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David L. COOK Meenakshi WADHWA Robert N. CLAYTON Nicolas DAUPHAS Philip E. JANNEY Andrew M. DAVIS 《Meteoritics & planetary science》2007,42(12):2067-2077
Abstract— We measured nickel isotopes via multicollector inductively coupled plasma mass spectrometry (MC‐ICPMS) in the bulk metal from 36 meteorites, including chondrites, pallasites, and irons (magmatic and non‐magmatic). The Ni isotopes in these meteorites are mass fractionated; the fractionation spans an overall range of ~0.4‰ amu?1. The ranges of Ni isotopic compositions (relative to the SRM 986 Ni isotopic standard) in metal from iron meteorites (~0.0 to ~0.3‰ amu?1) and chondrites (~0.0 to ~0.2‰ amu?1) are similar, whereas the range in pallasite metal (~–0.1 to 0.0‰ amu?1) appears distinct. The fractionation of Ni isotopes within a suite of fourteen IIIAB irons (~0.0 to ~0.3‰ amu?1) spans the entire range measured in all magmatic irons. However, the degree of Ni isotopic fractionation in these samples does not correlate with their Ni content, suggesting that core crystallization did not fractionate Ni isotopes in a systematic way. We also measured the Ni and Fe isotopes in adjacent kamacite and taenite from the Toluca IAB iron meteorite. Nickel isotopes show clearly resolvable fractionation between these two phases; kamacite is heavier relative to taenite by ~0.4‰ amu?1. In contrast, the Fe isotopes do not show a resolvable fractionation between kamacite and taenite. The observed isotopic compositions of kamacite and taenite can be understood in terms of kinetic fractionation due to diffusion of Ni during cooling of the Fe‐Ni alloy and the development of the Widmanstätten pattern. 相似文献
134.
Automatic triangulation of scattered locations permits analysis of local variation in a dependent variable through calculation of a roughness index. This is approached by treating triangles of the triangulation (including the dependent variable) as vectorial structures, and accumulating at each data point the vector sum of the cluster of triangles surrounding it. The roughness index is defined as the complement of the ratio of the area of a triangle cluster to the area of component triangles as projected onto a gradient plane defined by their vector sum. The roughness index provides a measure of consistency of data values relative to surrounding observations and can be interpreted as a local index of reliability of interpolation. 相似文献
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We describe a powerful signal processing method, the continuous wavelet transform, and use it to analyze radial structure in Cassini ISS images of Saturn's rings. Wavelet analysis locally separates signal components in frequency space, causing many structures to become evident that are difficult to observe with the naked eye. Density waves, generated at resonances with saturnian satellites orbiting outside (or within) the rings, are particularly amenable to such analysis. We identify a number of previously unobserved weak waves, and demonstrate the wavelet transform's ability to isolate multiple waves superimposed on top of one another. We also present two wave-like structures that we are unable to conclusively identify. In a multi-step semi-automated process, we recover four parameters from clearly observed weak spiral density waves: the local ring surface density, the local ring viscosity, the precise resonance location (useful for pointing images, and potentially for refining saturnian astrometry), and the wave amplitude (potentially providing new constraints upon the masses of the perturbing moons). Our derived surface densities have less scatter than previous measurements that were derived from stronger non-linear waves, and suggest a gentle linear increase in surface density from the inner to the mid-A Ring. We show that ring viscosity consistently increases from the Cassini Division outward to the Encke Gap. Meaningful upper limits on ring thickness can be placed on the Cassini Division (3.0 m at r∼118,800 km, 4.5 m at r∼120,700 km) and the inner A Ring (10-15 m for r<127,000 km). 相似文献
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Jutta ZIPFEL Bradley L. JOLLIFF Ralf GELLERT Kenneth E. HERKENHOFF Rudolf RIEDER Robert ANDERSON James F. BELL III Johannes BRÜCKNER Joy A. CRISP Philip R. CHRISTENSEN Benton C. CLARK Paulo A.
De SOUZA Jr. Gerlind DREIBUS Claude
D’USTON Thanasis ECONOMOU Steven P. GOREVAN Brian C. HAHN Göstar KLINGELHÖFER Timothy J. McCOY Harry Y. McSWEEN Jr. Douglas W. MING Richard V. MORRIS Daniel S. RODIONOV Steven W. SQUYRES Heinrich WÄNKE Shawn P. WRIGHT Michael B. WYATT Albert S. YEN 《Meteoritics & planetary science》2011,46(1):1-20
Abstract– The Opportunity rover of the Mars Exploration Rover mission encountered an isolated rock fragment with textural, mineralogical, and chemical properties similar to basaltic shergottites. This finding was confirmed by all rover instruments, and a comprehensive study of these results is reported here. Spectra from the miniature thermal emission spectrometer and the Panoramic Camera reveal a pyroxene‐rich mineralogy, which is also evident in Mössbauer spectra and in normative mineralogy derived from bulk chemistry measured by the alpha particle X‐ray spectrometer. The correspondence of Bounce Rock’s chemical composition with the composition of certain basaltic shergottites, especially Elephant Moraine (EET) 79001 lithology B and Queen Alexandra Range (QUE) 94201, is very close, with only Cl, Fe, and Ti exhibiting deviations. Chemical analyses further demonstrate characteristics typical of Mars such as the Fe/Mn ratio and P concentrations. Possible shock features support the idea that Bounce Rock was ejected from an impact crater, most likely in the Meridiani Planum region. Bopolu crater, 19.3 km in diameter, located 75 km to the southwest could be the source crater. To date, no other rocks of this composition have been encountered by any of the rovers on Mars. The finding of Bounce Rock by the Opportunity rover provides further direct evidence for an origin of basaltic shergottite meteorites from Mars. 相似文献
140.
Dale P. Cruikshank Allan W. Meyer Roger N. Clark Katrin Stephan Scott A. Sandford Gianrico Filacchione Philip D. Nicholson Thomas B. McCord J. Brad Dalton Dennis L. Matson 《Icarus》2010,206(2):561-572
Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO2) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm−1), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO2 absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO2, CO2 clathrates, ternary mixtures of CO2 with other volatiles, implanted and adsorbed CO2 in non-volatile materials, and ab initio theoretical calculations of CO2 * nH2O. At the wavelength resolution of VIMS, the CO2 on Phoebe is indistinguishable from pure CO2 ice (each molecule’s nearby neighbors are also CO2) or type II clathrate of CO2 in H2O. In contrast, the CO2 band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm−1)) and broadened. These wavelengths are characteristic of complexes of CO2 with different near-neighbor molecules that are encountered in other volatile mixtures such as with H2O and CH3OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO2 is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO2 on the other three satellites results at least in part from particle or UV irradiation of native H2O plus a source of C, implantation or accretion from external sources, or redistribution of native CO2 from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO2 gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO2 absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO2 absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO2, as discussed in this paper. 相似文献