The inception and early evolution of the North Alpine Foreland Basin, Switzerland

The stratigraphy of the Eocene-Miocene peripheral foreland basin in Switzerland consists of basal deposits of Nummulitic Limestones and Globigerina Marls representing a phase of deepening, followed by two shallowing-up megacycles culminating in fully continental sedimentation. The onset of sedimentation was diachronous and took place on an unconformity surface with increasing stratigraphic gap to the north and west. In the Ultrahelvetic units, which were derived from the south and have a provenance between the Helvetic shelf and the Penninic ocean, the stratigraphic gap is minimal. This restricts the initiation of erosion of the southern European margin due to emersion to post-Maastrichtian and pre-late Palaeocene. This coincides with the final closing of the Valais trough and may therefore be interpreted as the point at which continental flexure s. s. started. In the autochthon, the subcrop map of the unconformity surface shows that the regional pattern of subcropping units is oblique to both neo-Alpine tectonic structures and Helvetic (Mesozoic) passive margin structures. There are local zones of disruption to the broad regional pattern suggesting that the basal unconformity was corrugated. Both the paliaspastic restoration of the autochthon relative to the thrust front during the Palaeocene, and the regional pattern of erosion indicate that the basal unconformity may be due to erosion of a flexural forebulge. Following deposition of the shallow water Nummulitic Limestones and the deeper water Globigerina Marls, clastic sediments were shed from the orogenic wedge in the south. These turbidites, the Taveyannaz Sandstones, filled both ponded basins at the contemporaneous thrust front and the frontal trench or foredeep. Evidently, early thrusts drove at a shallow level into the embryonic basin as ‘front-runners’, whereas most shortening and uplift continued to take place within the main part of the orogenic wedge further to the south. Eventually, the frontal palaeohighs, together with the turbidite basins, were buried by the northward emplacement of surface mud-slides, and sediment depocentres were translated northwards onto the foreland. The most likely cause of the underfilled ‘Flysch’ stage is the rapid advance of a submarine thrust wedge over the flexed European plate which resulted in (i) low sediment fluxes and (ii) high subsidence rates associated with the rapid migration of the load and depocentre. Later, as the rate of advance slowed and the wedge became subaerially exposed, the basin rapidly filled with coarse-grained detritus representing the ‘Molasse’ stage.     

Chemical and chronologic complexity in the convecting upper mantle: Evidence from the Taitao ophiolite, southern Chile

Exposure of the ca. 6 Ma Taitao ophiolite, Chile, located 50 km south of the Chile Triple Junction, allows detailed chemical and isotopic study of rocks that were recently extracted from the depleted mantle source of mid-ocean ridge basalts (DMM). Ultramafic and mafic rocks are examined for isotopic (Os, Sr, Nd, and O), and major and trace element compositions, including the highly siderophile elements (HSE). Taitao peridotites have compositions indicative of variable extents of partial melting and melt extraction. Low δ¹⁸O values for most whole rock samples suggest some open-system, high-temperature water–rock interaction, most likely during serpentinization, but relict olivine grains have δ¹⁸O values consistent with primary mantle values. Most of the peridotites analyzed for Nd–Sr isotopes have compositions consistent with estimates for the modern DMM, although several samples are characterized by ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd indicative of crustal contamination, most likely via interactions with seawater. The peridotites have initial ¹⁸⁷Os/¹⁸⁸Os ratios that range widely from 0.1168 to 0.1288 (γ_Os = −8.0 to +1.1), averaging 0.1239 (γ_Os = −2.4), which is comparable to the average for modern abyssal peridotites. A negative correlation between the Mg^# of relict olivine grains and Os isotopic compositions of whole rock peridotites suggests that the Os isotopic compositions reflect primary mantle Re/Os fractionation produced by variable extents of partial melting at approximately 1.6 Ga. Recent re-melting at or near the spatially associated Chile Ridge further modified these rocks, and Re, and minor Pt and Pd were subsequently added back into some rocks by late-stage melt–rock or fluid–rock interactions.In contrast to the peridotites, approximately half of the mafic rocks examined have whole rock δ¹⁸O values within the range of mantle compositions, and their Nd and Sr isotopic compositions are all generally within the range of modern DMM. These rocks have initial ¹⁸⁷Os/¹⁸⁸Os ratios, calculated for 6 Ma, that range from 0.126 (γ_Os = −1) to as high as 0.561 (γ_Os = +342). The Os isotopic systematics of each of these rocks may reflect derivation from mixed lithologies that include the peridotites, but may also include pyroxenites with considerably more radiogenic Os than the peridotites. This observation supports the view that suprachondritic Os present in MORB derives from mixed mantle source lithologies, accounting for some of the worldwide dichotomy in ¹⁸⁷Os/¹⁸⁸Os between MORB and abyssal peridotites.The collective results of this study suggest that this >500 km³ block of the mantle underwent at least two stages of melting. The first stage occurred at 1.6 Ga, after which the block remained isolated and unmixed within the DMM. A final stage of melting recently occurred at or near the Chile Ridge, resulting in the production of at least some of the mafic rocks. Convective stirring of this mantle domain during a >1 Ga period was remarkably inefficient, at least with regard to Os isotopes.     

Diagenesis of vascular plant organic matter components during burial in lake sediments

Diagenetic changes are difficult to distinguish from variations in sources of organic matter to sediments. Organic geochemical comparisons of samples of wood, bark, and needles from a white spruce (Picea glauca) living today and one buried for 10,000 years in lake sediments have been used to identify the effects of diagenesis on vascular plant matter. Important biogeochemical changes are evident in the aged spruce components, even though the cellular structures of the samples are well preserved. Concentrations of total fatty acids dramatically diminish; unsaturated and shorter chainlength components are preferentially lost from the molecular distributions. Concentrations of total alcohols are similar in the modern and 10,000-year-old wood and bark but markedly lowered in the aged needles. Hydrocarbon concentrations and distributions show little diagenetic change in the 10,000-year-old plant materials. Cellulose components in the wood decrease relative to lignin components, although both types of materials remain in high concentration in comparison to other organic components. Aromatization of abietic acid proceeds more rapidly in buried spruce wood than in bark; retene is the dominant polyaromatic hydrocarbon in the aged wood. In contrast to the variety of changes evident in molecular compositions, neither ¹³C values nor C/N ratios differ significantly in the bulk organic matter of modern and aged spruce components.     

Generalized Born inversion of seismic reflection data

Summary . Born inverse methods give accurate and stable results when the source wavelet is impulsive. However, in many practical applications (reflection seismology) an impulsive source cannot be realized and the inversion needs to be generalized to include an arbitrary source function. In this paper, we present a Born solution to the seismic inverse problem which can accommodate an arbitrary source function and give accurate and stable results. It is shown that the form of the generalized inversion algorithm reduces to a Wiener shaping ***filter, which is solved efficiently using a Levinson recursion algorithm. Numerical examples of synthetic and real field data illustrate the validity of our method.     

X-Ray Excitation of Molecular Hydrogen and [Fe II] Emission in NGC 1068

NGC 1068 is a source of luminous emission in the near-infrared lines of molecular hydrogen and [Fe II]. Although these emission lines are commonly attributed to shocks, I show that in NGC 1068 it is quite plausible that they arise in the X-Ray Dissociation Region (XDR) produced by X-ray irradiation of the gas in the disk by the powerful active nucleus. This mechanism naturally produces the observed size scale of the H2 emission. I will also briefly discuss the implications of the observations of the pure rotation lines of H2 with ISO (Lutz, this workshop).     

The Effects of Ocean Acidification on Feeding and Contest Behaviour by the Beadlet Anemone <Emphasis Type="Italic">Actinia equina</Emphasis>

Increasing concentrations of atmospheric carbon dioxide are causing oceanic pH to decline worldwide, a phenomenon termed ocean acidification. Mounting experimental evidence indicates that near-future levels of CO₂ will affect calcareous invertebrates such as corals, molluscs and gastropods, by reducing their scope for calcification. Despite extensive research into ocean acidification in recent years, the effects on non-calcifying anthozoans, such as sea anemones, remain little explored. In Western Europe, intertidal anemones such as Actinia equina are abundant, lower trophic-level organisms that function as important ecosystem engineers. Changes to behaviours of these simple predators could have implications for intertidal assemblages. This investigation identified the effects of reduced seawater pH on feeding and contest behaviour by A. equina. Video footage was recorded for A. equina feeding at current-day seawater (pH 8.1), and the least (pH 7.9) and most (pH 7.6) severe end-of-century predictions. Footage was also taken of contests over ownership of space between anemones exposed to reduced pH and those that were not. No statistically significant differences were identified in feeding duration or various aspects of contest behaviour including initiating, winning, inflating acrorhagi, inflicting acrorhagial peels and contest duration. Multivariate analyses showed no effect of pH on a combination of these variables. This provides contrast with other studies where anemones with symbiotic algae thrive in areas of natural increased acidity. Thus, novel experiments using intraspecific contests and resource-holding potential may prove an effective approach to understand sub-lethal consequences of ocean acidification for A. equina, other sea anemones and more broadly for marine ecosystems.     

PRODUCTIVITY RATINGS BASED ON SOIL SERIES: A METHODOLOGICAL CRITIQUE

Most regional maps of soil productivity are based on the erroneous assumption that the soil series, the fundamental taxonomic unit, is also a homogeneous unit of productivity with consistent and predictable yields when compared with other series. This assumption may lead to significant errors in estimates of potential productivity, with profound implications for prime-land delimitation, tax assessment, zoning administration, and other policies that presently rely on published soil productivity ratings.     

A comparison of mud- and sand-dominated meanders in a downstream coarsening reach of the mixed bedrock-alluvial Klip River, eastern Free State, South Africa

Along a 28 km reach of the Klip River, eastern Free State, South Africa, mud- and sand-dominated meanders have developed in close proximity within a floodplain wetland up to 1.5 km wide, providing an unusual opportunity to compare their characteristics under similar hydrological conditions. Throughout the reach, the channel bed is grounded on sandstone/shale bedrock although the banks are alluvial, and most river activity occurs during summer high flows. The reach can be divided into three geomorphological zones: Zone 1 (0–11 km), a muddy proximal part with a single meandering channel (w/d < 10) and near-permanent standing water in oxbows and backswamps; Zone 2 (11–17.5 km), a transitional mud-to-sand part with one main channel (w/d  20–30), a number of sinuous palaeochannels and oxbows, and only limited standing water; and Zone 3 (17.5–28 km), a sandy distal part with a single meandering channel (w/d  15–30), scroll bars and oxbows, and little standing water. Each zone also has a distinctive sedimentology: Zone 1 is characterised by an  3–4 m thick succession of basal sand and minor granules overlain by dominantly muddy sediment deposited primarily by oblique accretion in meander bends; Zone 2 is characterised by < 4 m of interbedded sand and mud deposited primarily by lateral point-bar accretion, although a history of avulsions also attests to the importance of abandoned-channel accretion; and Zone 3 is characterised by < 3 m of dominantly sand deposited primarily by lateral point-bar accretion. This unusual downstream sediment coarsening trend, and the associated changes in channel and floodplain character, are independent of sediment inputs from tributaries, and result from a downstream increase in bankfull unit stream power from < 3.5 W m^− 2 (Zone 1) to  4–10 W m^− 2 (Zone 3). Mud is deposited primarily in low-energy Zone 1 but is conveyed in suspension more effectively through higher energy Zones 2 and 3, only forming drapes over sandy lateral accretion deposits during waning flood stages. The downstream increase in unit stream power is controlled in part by a slight downstream increase in floodplain gradient that may be related to a subtle variation in the erosional resistance of the bedrock underlying the channel bed. These findings add to previous work on meandering rivers by demonstrating that mud-dominated meanders can occur in long-term erosional settings where the channel bed is grounded on bedrock, and that downstream fining trends may be reversed locally.     

Compositional controls on spinel clouding and garnet formation in plagioclase of olivine metagabbros,Adirondack Mountains,New York

Olivine metagabbros from the Adirondacks usually contain both clear and spinel-clouded plagioclase, as well as garnet. The latter occurs primarily as the outer rim of coronas surrounding olivine and pyroxene, and less commonly as lamellae or isolated grains within plagioclase. The formation of garnet and metamorphic spinel is dependent upon the anorthite content of the plagioclase. Plagioclase more sodic than An_38±2 does not exhibit spinel clouding, and garnet rarely occurs in contact with plagioclase more albitic than An_36±4. As a result of these compositional controls, the distribution of spinel and garnet mimics and visually enhances original igneous zoning in plagioclase. Most features of the arrangement of clear (unclouded) plagioclase, including the shells or moats of clear plagioclase which frequently occur inside the garnet rims of coronas, can be explained on the basis of igneous zoning. The form and distribution of the clear zones may also be affected by the metamorphic reactions which have produced the coronas, and by redistribution of plagioclase in response to local volume changes during metamorphism.Authors listed alphabeticallyPublished by permission of the Director, New York State Museum, Journal Series Number 299