Benthic foraminifera assemblages as elemental pollution bioindicator in marine sediments around fish farm (Vrgada Island,Central Adriatic,Croatia)

Effects on sediments of fish farming activity near Vrgada Island was analysed through living and total foraminiferal assemblages and concentration of major, minor and trace elements from three sediment cores. Elemental concentrations of sediments are in accordance with carbonate characteristics of the surrounding area and show mostly natural element variations between sampling locations and throughout the cores, with no significant increases due to fish farming activity. Only phosphorus concentration shows elevate values below the fish cage, assigned to fish pellets. Foraminiferal communities are dominated by epifaunal and stress tolerant species, while diversity indices point to normal marine conditions. The type of substrate and phosphorus content in sediments principally influence foraminiferal community composition, while other elemental concentrations have no perceptible effect on the assemblages. Some foraminiferal species Ammoniatepida, Ammoniabeccarii, Elphidiumcrispum, Elphidiummacellum and genus Haynesina are confirmed to be tolerant to elevated nutrient (phosphorus) content, while Ammonia parkinsoniana shows sensitivity to pollution. Postmortem processes cause decrease of foraminiferal density and species richness with core depth. All results point to negligible influence of fish farming and relatively stable environmental conditions at all sampling locations.     

Seasonal Water Storage Variations as Impacted by Water Abstractions: Comparing the Output of a Global Hydrological Model with GRACE and GPS Observations

Better quantification of continental water storage variations is expected to improve our understanding of water flows, including evapotranspiration, runoff and river discharge as well as human water abstractions. For the first time, total water storage (TWS) on the land area of the globe as computed by the global water model WaterGAP (Water Global Assessment and Prognosis) was compared to both gravity recovery and climate experiment (GRACE) and global positioning system (GPS) observations. The GRACE satellites sense the effect of TWS on the dynamic gravity field of the Earth. GPS reference points are displaced due to crustal deformation caused by time-varying TWS. Unfortunately, the worldwide coverage of the GPS tracking network is irregular, while GRACE provides global coverage albeit with low spatial resolution. Detrended TWS time series were analyzed by determining scaling factors for mean annual amplitude (f _GRACE) and time series of monthly TWS (f _GPS). Both GRACE and GPS indicate that WaterGAP underestimates seasonal variations of TWS on most of the land area of the globe. In addition, seasonal maximum TWS occurs 1 month earlier according to WaterGAP than according to GRACE on most land areas. While WaterGAP TWS is sensitive to the applied climate input data, none of the two data sets result in a clearly better fit to the observations. Due to the low number of GPS sites, GPS observations are less useful for validating global hydrological models than GRACE observations, but they serve to support the validity of GRACE TWS as observational target for hydrological modeling. For unknown reasons, WaterGAP appears to fit better to GPS than to GRACE. Both GPS and GRACE data, however, are rather uncertain due to a number of reasons, in particular in dry regions. It is not possible to benefit from either GPS or GRACE observations to monitor and quantify human water abstractions if only detrended (seasonal) TWS variations are considered. Regarding GRACE, this is mainly caused by the attenuation of the TWS differences between water abstraction variants due to the filtering required for GRACE TWS. Regarding GPS, station density is too low. Only if water abstractions lead to long-term changes in TWS by depletion or restoration of water storage in groundwater or large surface water bodies, GRACE may be used to support the quantification of human water abstractions.     

River loads of suspended solids, nitrogen, phosphorus and herbicides delivered to the Great Barrier Reef lagoon

Degradation of coastal ecosystems in the Great Barrier Reef (GBR) lagoon, Australia, has been linked with increased land-based runoff of suspended solids, nutrients and pesticides since European settlement. This study estimated the increase in river loads for all 35 GBR basins, using the best available estimates of pre-European and current loads derived from catchment modelling and monitoring. The mean-annual load to the GBR lagoon for (i) total suspended solids has increased by 5.5 times to 17,000ktonnes/year, (ii) total nitrogen by 5.7 times to 80,000tonnes/year, (iii) total phosphorus by 8.9 times to 16,000tonnes/year, and (iv) PSII herbicides is 30,000kg/year. The increases in river loads differ across the 10 pollutants and 35 basins examined, reflecting differences in surface runoff, urbanisation, deforestation, agricultural practices, mining and retention by reservoirs. These estimates will facilitate target setting for water quality and desired ecosystem states, and enable prioritisation of critical sources for management.     

Improvement of HVSR technique by self-organizing map (SOM) analysis

Data interpretation is one of the most important and thorny tasks in geosciences. Difficulties occur especially in non-invasive geophysical techniques and/or when the data that have to be analyzed are multidimensional, non-linear and highly noisy. Another important task is to ensure an efficient automatic data analysis, in order to allow a data interpretation as independent as possible from any a priori knowledge. This paper describes the post-processing application of a kind of neural network (self-organizing map, SOM) to the identification of the fundamental HVSR frequency of a given site. SOM results can be represented as two-dimensional maps, with a non-parametric mapping that projects the high dimensional original dataset in a fashion that provides both an unsupervised clustering and a highly visual representation of the data relationships. This innovative application of the SOM algorithm is presented with a case study related to the characterization of a mineral deposit.     

Problematic non-double-couple mechanism of the 2002 Amfilochia Mw5 earthquake, Western Greece

Two seismic agencies reported a very low double-couple percentage (DC%) of the Amfilochia earthquake, of about 30% and 60%, by Schweizerischer Erdbebendienst and Mediterranean Very Broadband Seismographic Network, respectively. Near-regional waveforms, carefully analyzed in this paper for the DC%, suggested a higher DC%, ranging from 75 to 100, dependent on the uncertainty of the source position (optimum value DC% = 93). Using a statistical F test, forward modeling of the near-regional data with a single-event low-DC% source yields a significantly worse waveform match. The fit of near-regional data can be further improved (although at the 90% significance level only) when considering a speculative two-event model. The same model, when viewed at the very-low frequency range, reaches the very low DC% values. However, two features make the two-event model unlikely: The two subevents strongly differ in their focal mechanism, and their mutual separation (3.5 s) is larger than the expected duration of this earthquake. Therefore, the two-source model appears to be nothing but an interesting equivalent representation of the non-DC model, providing some insight into the possible origin of the apparently low DC%. Preference is given to the simple interpretation, most clearly supported by the near-regional data, that the Amfilochia earthquake was an almost pure-shear event.     

Late Carboniferous foreland basin formation and Early Carboniferous stretching in Northwestern Europe: inferences from quantitative subsidence analyses in the Netherlands

The large thickness of Upper Carboniferous strata found in the Netherlands suggests that the area was subject to long-term subsidence. However, the mechanisms responsible for subsidence are not quantified and are poorly known. In the area north of the London Brabant Massif, onshore United Kingdom, subsidence during the Namurian–Westphalian B has been explained by Dinantian rifting, followed by thermal subsidence. In contrast, south and east of the Netherlands, along the southern margin of the Northwest European Carboniferous Basin, flexural subsidence caused the development of a foreland basin. It has been proposed that foreland flexure due to Variscan orogenic loading was also responsible for Late Carboniferous subsidence in the Netherlands. In the first part of this paper, we present a series of modelling results in which the geometry and location of the Variscan foreland basin was calculated on the basis of kinematic reconstructions of the Variscan thrust system. Although several uncertainties exist, it is concluded that most subsidence calculated from well data in the Netherlands cannot be explained by flexural subsidence alone. Therefore, we investigated whether a Dinantian rifting event could adequately explain the observed subsidence by inverse modelling. The results show that if only a Dinantian rifting event is assumed, such as is found in the United Kingdom, a very high palaeowater depth at the end of the Dinantian is required to accommodate the Namurian–Westphalian B sedimentary sequence. To better explain the observed subsidence curves, we propose (1) an additional stretching event during the Namurian and (2) a model incorporating an extra dynamic component, which might well explain the very high wavelength of the observed subsidence compared with the wavelength of the predicted flexural foreland basin.     

On Methods for the Light Curves Extrema Determination

We present two methods for the determination of moments of extrema and their errors appropriate for the analysis of light variations of variable objects. The method I is suitable for determination of times of extrema of non-periodical variables or objects, whose light curves vary. The method II is apt for O-C analyses of objects whose light curves are more or less repeating. Both methods are displayed on the analysis of BL Cam light variations and compared with the Kwee-van Woerden method.     

Carbon for Farmers: Assessing the Potential for Soil Carbon Sequestration in the Old Peanut Basin of Senegal

Carbon sequestration in soil organic matter of degraded Sahelian agro-ecosystems could play a significant role in the global carbon (C) uptake through terrestrial sinks while, simultaneously, contributing to sustainable agriculture and desertification control. The paper documents the results of a two-year pilot project in Senegal assessing real project opportunities with main emphasis on the West-Central Agricultural Region (Old Peanut Basin). Current total system C content in this region, calculated on the basis of in situ soil and biomass carbon measurements, amounted to 28 t ha^–1 with 11 t C ha^–1 in soils (0–20 cm) and 6.3 t C ha^–1 in trees. Potential changes in soil C, simulated with CENTURY for a 25-year period, ranged from –0.13 t C ha^–1 yr^–1 under poor management to +0.43 t C ha^–1 yr^–1 under optimum agricultural intensification. Simulated changes in crop yields varied from –62% to +200% under worst and best management scenarios respectively. Best management practices that generate the highest sequestration rates are economically not feasible for the majority of local smallholders, unless considerable financial support is provided. Especially when applied on a larger scale, such packages risk to undermine local, opportunistic management regimes and, in the long run, also the beneficiaries capacity to successfully adapt to their constantly changing environment.     

Transport of pharmaceutically active compounds in saturated laboratory columns

Occurrences of pharmaceutically active compounds in surface water and sewage water have been widely reported. Investigations show the presence of several classes of pharmaceuticals such as antirheumatics (e.g., diclofenac), analgesics (e.g., propyphenazone), and blood lipid regulators (clofibric acid), even in ground water. Compared to their occurrences in surface water, however, the reported incidences of drugs in ground water are much rarer. This may be due to the input, but also to transport processes and degradation in the aquifer. In field studies investigating ground water sampled at a bank infiltration site at Lake Tegel, Berlin, Germany, clofibric acid was found at concentrations up to 290 ng/L, and propyphenazone up to 250 ng/L, whereas concentrations of diclofenac were around the detection limit. The aim of this study was to investigate the ground water transport behavior of the pharmaceuticals clofibric acid, propyphenazone, and diclofenac with a laboratory soil column experiment. Results show that clofibric acid exhibits no degradation and almost no retardation (Rf = 1.1). Diclofenac (Rf = 2.0) and propyphenazone (Rf = 1.6) are retarded, whereas significant degradation was not observed for both pharmaceuticals under the prevailing conditions in the soil column. We conclude that the concentration distribution of the pharmaceuticals at the bank filtration site at Lake Tegel is controlled by sorption, desorption, and input variation, rather than by degradation.