Origin of the Zálesí U–Ni–Co–As–Ag/Bi deposit,Bohemian Massif,Czech Republic: fluid inclusion and stable isotope constraints

The Zálesí vein-type deposit is hosted by Early Paleozoic high-grade metamorphic rocks on the northern margin of the Bohemian Massif. The mineralization is composed of three main stages: uraninite, arsenide, and sulfide. The mineral assemblages formed at low temperatures (~80 to 130°C, locally even lower) and low pressures (<100 bars). The salinity of the aqueous hydrothermal fluids (0 to 27 wt.% salts) and their chemical composition vary significantly. Early fluids of the oldest uraninite stage contain a small admixture of a clathrate-forming gas, possibly CO₂. Salinity correlates with oxygen isotope signature of the fluid and suggests mixing of brines [δ ¹⁸O around +2‰ relative to standard mean ocean water (SMOW)] with meteoric waters (δ ¹⁸O around −4‰ SMOW). The fluid is characterized by highly variable halogen ratios (molar Br/Cl = 0.8 × 10⁻³ to 5.3 × 10⁻³; molar I/Cl = 5.7 × 10⁻⁶ to 891 × 10⁻⁶) indicating a dominantly external origin for the brines, i.e., from evaporated seawater, which mixed with iodine-enriched halite dissolution brine. The cationic composition of these fluids indicates extensive interaction of the initial brines with their country rocks, likely associated with leaching of sulfur, carbon, and metals. The brines possibly originated from Permian–Triassic evaporites in the neighboring Polish Basin, infiltrated into the basement during post-Variscan extension and were finally expelled along faults giving rise to the vein-type mineralization. Cenozoic reactivation by low-salinity, low-δ ¹⁸O (around −10‰ SMOW) fluids of mainly meteoric origin resulted in partial replacement of primary uraninite by coffinite-like mineral aggregates.     

The Western Bohemia/Vogtland Region in the Light of the Webnet Network

The local network of digital seismic stations WEBNET monitors the seismic activitv of practically the whole region of Western Bohemia/Vogtland swarms. The network consists of ten short-period stations and one very broadband station. The paper describes the configuration of the network, instrumental equipment and the basic parameters of the stations. The method of and formula for computing the local magnitudes from the WEBNET and KRASLICE seismograms are also given. Based on continuous WEBNET observations in the period 1995-1999, we were able to improve the model of temporal and spatial energy release in the region, the principal characteristics of which are summarised in the paper. Apart from direct P and S waves, the WEBNET seismograms also contain other significant P- and S-type waves, provisionally interpreted as reflected PxP, SxS and SxP waves. The fundamental characteristics of these waves are given in the paper, and tentative mechanisms of their origination are discussed. The large residua in the travel times of the P and S waves, and the discrepancies in the seismograms recorded at stations located east of the principal focal zone are pointed out.     

Dynamics of Stream Water Quality during Snowmelt and Rainfall – Runoff Events in a Small Agricultural Catchment

Surface water quality can vary a lot with fluctuating discharge during a Rainfall – runoff event. This paper uses a set of hydrological and hydrochemical variables to explain concentration–discharge loops and hysteresis of ${\rm NO}_{3}^{- } $ , ${\rm NH}_{4}^{ + } $ and total suspended solids in a brook dewatering a small upland agricultural catchment in the Czech Republic. Our study is based on data collected by a continuous monitoring approach provided by an automatic ISCO sampler both from snow thawing and rainfall – runoff events. Methods of correlation, regression and principal component analysis (PCA) were employed to reveal possible relationships among the variables. For ${\rm NO}_{3}^{- } $ and ${\rm NH}_{4}^{ + } $ , we found several types of concentration–discharge loops due to the loop rotation direction and also the loop curvature shape, in mutual combinations, no matter which type of a hydrological event it was related to. PCA indicated that ${\rm NO}_{3}^{- } $ loops correlated mostly with the length of a rising hydrograph limb and with the slope of the initial phase of a falling hydrograph limb, 5‐day amount of precipitation and runoff coefficient. In case of ${\rm NH}_{4}^{ + } $ , the concentrations usually increased with elevated discharge, whereas PCA did not detect any closer linkages. For suspended solids, an unambiguous positive monotonic relationship was discovered. Although no definite pattern was found, this study showed the necessity of a continuous water quality monitoring system as an approach for capturing and understanding relationships between solute concentrations and runoff formation for tracing and modelling catchment pollution sources and describing transport processes.     

A radar survey of M- and X-class asteroids

We observed ten M- and X-class main-belt asteroids with the Arecibo Observatory's S-band (12.6 cm) radar. The X-class asteroids were targeted based on their albedos or other properties which suggested they might be M-class. This work brings the total number of main-belt M-class asteroids observed with radar to 14. We find that three of these asteroids have rotation rates significantly different from what was previously reported. Based on their high radar albedo, we find that only four of the fourteen—16 Psyche, 216 Kleopatra, 758 Mancunia, and 785 Zwetana—are almost certainly metallic. 129 Antigone has a moderately high radar albedo and we suggest it may be a CH/CB/Bencubbinite parent body. Three other asteroids, 97 Klotho, 224 Oceana, and 796 Sarita have radar albedos significantly higher than the average main belt asteroid and we cannot rule out a significant metal content for them. Five of our target asteroids, 16 Psyche, 129 Antigone, 135 Hertha, 758 Mancunia, and 785 Zwetana, show variations in their radar albedo with rotation. We can rule out shape and composition in most cases, leaving variations in thickness, porosity, or surface roughness of the regolith to be the most likely causes. With the exception of 129 Antigone, we find no hydrated M-class asteroids (W-class; Rivkin, A.S., Howell, E.S., Lebofsky, L.A., Clark, B.E., Britt, D.T., 2000. Icarus 145, 351-368) to have high radar albedos.     

Ground-air temperature tracking and multi-year cycles in the subsurface temperature time series at geothermal climate-change observatory

Long-term observations of air, near-surface (soil) and ground temperatures, collected between 1994 and 2011, monitored in the Geothermal Climate Change Observatory at Spo?ilov, Prague (GCCO) are analyzed to better understand the relationship between these quantities and to describe the mechanism of heat transport at the land-atmosphere boundary layer. The 17 years long monitoring series provided a surprisingly small mean ground-air temperature offset of only 0.31 K with no clear annual course and with the offset value changing irregularly even on a daily scale. Such value is substantially lower than similar values (1–2 K and more) found elsewhere, but it may be well characteristic for a mild temperate zones, when all so far available information referred rather to more southern locations. As many other observed geophysical data, temperature time series consist of a systematic pattern (usually a set of identifiable components) contaminated by random noise, which makes the identification of the proper pattern difficult. To identify the existing systematic patterns (cycles) of the temperature-time series at several depth levels in the investigated depth interval 0–40 m, the observed data were processed with the help of the Fast Fourier Transform (FFT) and Recurrence Quantification Interval (RQI) analysis. The latter represents recently developed powerful technique to uncover hidden periodicities in a noisy time environment. At low frequency band the RQI may provide far finer resolution than the conventional FFT technique. The results proved considerable similarity for all investigated depth levels. In addition to the annual wave all measured series proved to have a more complex pattern including predominantly 8-year and 11 years long periodicities. The results were compared with similar analysis of the meteorological air temperature series as well as with the results of other similar studies. The potential dynamics explaining the occurrence of the 8-year wave is briefly discussed.     

Analysis of uncertainties in regional climate model outputs over the Czech Republic

In this study we present results of uncertainty analysis in eight regional climate model (RCM) outputs over the area of the Czech Republic. The RCM simulations come from the EU 5th Framework program project PRUDENCE (Prediction of Regional scenarios and Uncertainties for Defining EuropeaN Climate change risks and Effects). Using the analysis of variance we have found that the main source of uncertainty in projected changes of mean seasonal air temperature is the driving global climate model. In case of precipitation changes, the RCM is the largest source of uncertainty in all seasons except for the spring. With the second method, the Reliability Averaging method, we have focused on the uncertainty coming from the RCM itself. The results of both methods showed that the relative contribution of the regional climate model to the uncertainty of simulated mean seasonal air temperature and precipitation changes is largest in summer and smallest in winter.     

Magnetostratigraphy and fold tests from Račiška pečina and Pečina v Borštu caves (Classical Karst,Slovenia)

Clastic and chemogenic cave sediments were sampled and analyzed from Račiška pečina and Pečina v Borštu caves of southwestern Slovenia. Samples were subjected to both thermal and alternating field demagnetization; specimens belonging to the same sample of the same layer produce identical results. Unblocking temperatures of 540 to 560°C on average suggests magnetite as the principal carrier of magnetization. These directions also pass a reversals test indicating the demagnetization results are free of secondary overprints and have adequately averaged out paleosecular variation. Normally magnetized clays containing fauna belonging to the MN17 mammal biozone at a depth of ∼ 4 m in Račiška pecina cave indicate these clays were deposited at the beginning of the Olduvai subchron (1.95 Ma). Correlation with the Geomagnetic Polarity Time Scale (GPTS) indicates the base of the speleothems in Račiška pečina terminate in the upper part of subchron C2An.3n with numerous breaks in deposition, lasting up to 250 ka and more. Therefore rates of speleothem growth cannot be calculated. Fold tests on dome-like stalagmites of differing sizes and ages (Pleistocene, Pliocene) from the two caves indicate the domelike structures are primary.