Geomorphic evolution of the Southern Alps,New Zealand

The Southern Alps are the topographic expression of late Cenozoic (<8 Ma ago) uplift of the crust of the leading edge of the Pacific plate in South Island, New Zealand. New fission track data on the basement exposed in the Southern Alps quantify the age, amount, and rate of rock uplift, and in combination with geomorphic parameters permit the construction of a new model of the geomorphic evolution of the Southern Alps. The model emphasizes the development over time and space of rock uplift, mean surface elevation, exhumation of crustal section, and relief. The earliest indications of mean surface uplift are between 4 and 5 Ma ago at the Alpine Fault. Mean surface uplift, which lagged the start of rock uplift, propagated southeastward from the Alpine Fault at a rate of 30 km/Ma. By about 4 Ma ago, exhumation had exposed greywacke basement adjacent to and east of the entire 300 km long central section of the Alpine Fault. At 3 Ma ago, greenschist was exposed in the southern parts of the Southern Alps near Lake Wanaka, and since then has become exhumed along a narrow strip east of the Alpine Fault. The model infers that amphibolite grade schist has been exhumed adjacent to the Alpine Fault only in the last 0·3 Ma. The age of the start of rock uplift and the amount and rate of rock uplift, all of which vary spatially, are considered to be the dominant influences on the development of the landscape in the Southern Alps. The Southern Alps have been studied in terms of domains of different rock uplift rate. At present the rate of rock uplift varies from up to 8–10 mm/a adjacent to the Alpine Fault to 0·8–1·0 mm/a along the southeastern margin of the Southern Alps. This spectrum can be divided into two domains, one northwest of the Main Divide where the present rock uplift rates are very high (up to 8–10 mm/a) and exceed the long-term value of 0·8–1·0 mm/a, and another to the southeast of the Main Divide where the long-term rate is 0·8–1·0 mm/a. A domain of no uplift lies immediately to the east of the Southern Alps, and is separated from them by a 1·0–1·5 km step in the basement topography. We argue that this spatial sequence of uplift rate domains represents a temporal one. The existing models of the geomorphic development of the Southern Alps—the dynamic cuesta model of J. Adams and the numerical model of P. Koons—are compared with the new data and evolutionary model. Particular constraints unrealized by these two earlier models include the following: the earlier timing of the start of rock uplift of the Southern Alps (8 Ma ago); the spatial variation in the timing of the start of rock uplift (8 Ma ago to 3 Ma ago); the lower long-term rock uplift rate (0·8–1·0 mm/a) of the Southern Alps for most of the late Cenozoic; the lag between the start of rock uplift and the start of mean surface uplift; and the patterns of the amounts of late Cenozoic rock uplift and erosion across the Southern Alps.     

Turbulent heat fluxes by profile and inertial dissipation methods: analysis of the atmospheric surface layer from shipboard measurements during the SOFIA/ASTEX and SEMAPHORE experiments

Heat flux estimates obtained using the inertial dissipation method, and the profile method applied to radiosonde soundings, are assessed with emphasis on the parameterization of the roughness lengths for temperature and specific humidity. Results from the inertial dissipation method show a decrease of the temperature and humidity roughness lengths for increasing neutral wind speed, in agreement with previous studies. The sensible heat flux estimates were obtained using the temperature estimated from the speed of sound determined by a sonic anemometer. This method seems very attractive for estimating heat fluxes over the ocean. However allowance must be made in the inertial dissipation method for non-neutral stratification. The SOFIA/ASTEX and SEMAPHORE results show that, in unstable stratification, a term due to the transport terms in the turbulent kinetic energy budget, has to be included in order to determine the friction velocity with better accuracy. Using the profile method with radiosonde data, the roughness length values showed large scatter. A reliable estimate of the temperature roughness length could not be obtained. The humidity roughness length values were compatible with those found using the inertial dissipation method.     

Evidence for Enhanced Mineral Dissolution in Organic Acid-Rich Shallow Ground Water

Total concentrations of formate, acetate, and isobutyrate varied from less than 5 to greater than 9,000 μmol/l over distances of < 3 m in ground water from a shallow hydrocarbon contaminated aquifer. Laboratory incubations of aquifer material indicate that organic acid concentrations were dependent on the amount of hydrocarbon loading in the sediment and the relative rates of microbial organic acid production and consumption. In heavily contaminated sediments, production greatly exceeded consumption and organic acid concentrations increased. In lightly contaminated sediments rates were essentially equal and organic acid concentrations remained low. Concentrations of dissolved calcium, magnesium, and iron generally were one to two orders of magnitude higher in organic acid-rich ground water than in ground water having low organic acid concentrations. Carbonate and Fe(III)-oxyhydroxide minerals were the likely sources of these elements. Similarly, concentrations of dissolved silica, derived from quartz and k-feldspar, were higher in organic acid-rich ground water than in other waters. The positive relation (r = 0.60, p < .05, n = 16) between concentrations of silica and organic acids suggests that the microbially mediated buildup of organic acids in ground water enhanced quartz/k-feldspar dissolution in the aquifer, although it was not the only factor influencing their dissolution. A model that included organic acid microequivalents normalized by cation microequivalents significantly strengthened the correlation (r = 0.79, p < .001, n = 16) between dissolved silica and organic acid concentrations, indicating that competition between silica and cations for complexation sites on organic acids also influenced quartz/k-feldspar dissolution. Physical evidence for enhanced mineral dissolution in organic acid-rich waters included scanning electron microscopy images of highly corroded quartz and k-feldspar grains from portions of the aquifer containing organic acid-rich ground water. Microporosity generated in hydrocarbon contaminated sediments may adversely affect remediation efforts that depend on the efficient injection of electron acceptors into an aquifer or on the recovery of solutes from an aquifer.     

Radiocarbon and δ13C Values Related to Ground-Water Recharge and Mixing

Ground-water levels in the Upper Floridan aquifer beneath the southeastern coast of South Carolina have undergone pumpage-induced declines approaching 20 ft below sea level at the southern end of Hilton Head Island. This scenario suggests the potential exists for the inducement of recharge to the Upper Floridan aquifer across the island, which could affect the quality of water being pumped by wells. However, low radiocarbon concentrations in ground-water samples (0.5 to 1.4 ± 0.1 PMC) indicate that most of the water is relict ground water reflecting prepumpage ground-water flow conditions in the Upper Floridan aquifer. The isotopic data indicate long residence times and water-chemistry evolution more characteristic of ground-water recharge occurring farther inland prior to the commencement of pumpage in the late 1800s. Radiocarbon concentrations (as Percent Modern Carbon) and stable carbon isotope ratios (as δ¹³C in dissolved inorganic carbon) determined during this study and reported in other studies on and around Hilton Head Island varied in a systematic manner. Heavier δ¹³C values (–2.8 to –1.6 per mil) in ground water beneath southern Hilton Head Island reflect ground-water discharge from prepumpage flowpaths originating over 100 miles away, hence a depletion in radiocarbon concentration with corrected ground-water ages no younger than 16,000 yrs BP. In contrast, lighter δ¹³C values (–13.9 to –8.67 per mil) beneath the northern part of the island indicate recent recharge as a result of water-level declines, and recharge in areas off the island that have not changed as a result of pumpage (evidenced by enrichment in radiocarbon with corrected ground-water ages no older than 4,000 yrs BP). This suggests that the δ¹³C composition of ground water in the Upper Floridan aquifer is a useful indicator of mixing between ground waters from different sources, and can be used to delineate recharge-discharge patterns. This approach may be applicable to other aquifers of highly evolved ground-water chemistry in regional carbonate aquifer systems that may be receiving recent recharge. Moreover, this approach could prove useful in delineating the contribution of recent water being captured by pumped wells as part of wellhead protection programs designed to assess aquifer vulnerability from surficial contaminant sources.     

Impact of forest clearance on the soils of tropical cone karst

The precise nature and effects of forest clearance, followed by a two to three year cycle of shifting cultivation and subsequent secondary re-growth, was observed in an area of lowland evergreen forest over cone karst topography in central Belize. The surface soil properties varied in their response to disturbance but a number of significant changes were measured by comparing the pre-clearance and post-cultivation soil analyses. Four groups of soil properties were identified: (1) organic properties which suffered a marked decrease over the summit and upper slope areas and which showed a tendency to increase towards the foot, (2) alkaline status which demonstrated an increase on the upper slopes, (3) nutrient cations whose levels, from more limited evidence, were generally lower after clearance, particularly in the summit and upper slope areas, and (4) soil physical properties, where both the fine fraction and soil depth were drastically affected by clearance; the proportion of clay diminished on the upper slopes and increased at the footslope zone whilst soil depth thinned at the summit and increased markedly over the foreland. The scale of disturbance is so considerable that it has led to recommendations to limit cultivation and clearance pressure in these vulnerable environments.     

The influence of natural organic matter on the adsorption properties of mineral particles in lake water

The adsorption characteristics of sediment particles from a prealpine Swiss lake were compared with those of γ-aluminum oxide. Under lake water conditions, i.e. with particle concentration of 2–16 mg/1 and DOC concentrations of 1–4 mg/1 at pH=8, the adsorption of copper, zinc and orthophosphate is reduced significantly by the presence of natural organic matter (NOM). It is postulated that the binding sites of the natural mineral surfaces are occupied almost completely by NOM under natural conditions. A simple ligand exchange model can explain the observed phenomena.     

Long-term effects of crude oil on microbial processes in subarctic marine sediments: Studies on sediments amended with organic nutrients

Subarctic marine sediments amended with various organic compounds were exposed to fresh Cook Inlet crude oil at a concentration of 50 ppt for either 6 or 8 months. After the sediments were initially treated, they were returned to the approximate location where they were collected and left to be exposed to natural environmental conditions until they were retrieved for analysis. As a result of crude oil treatment, the activities of the enzymes that hydrolyse structural polysaccharides were reduced and the activities of the enzymes that hydrolyse storage polysaccharides were stimulated. In addition to these changes, we observed changes in phosphatase activity, nitrogen fixation rates, potential denitrification rates, methane concentrations, CO₂ production rates, and the glucose uptake and mineralization rates. The effect of the crude oil perturbation was different depending on the organic compound used in the amended sediments. Many of these differences could be explained by the effect of crude oil on the hydrolases which were responsible for degrading the compound in question. The results of this study suggest the effect of crude oil on microbial processes may be affected by the type of organic material present in the impacted marine sediment. This study also illustrates the value of measuring hydrolase activity in studies designed to determine the effects of this or any other pollutant on microbial processes in marine sediments.