A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.     

Model of the W3(OH) Environment Based on Data for Both Maser and “Quasi-Thermal” Methanol Lines

In studies of the environment of massive young stellar objects, recent progress in both observations and theory allows a unified treatment of data for maser and quasi-thermal lines. Interferometric maser images provide information on the distribution and kinematics of masing gas on small spatial scales. Observations of multiple masing transitions provide constraints on the physical parameters.Interferometric data on quasi-thermal molecular lines permits an investigation of the overall distribution and kinematics of the molecular gas in the vicinity of young stellar objects, including those which are deeply embedded. Using multiple transitions of different molecules, one can obtain good constraints on the physical and chemical parameters. Combining these data enables the construction of unified models, which take into account spatial scales differing by orders of magnitude.Here, we present such a combined analysis of the environment around the ultracompact HII region in W3(OH). This includes the structure of the methanol masing region, physical structure of the near vicinity of W3(OH), detection of new masers in the large-scale shock front and embedded sources in the vicinity of the TW young stellar object.     

Reproductive life history stages sensitive to oil and naphthalene in Atlantic croaker

The reproductive effects of chronic exposure to water-soluble fractions (WSF) of diesel fuel oil and naphthalene in female Atlantic croaker during critical periods of their reproductive life history were investigated. Fish were repeatedly exposed to WSF of oil (2.5 or 5%) or naphthalene (0.5 or 1.0 ppm) for 5 or 8 weeks. Both pollutants blocked sexual maturation in some fish and impaired ovarian recrudescence in others. The majority of the oocytes in exposed fish were undeveloped and widespread oocyte atresia was evident at higher concentrations of these polycyclic aromatic hydrocarbons (PAH). The disruption of ovarian growth and oocyte development in croaker after PAH exposure was associated with alterations in reproductive endocrine function at multiple sites on the hypothalamus-pituitarygonadal axis. A third period of increased sensitivity to xenobiotics was observed during final oocyte maturation.     

Stable isotope studies of fluid inclusions in speleothems and their paleoclimatic significance

Fluid inclusions found trapped in speleothems (cave deposited travertine) are interpreted as samples of seepage water from which enclosing calcium carbonate was deposited. The inclusions are assumed to have preserved their D/H ratios since the time of deposition. Initial ¹⁸O/¹⁶O ratios can be inferred from δD because rain- and snow-derived seepage waters fall on the meteoric water line (δD = 8δ¹⁸O + 10). Estimates of temperature of deposition of the carbonate can be calculated from inclusion D/H ratios and δ¹⁸O of enclosing calcite in Pleistocene speleothems. For most speleothems investigated (0–200,000 yr old) δ¹⁸O of calcite appears to have decreased with increasing temperature of deposition indicating that the dominant cause of climate-dependent change in δ¹⁸O of calcite was the change in K_cw, the isotope fractionation equilibrium constant, with temperature; δ¹⁸O of meteoric precipitation generally increased with increasing temperature, but not sufficiently to compensate for the decrease in K_cw.     

The alignment of clusters using large-scale simulations

The alignment of clusters of galaxies with their nearest neighbours and between clusters within a supercluster is investigated using simulations of 512³ dark matter particles for ΛCDM and τ CDM cosmological models. Strongly significant alignments are found for separations of up to 15  h ⁻¹ Mpc in both cosmologies, but for the ΛCDM model the alignments extend up to separations of 30  h ⁻¹ Mpc. The effect is strongest for nearest neighbours, but is not significant enough to be useful as an observational discriminant between cosmologies. As a check of whether this difference in alignments is present in other cosmologies, smaller simulations with 256³ particles are investigated for four different cosmological models. Because of poor number statistics, only the standard CDM model shows indications of having different alignments from the other models.     

Seasonal dynamics of water and nutrient fluxes in an agricultural peatland

The American cranberry (Vaccinium macrocarpon Ait.) is an important part of the cultural heritage and economy of Southeastern Massachusetts, yet water quality concerns and wetland protection laws challenge its commercial production. Here, we report inputs and outputs of water, nitrogen (N), and phosphorus (P) for a 2.12‐ha cranberry bed over a 2‐year period from 2013 to 2015. Water‐budget analysis indicated that precipitation contributed 40%, floodwater 37%, irrigation 15%, and groundwater 8% of water inputs to the cranberry bed. Minor annual variation in surface water discharge (~90 mm·year^?1 or 3%) contrasted with large decreases in net (= outputs ? inputs) nutrient export, from 16.2 to 9.1 kg N·ha^?1·year^?1 for total (dissolved + suspended particulate) nitrogen (TN) and from 3.34 to 1.47 kg P·ha^?1·year^?1 for total phosphorus (TP) between Years 1 and 2. Annual variation in net TN and TP export was tied to decreases in spring and summer nutrient export and controlled by the combined effects of fertilizer management, soil biogeochemistry, and hydrology. The relatively high spring TN export in Year 1 was associated with coincident increases in soil temperature and rainfall. A second factor was the timing of fertilizer application, which occurred 1 day prior to a major summer storm (i.e., third largest daily rainfall since 1926) and was responsible for up to 15% and 9% of the Year 1 TN and TP export, respectively. Nutrient budgets, which balanced water and fertilizer inputs with water, fruit, and vegetative outputs, were consistent with the burial of 21.6 kg N·ha^?1·year^?1 and 7.27 kg P·ha^?1·year^?1. Field measurements indicated that burial would increase TN and TP in the shallow (0–5 cm) rooting zone by 14% and 6%, respectively, which seemed plausible based on the relatively young age of the bed (4–5 years) and new root growth patterns in Vaccinium plants.     

Tectonothermal history of the basement rocks in the western zone of the North China Craton and its tectonic implications

The basement of the North China Craton can be divided into the eastern, central and western zones, based on lithological, structural, metamorphic and geochronological data. The western zone comprises two different petrotectonic units: Archaean tonalitic–trondhjemitic–granodioritic (TTG) grey gneisses and metamorphic mafic rocks, and Palaeoproterozoic khondalite series. The former is characterized by isobaric cooling (IBC)-type anticlockwise P–T paths in the north-northwestern part of the zone and near-isothermal decompression (ITD)-type clockwise P–T paths in the eastern part, adjacent to the central zone. On the other hand, the tectonothermal evolution of Palaeoproterozoic khondalite series rocks is characterized exclusively by nearly isothermal decompression following the peak of metamorphism and then cooling, defining clockwise P–T paths. The Archaean TTG gneisses and associated mafic rocks with anticlockwise metamorphic P–T paths reflects an origin related to underplating and intrusion of mantle-derived magmas which may be derived from mantle plumes. They represent a late Archaean continental block in the western part of the North China Craton. The Palaeoproterozoic khondalite series rocks represent passive continental margin deposits. They were metamorphosed and deformed in the late Palaeoproterozoic during the amalgamation of the western continental block with another continental block in the east part of the North China Craton. The ITD-type clockwise P–T–t paths of the Palaeoproterozoic khondalite series rocks record the tectonothermal histories of the collision of the western and eastern continental blocks which resulted in the final assembly of the North China Craton at c. 1800 Ma.     

Evolutionary Processes in Low-Mass Binary Systems

We consider the evolution of certain low-mass binaries, incorporating models of (a) internal evolution, (b) tidal friction, (c) dynamo activity driven by an elementary α,Ω dynamo, (d) stellar wind driven by the activity, and (e) magnetic braking as a consequence of wind and poloidal dynamo-generated magnetic field. In some circumstances the stellar wind is found to remove mass on a nuclear timescale, as is necessary to explain some observed systems. We can hope that various uncertainties in the model may be clarified by a careful comparison of the models with such observed quantities as rotation periods. These are modified by processes (a), (b) and (e). Assuming that stellar evolution is slow, rotation rate should in some circumstances represent a balance between magnetic braking trying to slow the star down and tidal friction trying to spin it up. Preliminary attempts are promising, but indicate that some fine tuning is necessary. When there is a third body present, in an orbit which is inclined but not necessarily of short period, the eccentricity of a close binary can be strongly modified by ‘Kozai cycles’. We show that this may complicate attempts to account for spin rates of stars in close binaries.