Photo induced dissociation of ferri and ferro cyanide in hydroponic solutions

The potential for photo-induced dissociation of ferri- and ferro-cyanide was investigated. The overall reactions followed first order kinetics, judged by the free cyanide analyzed in aqueous solution. The dissociation rates for ferri- and ferro-cyanide were mathematically described by the equations: C _(CN,t) = C _(CN,O)e^1.3t and C _(CN,t) = C _(CN,O)e^0.39t , respectively. In addition, photo-induced dissociation of both iron cyanides was enhanced under an alkaline environment than a neutral condition. Results from the temperature-dependent tests indicated that the dissociation rate of ferri- cyanide was significantly higher than that of ferro-cyanide at all treatment temperatures. The kinetic parameter, activation energy (E _a ) was also experimentally determined to be 12.02 and 12.32 kJ/mol for ferri- and ferro-cyanide, respectively. The results obtained suggest that both iron cyanides are susceptible to photo-dissociation and the rates are positively correlated to the change of temperatures. The information collectively also has important implications for waste management of iron cyanides as well as for risk assessment in a field trial.     

Wave Breaker Indices in Finite Water Depth

Based on the analysis and comparison of wave breaker indices defined by geometric, kinetic as well as dynamic stabilities and verified by observation, the value a, which is equal to H / Lthkd by Miche's result and may be modified by Goda's results, is" suggested as the wave breaking criteria. The applicable values of a for pure waves or wave-current co-existing field are given in this paper. They are smaller than Miche's result (0.142), and they have been verified by model tests.     

La région axiale de la dorsale sud-ouest indienne entre 53° est et 59° est: Son evolution depuis 10 Ma

Resumé Cet article présente des données bathymétriques et magnétiques de la région axiale de la dorsale sud-ouest indienne au voisinage de la zone de fracture majeure Atlantis II. Elles proviennent pricipalement de la campagne MD34 (Marion-Dufresne, 1983).L'axe de la dorsale est défini par la vallée et l'anomalie magnétique qui lui est associée. Le rilief le long de l'axe varie localement très rapidement; A l'ouest de la zone de fracture Atlantis II, le plancher axial présente deux bombements séparés par une dépression importante (4600 m). Cette étude met en évidence la corrélation entre ces hauts bathymétriques, la forme de la vallée et la l'amplitude de l'anomalie magnétique axiale: lorsque la profondeur du plancher axial diminue, la vallée se creuse et son encaissement augmente. On observe ainsi sur les hauts bathymétriques une section d'axe très encaissée, associée à une anomalie magnétique d'amplitude plus importance.L'identification de l'anomalie 5 (10 Ma) sur chaque flanc de la dorsale sud-ouest indienne permet la reconstitution de cette isochrone qui montre clairement une évolution de la géométrie de l'axe: à l'époque de l'anomalie 5, l'axe était composé de segments perpendiculaires à la direction d'expansion, décalés par des failles transformantes, alors qu'il apparait actuellement continu et formé sur les hauts topographiques de courts segments perpendiculaires à la direction d'expansion (et dans les dépressions par des sections d'axe très obliques).La carte bathymétrique met en évidence des lignes de crêtes grossièrement Nord-Sud (007°) dont la direction diffère de la direction d'expansion (357°) déduite des reconstructions, et parallèle à la zone de fracture majeure Atlantis II. Sur les dorsales lentes, les zones de fractures mineures, n'indiqueraient donc pas la véritable direction d'expansion.

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The axial region of the Southwest Indian Ridge between 53° E and 59° E: Evolution during the last 10 Ma

An interpretation of bathymetric and magnetic data obtained aboard the R/V Marion Dufresne provides us with new information concerning the evolution of the Southwest Indian Ridge, in the region of the Atlantis II Fracture Zone (57° E), since 10 Ma. On all profiles, the ridge axis and the axial magnetic anomaly have been clearly recognized. Bathymetric data illustrate the rapid variation of depth along the axis. On the western side of the Atlantis II Fracture Zone, the along axis profile is characterized by a succession of two highs, and an important depression between them.Our data show a strong relationship between the regional axial depth, the steep-sidedness of the axial valley and the signature of the central magnetic anomaly. In particular, where the axis is deepest (4500 m), there is a wide, shallow axial valley which is oblique to the spreading direction, and a non-typical central magnetic anomaly signature. In contrast, where the regional axial depth is shallow (3500 m), the axial valley is deep, narrow, perpendicular to the spreading direction, and the central magnetic anomaly is high in amplitude. The ridge axis on the western side of the Atlantis II Fracture Zone appears to consist of short segments located on the axial highs, which are linked by oblique zones. On the eastern side, the ridge axis is continuous, and appears to be oblique to the spreading direction.Clearly lineated magnetic anomalies 3A (5 Ma) and 5 (10 Ma) have been identified and mapped. These magnetic data allow a reconstruction which shows an evolution of the axial geometry since 10 Ma. On the western side of the Atlantis II Fracture Zone, the axis at anomaly 5 time consisted of segments perpendicular to the spreading direction which were offset by transform faults. On the eastern side, the isochron A5 appears to be parallel to the present-day ridge axis. From this plate reconstruction, a spreading direction of 357° was deduced, and appears to be parallel to the Atlantis II Fracture Zone.On each flank of the Suuthwest Indian Ridge, our bathymetric data show elongated ridges, aligned in a north-south direction, which correlate with the axial topographic highs. This direction is not precisely parallel to the spreading direction deduced from plate reconstruction. The differences in these directions suggest that transverse relief on show spreading ridge flanks (which could be interpreted as indicating the location of minor fracture zones) may not be indicative of the seafloor spreading direction.

     

Statistical Distributions of Wavelengths

The statistical distribution of wavelength is directly derived from a two-dimensional andspatially homogeneous Gaussian wave field.The present result differs from both the result of Rayleigh dis-tribution and Sun's result(1988b)which is transformed through the period distribution derived from atwo-dimensional and stationary Gaussian wave field.A laboratory experiment shows that the present re-sult is more consistent with the observations in the wave tank than the others.     

Dissolved load of the Loire River: chemical and isotopic characterization

The Loire River, with one of the largest watersheds in France, has been monitored just outside the city of Orleans since 1994. Physico-chemical parameters and major and trace elements were measured between 2-day and 1-week intervals according to the river flow. The sampling site represents 34% of the total Loire watershed with 76% silicate rocks and 24% carbonate rocks.

Elements are transported mainly in the dissolved phase with the ratio of total dissolved salts (TDS) to suspended matter (SM) ranging between 1.6 and 17.4. Chemical weathering of rocks and soils are thus the dominant mechanisms in the Loire waters composition. The highest TDS/SM ratios are due to dissolved anthropogenic inputs. The database shows no link between NO₃⁻ content and river flow. The Na⁺, K⁺, Mg²⁺, SO₄²⁻, and Cl⁻ concentrations are seen to decrease with increasing discharge, in agreement with a mixing process involving at least two components: the first component (during low flow) is concentrated and may be related with input from the groundwater and sewage station water, the second component (during high flow) is more dilute and is in agreement with bedrock weathering and rainwater inputs. A geochemical behaviour pattern is also observed for HCO₃⁻ and Ca²⁺ species, their concentrations increase with increasing discharge up to 300 m³/s, after which, they decrease with increasing discharge. The Sr isotopic composition of the dissolved load is controlled by at least five components — a series of natural components represented by (a) waters draining the silicate and carbonate bedrock, (b) groundwater, and (c) rainwaters, and two kinds of anthropogenic components.

The aim of this study is to describe the mixing model in order to estimate the contribution of each component. Finally, specific export rates in the upper Loire watershed were evaluated close to 12 t year⁻¹ km⁻² for the silicate rate and 47 t year⁻¹ km⁻² for the carbonate rate.     

Young nuclei in dwarf elliptical galaxies

We report the discovery of young embedded structures in three diffuse elliptical galaxies (dE) in the Virgo cluster: IC 783, IC 3468, and IC 3509. We performed 3D spectroscopic observations of these galaxies with the MPFS spectrograph at the 6-m Special Astrophysical Observatory telescope and obtained spatially resolved distributions of kinematic and stellar population parameters by fitting high-resolution PEGASE. HR synthetic single stellar populations (SSP) in pixel space. In all three galaxies, the luminosity-weighted age of the nuclei (∼4 Gyr) is considerably younger than that of the population in the outer regions of the galaxies. We discuss two possibilities for the formation of such structures—a dissipative merger event and a different ram pressure stripping efficiency during two consecutive crossings of the Virgo cluster centre. The article was translated by the authors.     

On coordinated development of oasis and environment in arid area

1 Formation and evolution of oasisBoth physical environment and human activities influence the formation and evolution of oasis. Natural oasis is a kind of ecological landscape formed mainly by water without human intervention. Its prosperity and adversity primarily depends on the flow direction and discharge of a river. With the increment of intensity of human activities, however, great changes have taken place in oasis in arid area. The evolution of oasis has been transformed from the contr…