Experimental determination of carbon isotope fractionation between CaCO3 and graphite

Carbon isotopic exchange between graphite and three polymorphs of CaCO₃ was investigated at temperatures of 600-1400 °C and at pressures from 1.4 to 2.3 GPa. Fractionation factors at all temperatures were determined by the partial exchange treatment of Northrop and Clayton (1966).Graphite starting material for the majority of the experiments was milled in water for 20-25 h, producing aggregates of nanosheets. The sheets range in width from 50 to 1000 nm and in thickness from 20 to 30 nm, and they retain hexagonal symmetry.Isotopic exchange appears to be the sum of surface exchange and interior exchange. At 1100-1400 °C, interior exchange exceeded surface exchange, probably by a combination of grain growth, as determined by increase in crystallite size, recrystallization, as observed in FESEM images, and diffusion. In some runs at 1200 and 1400 °C with an isotopic contrast between the initial graphite and calcite of close to 50‰, equilibrium fractionation was actually overstepped due to a kinetic effect. A weighted regression of fractionation factors from the high-temperature runs yields the line of equilibrium interior exchange:

     

Natural aggregates in the performance and durability of concrete: chemical characteristics

This article continues from the earlier feature in Geology Today (2011, v.27, n.4) and looks at the influence of chemical reactivity within concrete due to the presence of unsound aggregates or deleterious material incorporated in the aggregate used in the concrete mix. Some of the more disruptive problems from chemical unsoundness come from the presence of chlorides, which cause rusting in reinforced concrete or, sulphate attack from ground waters. Both of these reactions are relatively common in Britain. Alkali–silica reactions with aggregates and cement is not too prevalent in Britain but can be very prevalent and disruptive elsewhere in the world.     

Cavity expansion in cross‐anisotropic rock

Schistous rock can be considered—in a first approximation—as cross‐anisotropic linear elastic material. The determination of the corresponding material constants on the basis of the laboratory investigation of rock samples often fails, as the extraction of appropriate cores proves to be unfeasible (the cores disintegrate if the schistosity is pronounced). In this paper a new method is presented to determine the material constants of a linear elastic cross‐anisotropic rock on the basis of cavity expansion field tests, e.g. with a radial jack. To this purpose, an analytic approximation for the deformation of a hydrostatically loaded cylindrical cavity in cross‐anisotropic rock is derived which serves to the inverse analysis of the material parameters. Copyright © 2010 John Wiley & Sons, Ltd.     

Oxygen and hydrogen isotope fractionation in serpentine-water and talc-water systems from 250 to 450 °C, 50 MPa

Oxygen and hydrogen isotope fractionation factors in the talc-water and serpentine-water systems have been determined by laboratory experiment from 250 to 450 °C at 50 MPa using the partial exchange technique. Talc was synthesized from brucite + quartz, resulting in nearly 100% exchange during reaction at 350 and 450 °C. For serpentine, D-H exchange was much more rapid than ¹⁸O-¹⁶O exchange when natural chrysotile fibers were employed in the initial charge. In experiments with lizardite as the starting charge, recrystallization to chrysotile enhanced the rate of ¹⁸O-¹⁶O exchange with the coexisting aqueous phase. Oxygen isotope fractionation factors in both the talc-water and serpentine-water systems decrease with increasing temperature and can be described from 250 to 450 °C by the relationships: 1000 ln  = 11.70 × 10⁶/T² − 25.49 × 10³/T + 12.48 and 1000 ln  = 3.49 × 10⁶/T² − 9.48 where T is temperature in Kelvin. Over the same temperature interval at 50 MPa, talc-water D-H fractionation is only weakly dependent on temperature, similar to brucite and chlorite, and can be described by the equation: 1000 ln = 10.88 × 10⁶/T² − 41.52 × 10³/T + 5.61 where T is temperature in Kelvin. Our D-H serpentine-water fractionation factors calibrated by experiment decrease with temperature and form a consistent trend with fractionation factors derived from lower temperature field calibrations. By regression of these data, we have refined and extended the D-H fractionation curve from 25 to 450 °C, 50 MPa as follows: 1000 ln  = 3.436 × 10⁶/T² − 34.736 × 10³/T + 21.67 where T is temperature in Kelvin. These new data should improve the application of D-H and ¹⁸O-¹⁶O isotopes to constrain the temperature and origin of hydrothermal fluids responsible for serpentine formation in a variety of geologic settings.     

On a transformation of the differential equations of the lunar theory

This work contains a transformation of Hill-Brown differential equations for the coordinates of the satellite to a type which can be integrated in a literal form using an analytical programming language. The differential equation for the parallax of the satellite is also established. Its use facilitates the computation of Hill's periodic intermediary orbit of the satellite and provides a good check for the expansion of the coordinates and frequencies. The knowledge of the expansion of the parallax facilitates the formation of differential equations for terms with a given characteristic. These differential equations are put into a form which favors the solution by means of iteration on the computer. As in the classical theory we obtain the expansions of the coordinates and of the parallax in the form of trigonometric series in four arguments and in powers of the constants of integration. We expand the differential operators into series in squares of the constants of integration. Only the terms of order zero in these expansions are employed in the integration of the differential equations. The remaining terms are responsible for producing the cross-effects between the perturbations of different order. By applying the averaging operator to the right sides of the differential equations we deduce the expansion of the frequencies in powers of squares of the constants of integration.Basic Notations f the gravitational constant - E the mass of the planet - M the mass of the satellite - t dynamical time - x, y, z planetocentric coordinates of the satellite - u x+y–1 - s x–y–1 - the planetocentric distance of the satellite - w 1/ - ₀ the variational part of - w ₀ the variational part ofw, - n the mean daily sidereal motion of the satellite - a the mean semi-major axis of the satellite defined by means of the Kepler relation:a ³ n ²=f(E+M) - a the mean semi-major axis defined as the constant factor attached to the variational solution - e the constant of the eccentricity of the satellite - the sine of one half the orbital inclination of the satellite relative to the orbit of the sun - c(n–n) the anomalistic frequency of the satellite - c ₀ the part ofc independent frome,e, and - g(n–n) the draconitic frequency of the satellite, - g ₀ the part ofg independent frome,e, and - exp (n–n)t–1 - D d/d - e the eccentricity of the solar planetocentric orbit - a the semi-major axis of the solar orbit - n the mean daily motion of the sun in its orbit around the planet - m n/(n–n) - a/a-the parallactic factor - the disturbing function     

The sedimentary and tectonic evolution of the Amur River and North Sakhalin Basin: new evidence from seismic stratigraphy and Neogene–Recent sediment budgets

The North Sakhalin Basin in the western Sea of Okhotsk has been the main site of sedimentation from the Amur River since the Early Miocene. In this article, we present regional seismic reflection data and a Neogene–Recent sediment budget to constrain the evolution of the basin and its sedimentary fill, and consider the implications for sediment flux from the Amur River, in particular testing models of continental‐scale Neogene drainage capture. The Amur‐derived basin‐fill history can be divided into five distinct stages: the first Amur‐derived sediments (>21–16.5 Ma) were deposited during a period of transtension along the Sakhalin‐Hokkaido Shear Zone, with moderately high sediment flux to the basin (71 Mt year^?1). The second stage sequence (16.5–10.4 Ma) was deposited following the cessation of transtension, and was characterised by a significant reduction in sediment flux (24 Mt year^?1) and widespread retrogradation of deltaic sediments. The third (10.4–5.3 Ma) and fourth (5.3–2.5 Ma) stages were characterised by progradation of deltaic sediments and an associated increase in sediment flux (48–60 Mt year^?1) to the basin. Significant uplift associated with regional transpression started during this time in southeastern Sakhalin, but the north‐eastward propagating strain did not reach the NE shelf of Sakhalin until the Pleistocene (<2.5 Ma). This uplift event, still ongoing today, resulted in recycling of older deltaic sediments from the island of Sakhalin, and contributed to a substantially increased total sediment flux to the adjacent basinal areas (165 Mt year^?1). Adjusted rates to discount these local erosional products (117 Mt year^?1) imply an Amur catchment‐wide increase in denudation rates during the Late Pliocene–Pleistocene; however, this was likely a result of global climatic and eustatic effects, combined with tectonic processes within the Amur catchment and possibly a smaller drainage capture event by the Sungari tributary, rather than continental‐scale drainage capture involving the entire upper Amur catchment.     

A possible dependence of tectonic strength on the age of the crust in Asia

In Asia, the intensity and style of active tectonics appears to depend on the age of the last orogenic activity. The shields have remained essentially undeformed during the India-Eurasian collision, but Paleozoic and Mesozoic orogenic belts apparently have been reactivated by this collision, with a suggestion of greater reactivation and more diffuse deformation of the younger belts. If the greater observed heat flow in regions of more recent orogenic activity reflects, at least in part, a greater heat flow from the mantle beneath the younger belts, then the temperatures in the mantle beneath the younger belts should be higher than beneath older belts and shields. Because of the strong dependence on temperature of the creep strength of minerals, particularly of olivine, the crust and mantle beneath the hotter, younger belts should be much weaker than those beneath older belts. This difference in temperature, and consequent difference in strength, may be the cause of the greater reactivation of younger belts.     

Producer Services Research in the United Kingdom

This paper reviews recent research in the United Kingdom on producer services and suggests directions for further research. A recurrent theme in UK-based geographic research into producer services is the role of service activities, establishments, and trade in uneven development of the UK space economy, a role manifested in uneven provision and quality of services in peripheral regions. During the 1980s, overall growth in demand for producer services and the rapid rise in metropolitan London real estate costs reduced London's dominance, but these trends moderated by the end of the decade. In the absence of adequate government statistics, regular and standardized surveys are needed to compile a time series of service change in the United Kingdom. Directions for continued empirical research include the role of producer services in innovation and technology transfer, the implications of information technology for the location of employment in the sector, and the impacts of productivity increases on employment and wages.     

南极考察站废弃物对贼鸥食性的影响

对南极乔治王岛菲尔德斯半岛贼鸥的食性生态进行观测与研究 ,结果表明 ,本区贼鸥的食物结构中 ,自然生态类食物百分组成 ,棕贼鸥 (C .s.lonnbergi)占 63.4% ,灰贼鸥 (C .maccormic ki)占 77.8%。同期 ,取自考察站的人类废弃物中垃圾食物的百分组成分别为 36.6%和 2 2 .3%。贼鸥食性对考察站废弃物有一定的依赖性 ,与本区环境质量下降 ,尤其考察站对废弃物的疏于管理有着直接的关系。由此表明 ,强化南极考察人员环境意识 ,建立封闭式废弃物管理系统 ,对保护南极环境有重要意义