Tritium profiles in the Weddell Sea

Tritium data were collected between 1985 and 1987 on several cruises of the German research icebreaker “Polarstern” to the Weddell Sea. Maximum tritium concentrations in the surface waters are of the order of 200 mTU. The minimum values observed in the Weddell Sea Deep Water at about 1000 m depth are about 15–40 mTU. The bottom waters show tritium concentrations of about 70–100 mTU in the central gyre, increasing to about 120 mTU in the northwestern corner of the Weddell Sea. The overflowing Ice Shelf Water observed on the continental slope west of the Filchner Depression has tritium concentrations close to those of the surface waters, indicating rapid renewal of this water mass. The data reflect the rapid renewal of the bottom waters in the northwestern corner of the Weddell Sea and the mixing of bottom water from this boundary current into the bottom waters of the central Weddell Gyre.     

The alleged kimberlite-carbonatite relationship: evidence from ilmenite and spinel from Premier and Wesselton mines and the Benfontein sill,South Africa

Carbonate-rich, SiO₂-poor residua are developed in some kimberlites solidifying as ocelli, layers, or discrete dikes which satisfy petrographic definitions of carbonatite. Arguments that these rocks have mineralogies, antecedents, and comagmatic rocks differing from those of the carbonatites in alkaline rock complexes, including the specific observation that kimberlites and carbonatites contain ilmenites and spinels of different composition, have been used to refute the alleged kimberlite-carbonatite relationship. New microprobe analyses of ilmenites and spinels from carbonate-rich rocks associated with kimberlites in three South African localities correspond to spinels and ilmenites of carbonatites from alkalic complexes, or have characteristics intermediate between those of carbonatites and kimberlites. The ilmenites are distinguished from kimberlite ilmenites by higher MnO, FeTiO₃, and Nb₂O₅, and by negligible Cr₂O₃. The spinels are distinguished from kimberlite spinels by their Al₂O₃ and Cr₂O₃ contents. There is clearly a genetic relationship between the kimberlites and the carbonate-rich rocks, despite the observation that their ilmenites and spinels are distinctly different, which indicates that the same observation is not a valid argument against a petrogenetic relationship between kimberlites and carbonatites. These rocks are among the diverse products from mantle processes influenced by CO₂, and we believe that the petrogenetic links among them are forged in the upper mantle. We see insufficient justification to deny the name carbonatite to carbonate-rich rocks associated with kimberlites if they satisfy the petrographic definition in terms of major mineralogy.     

Influence of capture stress, salinity and reproductive status on zinc associated with metallothionein-like proteins in the livers of three marine teleost species

The influence of capture stress, salinity and reproductive status on zinc associated with the metallothionein-like (MT-like) proteins in the livers of three marine teleost species was investigated. In striped mullet, Mugil cephalus L., the zinc associated with the MT-like protein, as determined by gel-permeation HPLC, increased significantly from approximately 102 to 1162 nmol zinc bound/g wet wt 7 days following capture in the field, handling, transportation to the laboratory and transfer to holding tanks. Significant increases were also observed following exposure to reduced salinity for 7 days. Smaller increases were observed in cultured red drum, Sciaenops ocellatus, livers following exposure to reduced salinity and physical trauma for 7 days. Finally, there was approximately a 2·5-fold increase in the zinc associated with the MT-like protein in livers of female spotted seatrout, Cynoscion nebulosus, collected during the reproductive season compared to regressed animals. These findings emphasize the need for establishing the natural fluctuations in MT levels as well as the response to common physical environmental variables before measurement of MT can be used reliably as a biochemical indicator of environmental contamination.     

Design of a 3D Chirp Sub-bottom Imaging System

Chirp sub-bottom profilers are marine acoustic devices that use a known and repeatable source signature (1–24 kHz) to produce decimetre vertical resolution cross-sections of the sub-seabed. Here the design and development of the first true 3D Chirp system is described. When developing the design, critical factors that had to be considered included spatial aliasing, and precise positioning of sources and receivers. Full 3D numerical modelling of the combined source and receiver directivity was completed to determine optimal source and receiver geometries. The design incorporates four source transducers (1.5–13 kHz) that can be arranged into different configurations, including Maltese Cross, a square and two separated pairs. The receive array comprises 240 hydrophones in 60 groups whose group-centres are separated by 25 cm in both horizontal directions, with each hydrophone group containing four individual elements and a pre-amplifier. After careful consideration, it was concluded that the only way to determine with sufficient accuracy the source–receiver geometry, was to fix the sources and receivers within a rigid array. Positional information for the array is given by a Real Time Kinematic GPS and attitude system incorporating four antennas to give position, heading, pitch and roll. It is shown that this system offers vertical positioning accuracy with a root-mean-square (rms) error less than 2.6 cm, while the horizontal positioning rms error was less than 2.0 cm. The system is configured so that the Chirp source signature can be chosen by software aboard the acquisition vessel. The complete system is described and initial navigational and seismic data results are presented. These data demonstrate that the approach of using fixed source-receiver geometry combined with RTK navigation can provide complete 3D imaging of the sub-surface.     

Tectonic and magmatic ridges in the eltanin fault system,South Pacific

A Seabeam reconnaissance of the 400 km-long fast-slipping (88 mm yr^-1) Heezen transform fault zone and the 55 km-long spreading center that links it to Tharp transform defined and bathymetrically described several types of ridges built by tectonic uplift and volcanic construction. Most prominent is an asymmetric transverse ridge, at which abyssal hills adjacent to the fault zone have been raised 2–3 km above normal rise-flank depths. Topographic and petrologic evidence suggests that this uplift, which has produced a 5400 m scarp from the crest of the ridge to the floor of a 10 km-wide transform valley, is caused by rapid serpentinization of upper mantle which has been exposed to hydrothermal circulation by fault-zone fracturing of an unusually thin crust. Transverse ridges have been thought atypical of fast-slipping transforms. One class of volcanic ridge more common at these sites is the overshot ridge, formed by prolongation of spreading-center rift zones obliquely across the transform. Overshot ridges are well developed at Heezen transform, especially at the eastern end where an eruptive rift zone extending 60 km from the southern tip of the East Pacific Rise has built a transform-parallel ridge that fills the eastern transform valley. Obliteration of fault-zone structure by ridges overshooting from the spreading center intersections means that the topography of the aseismic fracture zones is not just inherited from that of the active transform fault zone. The latter has several en echelon and overlapping fault traces, linked by short oblique spreading axes that generally form pull-apart basins rather than volcanic ridges. Interpretation of the origin and pattern of the fault zone's tectonic and volcanic relief requires refinement of the plate geography and history of this part of the Pacific-Antarctic boundary, using new Seabeam and magnetic traverses to supplement and adjust the existing geophysical data base.     

Basement imaging with Side-Looking Seismics

The multistreamer Side-Looking Seismic system presented in this paper makes a sonograph of uncovered or buried crustal topography, thus revealing the structural fabric of the oceanic basement, even when this is covered with a sedimentary layer. Major elements of the system are an airgun as a sound source, five single-channel parallel streamers and two minicomputers for signal capture and processing.The system is used simultaneously for enhanced single-channel seismic profiling and for side-looking seismics. A vertical section with an improved signal-to-noise ratio and a suppression of side-echoes is produced on a digital seismic recorder. Primary side-looking seismic output in the form of 5 profiles with different angles of incidence is obtained within 10 seconds. This part of the processing can be done in real time.In sediment-covered areas the low frequencies used cause the slanted profiles (the side beams in the primary output) to be side-looking sonar images of buried topography. The projection process yielding final side-looking output corrects for slant range deformation caused by the water column and, if necessary, for deformation caused by refraction within the sedimentary column. The result approaches a conformal map of the structure of the traversed basement. Swath width is mainly determined by water depth and refraction effects in the sediment. In Madeira abyssal plain a swath width of 8000 m was attained in a water depth of 5000 m.Within the swath, oceanic basement structures are recognized in the form of elongate more or less parallel reflectors. They are interpreted as buried spreading topography. The lack of side-echoes within fracture zones combined with typical wall signatures can be used to trace fracture zones. These features are demonstrated for an area in Madeira abyssal plain.     

Bioavailability: the organism as sensor

The use of a system of continuous culture of phytoplankton at constant population density, the ‘cage-culture’ turbidostat, as a monitor of the bioavailability of pollutant materials, is illustrated. In the case of proposed dredge spoils from two polluted areas, it is shown that bulk analyses for scheduled materials cannot be equated with bioavailability. Monitoring for the effect of the whole pollutant mixture on a properly chosen test population could obviate the necessity for chemical analyses for each component.     

Spatial variability in petrophysical properties in Upper Maastrichtian chalk outcrops at Stevns Klint, Denmark

The spatial variability of porosity and permeability was determined for a section in the uppermost Maastrichtian chalk exposed in the Sigerslev quarry at Stevns Klint. The aims were threefold: (1) to quantify the spatial variability pattern and its link to geology by applying systematic variogram analysis procedure, (2) to detect potential cyclicity in the petrophysical properties in this pure and overtly homogeneous chalk, and (3) to compare the section with chalk reservoirs in the North Sea in order to asses to what extent this onshore sequence has a potential as an analogue of the offshore, more deeply buried chalk reservoirs. The interval is of comparable stratigraphic age to the uppermost reservoir zones in the Tor Formation of the North Sea chalk reservoirs. The variability and spatial correlation of porosity and permeability in both horizontal and vertical directions are interpreted in a geological context and show indications of small-scale heterogeneity at 15–25 cm scale, but the clear cyclic layering described from other chalk deposits is not recognised at this locality. The investigated outcrop is not a close analogue to North Sea reservoir chalk, but some aspects are common including basic material properties, porosity/permeability trends and the variability pattern. The outcrop has a potential as analogue for some of the onshore subsurface chalk successions at shallow burial depth that form important aquifers.