3

The fluoroperovskite phase RbCaF₃ has been investigated using high-pressure neutron powder diffraction in the pressure range ~0–7.9 GPa at room temperature. It has been found to undergo a first-order high-pressure structural phase transition at ~2.8 GPa from the cubic aristotype phase to a hettotype phase in the tetragonal space group I4/mcm. This transition, which also occurs at ~200 K at ambient pressure, is characterised by a linear phase boundary and a Clapeyron slope of 2.96 × 10^?5 GPa K^?1, which is in excellent agreement with earlier, low-pressure EPR investigations. The bulk modulus of the high-pressure phase (49.1 GPa) is very close to that determined for the low-pressure phase (50.0 GPa), and both are comparable with those determined for the aristotype phases of CsCdF₃, TlCdF₃, RbCdF₃, and KCaF₃. The evolution of the order parameter with pressure is consistent with recent modifications to Landau theory and, in conjunction with polynomial approximations to the pressure dependence of the lattice parameters, permits the pressure variation of the bond lengths and angles to be predicted. On entering the high-pressure phase, the Rb–F bond lengths decrease from their extrapolated values based on a third-order Birch–Murnaghan fit to the aristotype equation of state. By contrast, the Ca–F bond lengths behave atypically by exhibiting an increase from their extrapolated magnitudes, resulting in the volume and the effective bulk modulus of the CaF₆ octahedron being larger than the cubic phase. The bulk moduli for the two component polyhedra in the tetragonal phase are comparable with those determined for the constituent binary fluorides, RbF and CaF₂.     

Identifying transboundary aquifers in need of international resource management in the Southern African Development Community region

Transboundary aquifer (TBA) management, in part, seeks to mitigate degradation of groundwater resources caused either by an imbalance of abstraction between countries or by cross-border pollution. Fourteen potential TBAs were identified within a hydrogeological mapping programme based on simple hydrogeological selection criteria for the Southern African Development Community (SADC) region. These have been reassessed against a set of data associated with five categories: (1) groundwater flow and vulnerability (which is perceived as the over-arching influence on the activity level of each TBA), (2) knowledge and understanding, (3) governance capability, (4) socio-economic/water-demand factors, and (5) environmental issues. These assessments enable the TBAs to be classified according to their need for cross-border co-operation and management. The study shows that only two of the 14 TBAs have potential to be the cause of tension between neighbouring states, while nine are potentially troublesome and three are unlikely to become problematic even in the future. The classification highlights the need to focus on data gathering to enable improved understanding of the TBAs that could potentially become troublesome in the future due to, for example, change in demographics and climate.     

An Assessment of Performance in the Routine Analysis of Silicate Rocks Based on an Analysis of Data Submitted to the GeoPT Proficiency Testing Programme for Geochemical Laboratories (2001–2011)

Data reported by laboratories contributing to the GeoPT proficiency testing programme for geochemical laboratories over the period from 2001 to 2011 have been assessed to identify the elements and concentration ranges over which analytical performance can be considered satisfactory. Criteria developed in the paper indicated that performance in the content determination of the elements/constituents SiO₂, Al₂O₃, MnO, Cs, Dy, Er, Eu, Ga, Hf, Ho, Lu, Nd, Pr, Sm, Sr, Tb, Tl, Tm, U, Y, Yb and Zn was satisfactory over the full concentration range assessed. The elements/constituents TiO₂, Fe₂O₃(T), MgO, CaO, Na₂O, K₂O, P₂O₅, Ba, Be, Cd, Ce, Co, Gd, La, Li, Nb, Rb, Sb, Sc, Sn, Ta, Th, V and Zr showed some degradation in performance at lower concentration levels (approaching the detection limit of some techniques). Performance in determining LOI, As, Bi, Cr, Cu, Ge, Mo, Ni, Pb and W was in general unsatisfactory over the full concentration range assessed. Other elements (especially Fe(II)O, H₂O⁺, CO₂, Ag, Au, B, Br, Cl, F, Hg, I, In, Ir, N, Os, Pd, Pt, Re, Rh, S, Se, Te) could not be evaluated as they were not routinely reported by laboratories participating in the GeoPT programme, often because they are present in silicate rocks at sufficiently low concentrations to require a pre‐concentration stage. Some suggestions are made for the causes of unsatisfactory performance, but further progress will require a detailed assessment of the methods used by participating laboratories, which will form the subject of a further paper.     

H2O–CO2 solubility in mafic alkaline magma: applications to volatile sources and degassing behavior at Erebus volcano, Antarctica

We present new equilibrium mixed-volatile (H₂O–CO₂) solubility data for a phonotephrite from Erebus volcano, Antarctica. H₂O–CO₂-saturated experiments were conducted at 400–700 MPa, 1,190 °C, and ~NNO + 1 in non-end-loaded piston cylinders. Equilibrium H₂O–CO₂ fluid compositions were determined using low-temperature vacuum manometry, and the volatile and major element compositions of the glassy run products were determined by Fourier transform infrared spectroscopy and electron microprobe. Results show that the phonotephrite used in this study will dissolve ~0.8 wt% CO₂ at 700 MPa and a fluid composition of $ X_{{{\text{H}}_{ 2} {\text{O}}}} $ ~0.4, in agreement with previous experimental studies on mafic alkaline rocks. Furthermore, the dissolution of CO₂ at moderate to high $ X_{{{\text{H}}_{ 2} {\text{O}}}}^{\text{fluid}} $ in our experiments exceeds that predicted using lower-pressure experiments on similar melts from the literature, suggesting a departure from Henrian behavior of volatiles in the melt at pressures above 400 MPa. With these data, we place new constraints on the modeling of Erebus melt inclusion and gas emission data and thus the interpretation of its magma plumbing system and the contributions of primitive magmas to passive and explosive degassing from the Erebus phonolite lava lake.     

Pacific Basin tsunami hazards associated with mass flows in the Aleutian arc of Alaska

We analyze mass-flow tsunami generation for selected areas within the Aleutian arc of Alaska using results from numerical simulation of hypothetical but plausible mass-flow sources such as submarine landslides and volcanic debris avalanches. The Aleutian arc consists of a chain of volcanic mountains, volcanic islands, and submarine canyons, surrounded by a low-relief continental shelf above about 1000–2000 m water depth. Parts of the arc are fragmented into a series of fault-bounded blocks, tens to hundreds of kilometers in length, and separated from one another by distinctive fault-controlled canyons that are roughly normal to the arc axis. The canyons are natural regions for the accumulation and conveyance of sediment derived from glacial and volcanic processes. The volcanic islands in the region include a number of historically active volcanoes and some possess geological evidence for large-scale sector collapse into the sea. Large scale mass-flow deposits have not been mapped on the seafloor south of the Aleutian Islands, in part because most of the area has never been examined at the resolution required to identify such features, and in part because of the complex nature of erosional and depositional processes. Extensive submarine landslide deposits and debris flows are known on the north side of the arc and are common in similar settings elsewhere and thus they likely exist on the trench slope south of the Aleutian Islands. Because the Aleutian arc is surrounded by deep, open ocean, mass flows of unconsolidated debris that originate either as submarine landslides or as volcanic debris avalanches entering the sea may be potential tsunami sources.To test this hypothesis we present a series of numerical simulations of submarine mass-flow initiated tsunamis from eight different source areas. We consider four submarine mass flows originating in submarine canyons and four flows that evolve from submarine landslides on the trench slope. The flows have lengths that range from 40 to 80 km, maximum thicknesses of 400–800 m, and maximum widths of 10–40 km. We also evaluate tsunami generation by volcanic debris avalanches associated with flank collapse, at four locations (Makushin, Cleveland, Seguam and Yunaska SW volcanoes), which represent large to moderate sized events in this region. We calculate tsunami sources using the numerical model TOPICS and simulate wave propagation across the Pacific using a spherical Boussinesq model, which is a modified version of the public domain code FUNWAVE. Our numerical simulations indicate that geologically plausible mass flows originating in the North Pacific near the Aleutian Islands can indeed generate large local tsunamis as well as large transoceanic tsunamis. These waves may be several meters in elevation at distal locations, such as Japan, Hawaii, and along the North and South American coastlines where they would constitute significant hazards.     

Win-win scenarios at the climate–development interface: Challenges and opportunities for stove replacement programs through carbon finance

Achieving win-win outcomes in environment–development programs is a laudable goal, but frequently difficult to realize. In this paper we review the possibilities for win-win climate and development outcomes in programs that distribute improved cookstoves with the use of carbon finance. We show that improved cookstove technologies form an important, if asymmetrical, environment–development interface, and illustrate the mutually supported local (development) and global (climate change) benefits of continued improved stoves use—where success in one program area is directly tied to benefits in the other. We also describe how program results are highly contextual and that, in practice, there are a number of challenges to achieving effective ‘win-win’ outcomes—including cultural, financial, governance and technological barriers. While carbon finance provides an opportunity to fund scaleable and enforceable stove programs, it may also introduce mutually supported impediments—where progress towards one set of program objectives, directly compromises progress towards other objectives. Drawing on development debates for improved cookstove use, scientific reports on stove-based greenhouse gas reductions, and preexisting case studies of carbon and non-carbon financed cookstoves in Peru, Uganda and Cambodia, we conclude that the challenge for future carbon financed improved cookstove projects will be to leverage inherent symbioses between climate and development arenas in order to overcome mutually supported impediments. Achieving substantive win-win conditions will require further scholarly and practical engagement to tackle the many outstanding challenges and uncertainties reviewed in this essay.     

Predictions for the frequency and orbital radii of massive extrasolar planets

We investigate the migration of massive extrasolar planets caused by gravitational interaction with a viscous protoplanetary disc. We show that a model in which planets form at 5 au at a constant rate, before migrating, leads to a predicted distribution of planets that is a steeply rising function of log( a ), where a is the orbital radius. Between 1 and 3 au, the expected number of planets per logarithmic interval in a roughly doubles. We demonstrate that, once selection effects are accounted for, this is consistent with current data, and then extrapolate the observed planet fraction to masses and radii that are inaccessible to current observations. In total, approximately 15 per cent of stars targeted by existing radial velocity searches are predicted to possess planets with masses  0.3< M _p sin( i )<10 M _J  and radii  0.1< a <5 au  . A third of these planets (around 5 per cent of the target stars) lie at the radii most amenable to detection via microlensing. A further  5–10  per cent of stars could have planets at radii of  5< a <8 au  that have migrated outwards. We discuss the probability of forming a system (akin to the Solar system) in which significant radial migration of the most massive planet does not occur. Approximately  10–15  per cent of systems with a surviving massive planet are estimated to fall into this class. Finally, we note that a smaller fraction of low-mass planets than high-mass planets is expected to survive without being consumed by the star. The initial mass function for planets is thus predicted to rise more steeply towards small masses than the observed mass function.