广西丹池盆地晚古生代震积岩及其构造意义

广西丹池盆地（即南丹—河池盆地）为晚古生代与金沙江—红河—马江古特提斯洋共生的大陆边缘裂谷盆地,盆地从早泥盆世晚期开始裂陷,与相邻地区形成条块分割的深水裂陷槽（条）和孤立台地（块）间列的局面。该盆地于三叠纪随着金沙江—红河—马江古特提斯洋的闭合而逐渐萎缩,消亡。在丹池裂陷盆地形成、演化过程中,形成一系列典型的震积岩及与地震相关的滑塌构造。地震形成的沉积构造包括沉积岩墙、地裂缝、沉积岩脉、微褶皱、负荷构造、火焰构造、滑塌构造（滑塌不整合、滑塌褶皱、角砾岩化）等。丹池盆地的震积岩反映晚古生代处于强烈的伸展活动期,震积岩及其伴生的滑塌构造序列反映盆地的幕式构造活动。     

Production and Certification of Synthetic Selenium Isotopic Reference Materials

Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with ⁷⁶Se, ⁷⁸Se, ⁸⁰Se and ⁸²Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding ⁷⁸Se/⁷⁶Se isotope mixtures and ⁸²Se/⁷⁶Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ^82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios.     

基于HNGICS管理信息系统的设计与实现

解决了连续运行卫星定位系统管理和应用的异构性问题,以实际开发运行系统为例提出解决方法,对CORS站数据管理与应用具有参考作用。本文以HNGICS为基础,介绍了HNGICS采用的系统架构、软硬件环境、开发模式与系统功能,同时讨论了相关测试方法。     

Mobilization of arsenic and iron from Red River floodplain sediments, Vietnam

Sediments from the Red River and from an adjacent floodplain aquifer were investigated with respect to the speciation of Fe and As in the solid phase, to trace the diagenetic changes in the river sediment upon burial into young aquifers, and the related mechanisms of arsenic release to the groundwater. Goethite with subordinate amounts of hematite were, using Mössbauer spectroscopy, identified as the iron oxide minerals present in both types of sediment. The release kinetics of Fe, As, Mn and PO₄ from the sediment were investigated in leaching experiments with HCl and 10 mM ascorbic acid, both at pH 3. From the river sediments, most of the Fe and As was mobilized by reductive dissolution with ascorbic acid while HCl released very little Fe and As. This suggests As to be associated with an Fe-oxide phase. For oxidized aquifer sediment most Fe was mobilized by ascorbic acid but here not much As was released. However, the reduced aquifer sediments contained a large pool of Fe(II) and As that is readily leached by HCl, probably derived from an unidentified authigenic Fe(II)-containing mineral which incorporates As as well. Extraction with ascorbic acid indicates that the river sediments contain both As(V) and As(III), while the reduced aquifer sediment almost exclusively releases As(III). The difference in the amount of Fe(II) leached from river and oxidized aquifer sediments by ascorbic acid and HCl, was attributed to reductive dissolution of Fe(III). The reactivity of this pool of Fe(III) was quantified by a rate law and compared to that of synthetic iron oxides. In the river mud, Fe(III) had a reactivity close to that of ferrihydrite, while the river sand and oxidized aquifer sediment exhibited a reactivity ranging from lepidocrocite or poorly crystalline goethite to hematite. Mineralogy by itself appears to be a poor predictor of the iron oxide reactivity in natural samples using the reactivity of synthetic Fe-oxides as a reference. Sediments were incubated, both unamended and with acetate added, and monitored for up to 2 months. The river mud showed the fastest release of both Fe and As, while the effect of acetate addition was minor. This suggests that the presence of reactive organic carbon is not rate limiting. In the case of the river and aquifer sediments, the release of Fe and As was always stimulated by acetate addition and here reactive organic carbon was clearly the rate limiting factor. The reduced aquifer sediment apparently can sustain slower but prolonged microbially-driven release of As. The highly reactive pools of Fe(III) and As in the river mud could be due to reoxidation of As and Fe contained in the reducing groundwater from the floodplain aquifers that are discharging into the river. Deposition of the suspended mud on the floodplain during high river stages is proposed to be a major flux of As onto the floodplain and into the underlying aquifers.     

高层钢框架-支撑结构二阶非线性随机地震响应分析

针对常用的高层钢框架－支撑结构，考虑材料非线性和几何非线性，建立了框架部分、支撑部分的二阶动力分析模型。用等效线性方法对结构进行非线性随机地震响应分析，结合工程算例，论述不同场地土、不同层数、不同支撑情况下，二阶效应对结构地震响应统计量的影响。     

不同厚度饱和砂土中群桩结构动力响应试验研究

液化土中桩基础动力响应规律一直是工程抗震领域关注的热点问题。本文基于非液化砂土和不同厚度饱和砂土中的2×2群桩结构模型振动台试验,通过输入一定峰值加速度和频率的正弦波,对群桩在非液化土层和两种不同厚度饱和砂土层中的横向动力响应特性进行振动台试验研究。研究结果表明:在正弦波输入情况下,非液化砂土中群桩承台加速度和位移时程与台面输入时程相比,波形变化规律与峰值大小均相差不大;而对两种不同厚度饱和砂土中承台加速度和位移峰值放大较多,在相对较薄的饱和砂土中群桩承台加速度峰值较台面输入放大了1.83倍,较台面输出位移峰值放大了1.58倍;在相对较厚的饱和砂土中承台加速度和位移峰值则分别放大了2.18倍和1.91倍,说明在相同输入条件下,较厚的饱和砂土在发生液化后群桩承台的动力响应更加显著。     

柴达木盆地西部典型油田原油地球化学特征对比

利用色谱-质谱(GC-MS)分析技术,系统剖析了柴达木盆地西部南区尕斯库勒、油砂山油田(A区)与北区南翼山、油泉子油田(B区)原油的生物标志化合物组成和分布特征,探讨了A区和B区原油的成因差异及其地质影响因素.结果表明:A区部分浅层原油正构烷烃碳数分布不完整,具有异常高的姥鲛烷(Pr)与n-C17峰面积比值和植烷(Ph)与n-C18峰面积比值,说明A区浅层油藏保存条件较差,部分原油遭受了轻微生物降解;A区和B区原油中甾藿比均大于2.4,且甾烷C27R与甾烷C29R峰面积比值多大于1,指示这2个区域原油母质来源都以浮游藻类为主,但B区原油中甾烷C27R与甾烷C29R峰面积比值和补身烷系列相对含量普遍高于A区,表明B区原油浮游藻类和细菌生源贡献可能相对较高;所有原油都具有低姥植比、高伽马蜡烷含量的特点,且都检测出一定丰度的β-胡萝卜烷,说明生成原油的烃源岩形成于强还原咸水沉积环境,但A区原油中姥植比、伽马蜡烷指数以及 β-胡萝卜烷与C30藿烷峰面积比值明显高于B区,且升藿烷系列呈“翘尾巴”分布模式,而B区原油则没有这种现象,揭示生成A区原油的烃源岩沉积水体盐度更高、还原性更强;甾烷异构体比值(C2920S/(20S+ 20R)值和C29ββ/(ββ+αα)值)表明A区均为低熟原油,而B区多为成熟原油.结合柴达木盆地西部第三纪湖盆沉积和构造演化史,认为南区与北区烃源岩沉积相带的不同空间展布情况是造成A区与B区原油地球化学特征差异的根本原因.     

环境场对边界层低空急流形成的影响

本文利用两层流的浅水波模式,讨论了环境场对边界层低空急流形成的影响,并得到了边界层低空急流的特征宽度为L₀=(ρ₂-ρ₁)/(ν₂ρ₂-ρ₁ν₁)L₀*C₀*,式中C₀*=√gh₂, L₀*=C₀*/f为Rossby变形半径,ρ₁,p₂和v₁,v₂分别为上下两层大气的密度和大尺度经向地转风,H₂为低层大气的厚度,g为重力加速度,f为柯氏参数,当高低层大气中的大尺度经向地转风的垂直切变越强时,所形成的中尺度边界层低空急流就越强;当低层大气中的温度增高和湿度增大、并且低层大气中的大尺度经向地转风越强、高度越低时,越有利于形成边界层低空急流。      

汶川地震引发高速远程滑坡运动机理数值模拟研究——以谢家店子滑坡为例

针对汶川地震引发的谢家店子滑坡,在现场调查分析的基础上,建立了二维离散元数值模拟模型,采用2D-Block软件对其进行了全过程的数值模拟研究,并通过对跟踪块体的深入分析,研究了相应地质体在不同阶段下的运动特征。模拟结果表明,谢家店子滑坡经历了剧动启程抛掷阶段、快速撞击飞行阶段、铲刮减速碎屑流阶段及堆积掩埋阶段。为了揭示地震引发高速滑坡的发生规律,分别研究了地震震级、斜坡地形和斜坡上岩块的尺寸对高速滑坡启动和运动过程的影响规律。地震震级对边坡的启动、变形、破坏和运动有很大的影响,地震震级越大,滑体启动的加速度和速度也就越大,从而易形成高速远程滑坡。斜坡体本身的地形地貌对滑体运动也有较大影响。在震级和岩石力学参数一定的条件下,斜坡上岩块的大小对其启动、变形和运动过程有一定影响,随着岩块的增大,滑体运动的每个阶段历时都在减小,但当岩体十分破碎时,滑体虽然能够运动,但是很难发生抛掷。将地震滑坡的启动机理概括为积累变形效应、振荡启程效应和振荡加速效应。