Determination of organophosphorus insecticide residues in the rice paddies

In most rice paddies in Mazandaran Province, diazinon is applied to control Chilo suppressalis. Due to the extensive application of insecticides in the rice paddies of the Caspian coasts of Iran, this investigation was carried out on the rice fields in order to obtain the necessary data and information on the concentration of insecticide residues. A total of 125 samples were taken from five areas of Amol township in 2007. Then, according to the analysis of variance procedures, the water samples were statistically analyzed after the spraying of diazinon. Results indicate that the insecticide was used frequently to control stem boring caterpillar of rice. The residuals of this toxic chemical were observed in the majority of stations from the day after the spraying until one to two months later. The greatest level of diazinon was observed in station 1 in amount of 1.14 ppm. This study revealed that the physical and chemical properties of the studied diazinon such as fumigation characteristic as well as the ecological conditions and soil type influence the reduction and eventual removal of the insecticides during the cultivation and harvest periods.     

Zinc availability in relation to selected soil properties in a crude oil polluted eutric tropofluvent

The study investigated zinc availability in relation to selected soil properties in a crude-oil-polluted Eutric Tropofluvent in Egbema, Southeastern Nigeria. For this purpose, three treatments have been applied: unpolluted soil, polluted without vegetation and polluted with vegetation with five replicates arranged in a randomized complete block design. Guided by transect sampling technique, soil sampling was carried out in June 2008. Soil samples were collected from the three different land units using soil auger at a depth of 0–20 cm. Standard laboratory procedures were adopted in analysing the soils. Soil generated data were subjected to analysis of variance and correlation analysis. Results showed highly significant variation (p = 0.01) in bulk density, porosity, silt: clay ratio, pH, effective cation exchange capacity, percent base saturation, total nitrogen, organic matter, available phosphorus, calcium: magnesium ratio and zinc. It was found that zinc was higher in crude oil polluted soils than in non-polluted soil and it was below critical limits. Zinc availability in relation to selected soil properties in the crude oil polluted soils indicated that clay and organic matter did not affect zinc availability, while pH and effective cation exchange capacity did. A study on zinc dynamics in crude-oil-polluted soils will certainly provide further information on the management of crude-oil-polluted soils since it is one of the key micronutrient for crop productivity.     

Assessment of airborne bacteria and fungi in an indoor and outdoor environment

Airborne indoor and outdoor bacteria and fungi were assessed during the spring season using conventional methods to investigate the enumeration and identification of airborne micro-organisms. This was determined through air quality sampling using the ‘open plate technique’. The air samples were collected during the spring season (March-May) from four different locations. Conventional enumeration of airborne micro-organisms relies on culture-based or microscopic methods. Although a culture-based analysis is most widely used for bio-aerosol, four public places located in urban residential areas were selected for indoor/outdoor air bio-pollutant measurement. The public places included kitchens, classrooms, recreational areas, laboratories. Public parks are an important facility associated with the environmental exposure of children. Cultivation and total microscopic enumeration methods were employed for the sample analysis. 26 groups of bacteria and fungi, either of human or environmental origin were detected. Environmental agents generally predominated while significantly higher counts were detected as the level of hygiene or standard of housing dropped. Seven genera of fungi, mainly members of the genus Aspergillum, were isolated from all residents. Bacteria shows higher growth numbers as opposed to the slow growing fungi. Sample collection and pretreatment, determination techniques and performance results are summarized and discussed.     

Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon

Granular activated carbon produced from palm kernel shell was used as adsorbent to remove copper, nickel and lead ions from a synthesized industrial wastewater.Laboratory experimental investigation was carried out to identify the effect of pH and contact time on adsorption of lead, copper and nickel from the mixed metals solution. Equilibrium adsorption experiments at ambient room temperature were carried out and fitted to Langmuir and Freundlich models. Results showed that pH 5 was the most suitable, while the maximum adsorbent capacity was at a dosage of 1 g/L, recording a sorption capacity of 1.337 mg/g for lead, 1.581 mg/g for copper and 0.130 mg/g for nickel. The percentage metal removal approached equilibrium within 30 min for lead, 75 min for copper and nickel, with lead recording 100 %, copper 97 % and nickel 55 % removal, having a trend of Pb²⁺ > Cu²⁺ > Ni²⁺. Langmuir model had higher R² values of 0.977, 0.817 and 0.978 for copper, nickel and lead respectively, which fitted the equilibrium adsorption process more than Freundlich model for the three metals.     

Study of mango biomass (Mangifera indica L) as a cationic biosorbent

Unfertilizable fruiting buds of mango plant Mangifera Indica L, an agrowaste, is used as a biomass in this study. The efficacy of the biosorbent was tested for the removal of lead, copper, zinc and nickel metal ions using batch experiments in single and binary metal solution under controlled experimental conditions. It is found that metal sorption increases when the equilibrium metal concentration rises. At highest experimental solution concentration used (150 mg/L), the removal of metal ions were 82.76 % for lead, 76.60 % for copper, 63.35 % for zinc and 59.35 % for nickel while at lowest experimental solution concentration (25 mg/L), the removal of metal ions were 92.00% for lead, 86.84 % for copper, 83.96 % for zinc and 82.29 % for nickel. Biosorption equilibrium isotherms were plotted for metal uptake capacity (q) against residual metal concentrations (C_f) in solution. The q versus C_f sorption isotherm relationship was mathematically expressed by Langmuir and Freundlich models. The values of separation factor were between zero and one indicating favourable sorption for four tested metals on the biosorbent. The surface coverage values were approaching unity with increasing solution concentration indicating effectiveness of biosorbent under investigation. The non-living biomass of Mangifera indica L present comparable biosorption capacity for lead, copper, zinc and nickel metal ions with other types of biosorbent materials found in literature and is effective to remove metal ions from single metal solutions as well as in the presence of other co-ions with the main metal of solution.     

Ethnic Place Identity Within A Parisian Neighborhood

The Goutte d'Or neighborhood of Paris has long been seen as an impoverished yet colorful quarter of the city. In recent years, it has also developed a reputation as a center for immigrants. Three populations now share the neighborhood: the European French, the Maghrebi immigrant population and their children, and the newest population of migrants from former Francophone colonies. This paper examines how the Goutte d'Or's social and ethnic identity is revealed in the built environment and in its social and economic activity. This neighborhood demonstrates how different communities and place identities coexist. It also shows how global networks of migration, exchange, and visits infuse local places. The Goutte d'Or distills many aspects of French immigrant identities, providing an example for increasing numbers of immigrant neighborhoods in France and across the world.     

组合导航中一种新息自适应卡尔曼滤波算法

全球定位系统/航位推算组合导航定位中,由于目标运动的不确定性,GPS接收机与DR器件接收的数据存在噪声,使预置目标运动模型通常很难得到较高跟踪精度,针对应用常规卡尔曼滤波进行组合导航解算由于噪声统计特性未知而引起滤波不稳定的问题,本文提出了一种基于新息序列的量测计算进行自适应估计的卡尔曼滤波算法。该算法通过对新息方差强度进行极大似然估计,将新息计算引入卡尔曼滤波器的增益计算,达到控制发散的目的。最后对改进的算法与一般卡尔曼滤波算法做了对比仿真试验分析,结果表明了改进算法的有效性。     

Scaling Effects on MODIS Band Ratio of 645 to 859 nm Aggregated from 250 m to 1 km Resolution: A Case Study in Yellow River Estuary

In this study, a theoretical model for studying the scaling effects on the two-band ratio of red to near-infrared band (TBRRN) is suggested. The model is used to explain the relationship between scaling error and local scale error; the results revealed that a special scale scaling procedure can be divided into a series smaller scale scaling procedures, and the total scaling error is the sum of the scaling error of these series’ smaller scale scaling procedure. Consequently, under the condition that the local scale is adequately fine, the total scale error at the target scale may be estimated accurately. In order to understand the mechanisms associated with scale in practical remote sensing, TBRRN data with 250 m and 1 km resolution is estimated from MODIS data at 645 and 859 nm, retrieved on September 1, 2009, in the Yellow River estuary, China. It is found that the TBRRN estimated from the 1 km resolution MODIS data is ~2.94 % smaller than as estimated from the 250 m MODIS data. The large scaling error distributes neither in the turbid waters, nor in the low suspended sediment regions, but instead in the high-low suspended sediment concentration transitional zone, which may be attributed to the spatial variable of suspended sediment in the transitional zone. This paper also points out that, owing to the importance of total scale error in achieving NASA’s mission in oceanic remote sensing, the way in which to conveniently and precisely estimate the total scale error of remote sensing parameters may potentially be an important topic in the field of oceanic remote sensing, both in present research and in the future.     

Impact of GLONASS pseudorange inter-channel biases on satellite clock corrections

GLONASS carrier phase and pseudorange observations suffer from inter-channel biases (ICBs) because of frequency division multiple access (FDMA). Therefore, we analyze the effect of GLONASS pseudorange inter-channel biases on the GLONASS clock corrections. Different Analysis Centers (AC) eliminate the impact of GLONASS pseudorange ICBs in different ways. This leads to significant differences in the satellite and AC-specific offsets in the GLONASS clock corrections. Satellite and AC-specific offset differences are strongly correlated with frequency. Furthermore, the GLONASS pseudorange ICBs also leads to day-boundary jumps in the GLONASS clock corrections for the same analysis center between adjacent days. This in turn will influence the accuracy of the combined GPS/GLONASS precise point positioning (PPP) at the day-boundary. To solve these problems, a GNSS clock correction combination method based on the Kalman filter is proposed. During the combination, the AC-specific offsets and the satellite and AC-specific offsets can be estimated. The test results show the feasibility and effectiveness of the proposed clock combination method. The combined clock corrections can effectively weaken the influence of clock day-boundary jumps on combined GPS/GLONASS kinematic PPP. Furthermore, these combined clock corrections can improve the accuracy of the combined GPS/GLONASS static PPP single-day solutions when compared to the accuracy of each analysis center alone.