全文获取类型
收费全文 | 5762篇 |
免费 | 225篇 |
国内免费 | 89篇 |
专业分类
测绘学 | 168篇 |
大气科学 | 546篇 |
地球物理 | 1444篇 |
地质学 | 1994篇 |
海洋学 | 549篇 |
天文学 | 754篇 |
综合类 | 22篇 |
自然地理 | 599篇 |
出版年
2021年 | 60篇 |
2020年 | 64篇 |
2019年 | 87篇 |
2018年 | 124篇 |
2017年 | 116篇 |
2016年 | 157篇 |
2015年 | 144篇 |
2014年 | 202篇 |
2013年 | 323篇 |
2012年 | 243篇 |
2011年 | 263篇 |
2010年 | 191篇 |
2009年 | 304篇 |
2008年 | 285篇 |
2007年 | 262篇 |
2006年 | 220篇 |
2005年 | 188篇 |
2004年 | 196篇 |
2003年 | 189篇 |
2002年 | 181篇 |
2001年 | 133篇 |
2000年 | 136篇 |
1999年 | 113篇 |
1998年 | 107篇 |
1997年 | 91篇 |
1996年 | 84篇 |
1995年 | 85篇 |
1994年 | 75篇 |
1993年 | 63篇 |
1992年 | 65篇 |
1991年 | 69篇 |
1990年 | 66篇 |
1989年 | 59篇 |
1988年 | 58篇 |
1987年 | 65篇 |
1986年 | 43篇 |
1985年 | 73篇 |
1984年 | 80篇 |
1983年 | 72篇 |
1982年 | 65篇 |
1981年 | 76篇 |
1980年 | 63篇 |
1979年 | 57篇 |
1978年 | 38篇 |
1977年 | 54篇 |
1976年 | 63篇 |
1975年 | 46篇 |
1974年 | 56篇 |
1973年 | 47篇 |
1972年 | 25篇 |
排序方式: 共有6076条查询结果,搜索用时 15 毫秒
121.
A new method to determine semi-analytical solutions of one-dimensional contaminant transport problem with nonlinear sorption is described. This method is based on operator splitting approach where the convective transport is solved exactly and the diffusive transport by finite volume method. The exact solutions for all sorption isotherms of Freundlich and Langmuir type are presented for the case of piecewise constant initial profile and zero diffusion. Very precise numerical results for transport with small diffusion can be obtained even for larger time steps (e.g., when the Courant-Friedrichs-Lewy (CFL) condition failed). 相似文献
122.
123.
124.
Janet M. Hergt L. Paul Bédard Etienne Deloule Klaus Peter Jochum Kathryn L. Linge Paul J. Sylvester Matthias Willbold Jon D. Woodhead 《Geostandards and Geoanalytical Research》2006,30(3):141-142
In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields. 相似文献
125.
This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials. 相似文献
126.
Neal T. Skipper Peter A. Lock James O. Titiloye Jan Swenson Zakaria A. Mirza W. Spencer Howells Felix Fernandez-Alonso 《Chemical Geology》2006,230(3-4):182-196
The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH3OD and (CH2OD)2 in deuterated clay allows us to measure the diffusion of the CH3- and CH2-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution. 相似文献
127.
Application of the QUILF thermobarometer to the peralkaline trachytes and pantellerites of the Eburru volcanic complex, East African Rift, Kenya 总被引:1,自引:0,他引:1
Minghua Ren Peter A. Omenda Elizabeth Y. Anthony John C. White Ray Macdonald D.K. Bailey 《Lithos》2006,91(1-4):109-124
The Quaternary Eburru volcanic complex in the south-central Kenya Rift consists of pantelleritic trachytes and pantellerites. The phenocryst assemblage in the trachytes is sanidine + fayalite + ferrohedenbergite + aenigmatite ± quartz ± ilmenite ± magnetite ± pyrrhotite ± pyrite. In the pantellerites, the assemblage is sanidine + quartz + ferrohedenbergite + fayalite + aenigmatite + ferrorichterite + pyrrhotite ± apatite, although fayalite, ferrohedenbergite and ilmenite are absent from more evolved rocks (e.g. with SiO2 > 71%). QUILF temperature calculations for the trachytes range from 709 to 793 °C and for the pantellerites 668–708 °C, the latter temperatures being among the lowest recorded for peralkaline silicic magmas. The QUILF thermobarometer demonstrates that the Eburru magmas crystallized at relatively low oxidation states (ΔFMQ + 0.5 to − 1.6) for both trachytes and pantellerites. The trachytes and pantellerites evolved along separate liquid lines of descent, the trachytes possibly deriving from a more mafic parent by fractional crystallization and the pantellerites from extreme fractionation of comenditic magmas. 相似文献
128.
129.
M. Catherine Eimers Andrew M. Paterson Peter J. Dillon Sherry L. Schiff Brian F. Cumming Roland I. Hall 《Journal of Paleolimnology》2006,35(1):99-109
Stable isotopic compositions and concentrations of total sedimentary sulphur (S) were determined in cores from 6 lakes in
the acid-sensitive Muskoka-Haliburton region of south-central Ontario. The isotopic composition of S in deep sediment (> ~
20 cm) was approximately constant in all lakes, and indicated a pre-industrial δ 34S value between +4.0 and +5.3‰, which is similar to current bulk deposition. Similarly, total S concentrations in deep sediment
were relatively low (1.9–5 mg S g−1 dwt) and approximately constant with depth within cores. All lakes exhibited up-core increases in total S and decreases in
δ 34S at a depth corresponding to the beginning of industrialization in the Great Lakes region ( ~ 1900), resulting in a generally
reciprocal depth pattern between total S concentration and δ 34S ratios. While initial shifts in total S and δ 34S were likely due to enhanced SO4 reduction of newly available anthropogenic SO4, both the magnitude and pattern of up-core S enrichment and shifts in δ 34S varied greatly among lakes, and did not match changes in S deposition post 1900. Differences between lakes in total S and
δ 34S were not related to any single hydrologic (e.g., residence time) or physical (e.g., catchment-area-to-lake area ratio) lake
characteristic. This work indicates that sediment cores do not provide consistent records of changes in post-industrial S
deposition in this region, likely due to redox-related mobility of S in upper sediment. 相似文献
130.