Temporal association of arc–continent collision,progressive magma contamination in arc volcanism and formation of gold-rich massive sulphide deposits on Wetar Island (Banda arc)

Whole-rock ⁸⁷Sr/⁸⁶Sr and δ¹⁸O analyses of volcanic rocks and ³He/⁴He analyses of sulphides and sulphates from mineralized rocks on Wetar, Indonesia indicate a variable contribution of assimilated crustal material or sediment sourced from the subducted Australian craton to the south. These new data support the idea of progressive source contamination with precisely dated events showing that Wetar Island hosts the most extreme examples of crustal assimilation in the region. The increased continental contamination occurs during the Pliocene (Zanclian to Piacenzian) during distinct magmatic events between 5 and 4 Ma, and at 2.4 Ma when ⁸⁷Sr/⁸⁶Sr ratios in unaltered lavas, with whole-rock δ¹⁸O values between 5.7 and 9.6‰, increase from 0.707484 to extreme radiogenic values of 0.711656.The earlier of these magmatic events is important in the generation of the hydrothermal systems responsible for the mineralization recorded on Wetar. Samples from this yield radiogenic ³He/⁴He ratios between 0.5 and 1.4 R/R_A, similar to the data from volcanic rocks on nearby Romang. The later magmatic event coincides with the arrival of the Australian Continental Margin at the subduction zone along the Banda arc. Progressive incorporation of continental-sourced components into the source region below the Wetar Island edifice coincides with the formation of gold-rich volcanogenic massive sulphide deposits hosted within the contaminated volcanic pile.     

Aussiedler migration and its impact on Braşov's ethnic German population and built environment

The expression of different ethnic identities in the landscape is a product of the creation, destruction and preservation of the built environment. This may illustrate the changing processes over the evolution of a landscape. In the case of Braşov, Romania, it is possible to see in the urban landscape a reflection of the changing nature of the relationship between the ethnic German and Romanian populations, and the German and Romanian governments. This paper will demonstrate the persistence of ethnic German culture in the built environment and social organisation of Braşov in spite of the exodus of the ethnic German population. This revised version was published online in July 2006 with corrections to the Cover Date.     

A well‐established Early–Middle Pleistocene marine sequence on south‐east Zakynthos island,western Greece: Magneto‐biostratigraphic constraints and palaeoclimatic implications

The chronostratigraphy of a long, onshore Early–Middle Pleistocene marine sedimentary sequence on the south‐east part of Zakynthos island, Greece, is presented. Correlation of the succession with the isotope record of Ocean Drilling Program Site 963 reveals the combined influence of tectonics and eustacy in this area. The sequence is divided into three formations by two main unconformities that apparently relate to sea‐level lowstands associated with two major northern hemisphere glaciations, those of marine isotope stages (MIS) 22 and 12. The Zakynthos sequence in many ways is comparable with the Italian Valle di Manche section. Magnetostratigraphic and rock magnetic analyses, supported by biostratigraphy, document the position of the Matuyama/Brunhes Chron boundary (0.77 Ma), the top and base of the Jaramillo Subchron (0.99–1.07 Ma), the Cobb Mountain Subchron (1.173–1.185 Ma) and the top of the Olduvai Subchron (1.78 Ma). The underlying strata are constrained exclusively by detailed nannofossil biostratigraphy extending at least to the lowermost Pleistocene at around 2.54 Ma and therefore certainly incorporating the base of the Olduvai Subchron (1.95 Ma) and possibly the Gauss/Matuyama Chron boundary (2.58 Ma). In addition, a remarkable increase in sedimentation rate (from 3.2 and 28 cm ka^?1 to 167 cm ka^?1) and hence resolution above the Matuyama/Brunhes boundary (Middle Pleistocene) reveals one short‐lived magnetic excursion, possibly 17a (0.66 Ma), within the normal polarity Brunhes Chron. Copyright © 2011 John Wiley & Sons, Ltd.     

Earthquake recurrence on the Calaveras fault east of San Jose, California

Occurrence of small (3 M_L < 4) earthquakes on two 10-km segments of the Calaveras fault between Calaveras and Anderson reservoirs follows a simple linear pattern of elastic strain accumulation and release. The centers of these independent patches of earthquake activity are 20 km apart. Each region is characterized by a constant rate of seismic slip as computed from earthquake magnitudes, and is assumed to be an isolated locked patch on a creeping fault surface. By calculating seismic slip rates and the amount of seismic slip since the time of the last significant (M 3) earthquake, it is possible to estimate the most likely date of the next (M - 3) event on each patch. The larger the last significant event, the longer the time until the next one. The recurrence time also appears to be increased according to the moment of smaller (2 < M_L < 3) events in the interim. The anticipated times of future larger events on each patch, on the basis of preliminary location data through May 1977 and estimates of interim activity, are tabulated below with standard errors. The occurrence time for the southern zone is based on eight recurrent events since 1969, the northern zone on only three. The 95% confidence limits can be estimated as twice the standard error of the projected least-squares line. Events of M 3 should not occur in the specified zones at times outside these limits. The central region between the two zones was the locus of two events (M = 3.6, 3.3) on July 3, 1977. These events occurred prior to a window based on the three point, post-1969 slip-time line for the central region.

Latitude	Longitude	Depth	Mag.	Target date	Standard error (days)
37°17′± 2′N	121°39′±2′W	5.0 ±2 km	3.0–4.0	7-22-77	22.3
37°26′± 2′N	121°47′±2′W	6.0 ± 2 km	3.0–4.0	9-02-77	8.0

Full-size table

     

New Validity Conditions for the Multivariate Matérn Coregionalization Model,with an Application to Exploration Geochemistry

Mathematical Geosciences - This paper addresses the problem of finding parametric constraints that ensure the validity of the multivariate Matérn covariance for modeling the spatial...     

Determination of High Field Strength Elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g−1 Levels in Geological Reference Materials by Magnetic Sector ICP-MS after HF/HClO4 High Pressure Digestion

Six low abundance rock reference materials (basalt BIR-1, dunite DTS-1, dolerite DNC-1, peridotite PCC-1, serpentine UB-N and basalt TAFAHI) have been analysed for high field strength elements (Zr, Nb, Hf, Ta, Th and U), Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels (in rock) by magnetic sector inductively coupled plasma-mass spectrometry after HF/HClO₄ high pressure decomposition. The adopted method uses only indium as an internal standard. Detection limits were found to be in the range of 0.08 to 16.2 pg ml⁻¹ in solution (equivalent to 0.08 to 16.2 ng g⁻¹ in rock). Our data for high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi for the six selected low abundance geological reference materials show general agreement with previously published data. Our Ta values in DTS-1 and PCC-1 (1.3 and 0.5 ng g⁻¹) are lower than in previously published studies, providing smooth primitive mantle distribution patterns. Lower values were also found for Tl in BIR-1, DTS-1 and PCC-1 (2, 0.4 and 0.8 ng g⁻¹). Compared with quadrupole ICP-MS studies, the proposed magnetic sector ICP-MS method can generally provide better detection limits, so that the measurement of high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels can be achieved without pre-concentration, ion exchange separation or other specialised techniques.     

Trace element model studies of Nyanzian greenstone belts,western Kenya

The Archean greenstone belts of the Nyanzian System in western Kenya are composed principally of andesite with minor tholeiitic basalt and siliceous volcanics. The Nyanzian tholeiite is an intermediate-K tholeiite with a flat REE pattern. There are two chemically-distinct andesites: a low-K andesite (Andesite I) and a high-K andesite (Andesite II). The REE pattern of the Andesite II is enriched in light REE and depleted in heavy REE relative to Andesite I.Major and trace element calculations indicate an origin for the Nyanzian tholeiite by 35–40% equilibrium melting of a lherzolite source followed by 10% shallow fractional crystallization. Similar calculations best explain Andesite I and Andesite II by 20 and 5% melting, respectively, of an ecologite or garnet amphibolite source of Nyanzian tholeiite composition. The rhyolite may have formed either by 20–30% partial melting of a siliceous granulite or by 20–30% fractional crystallization of a granodiorite parent magma.With respect to total exposure areas, the Nyanzian volcanics have significantly less tholeiite and more Andesite and siliceous volcanics than other Archean greenstone belts. If these abundances are representative, two models are proposed to explain the anomalous abundances of Andesite and siliceous volcanics. The first model involves an Archaen upper mantle with a relatively low geothermal gradient beneath Kenya, while the second model involves a relatively cool mantle plume. Both models inhibit ascent of a significant amount of primary tholeiite to the surface and prevent formation of secondary tholeiite. Other Archean greenstone terranes with higher mantle geotherms or hotter mantle plumes would receive higher proportions of mafic and ultramafic magmas.     

In Situ Determination of First‐Row Transition Metal,Ga and Ge Abundances in Geological Materials via Medium‐Resolution LA‐ICP‐MS

An in situ, medium‐resolution LA‐ICP‐MS method was developed to measure the abundances of the first‐row transition metals, Ga and Ge in a suite of geological materials, namely the MPI‐DING reference glasses. The analytical protocol established here hinged on maximising the ablation rate of the ultraviolet (UV) laser system and the sensitivity of the ICP‐MS, as well minimising the production of diatomic oxides and argides, which serve as the dominant sources of isobaric interferences. Non‐spectral matrix effects were accounted for by using multiple external calibrators, including NIST SRM 610 and the USGS basaltic glasses BHVO‐2G, BIR‐1G and BCR‐2G, and utilising ⁴³Ca as an internal standard. Analyses of the MPI‐DING reference glasses, which represent geological matrices ranging from basaltic to rhyolitic in composition, included measurements of concentrations as low as < 10⁰ μg g^?1 and as high as > 10⁴ μg g^?1. The new data reported here were found to statistically correlate with the ‘preferred’ reference values for these materials at the 95% confidence level, though with significantly better precision, typically on the order of ≤ 3% (2s_m). This analytical method may be extended to any matrix‐matched geological sample, particularly oceanic basalts, silicate minerals and meteoritic materials.