The “North American shale composite”: Its compilation,major and trace element characteristics

The compilation and major element composition of the “North American shale composite” (NASC) are reported for the first time, along with redeterminations for the REE and selected other elements by modern, high precision analytical methods. The NASC is not strictly of North American origin; 5 of the constituent samples are from Africa and Antarctica, and 15 are from unspecified locations. The major element composition of the NASC compares quite closely with other average shale compositions. New analyses of the NASC document that significant portions of the REE and some other trace elements are contained in minor phases (zircon and possibly other minerals) and that their uneven distribution in the NASC powder appears to have resulted in heterogeneity among analyzed aliquants. The results of this study show that the REE distributions of detrital sediments can be dependent to some extent on their minor mineral assemblages and the sedimentological factors that control these assemblages. Consequently, caution should be exercised in the interpretation of the REE distributions of sediment samples as they may be variable and biased relative to average REE distribution of the crustal rocks supplying detritus. These effects appear to be largely averaged out in sediment composites, with the result that their REE distributions are more likely to be representative of their provenances.     

Heavy-mineral variability in bottom sediments of the lower Chesapeake Bay,Virginia

Heavy minerals in bottom-sediment samples of the lower Chesapeake Bay show distribution patterns and interrelationships that denote characteristic mineral suites associated with defined geographic provinces. The Baymouth province has a garnet—hornblende—pyroxene suite, which is largely attributed to the influx of littoral and shelf sediments; the Eastern Shore province has a similar suite, derived largely from coastal erosion of the Eastern Shore peninsula. The Northern and Combined River provinces have a zircon—tourmaline—staurolite assemblage, which reflects derivation from an Appalachian Piedmont—Atlantic Coastal Plain sourceland. The Western Shore province is associated with a zircon—epidote—staurolite assemblage, apparently derived jointly from tributary influx and coastal erosion of the western shore. Factor analysis identified two major factors that account for 63% of the total variation in the relative amounts of the seven most common heavy minerals. The dominant factor (44%) is based on a zircon—hornblende—staurolite—pyroxene relationship, which indicates that mineral stability, as influenced by sediment maturity, is a major contributing factor. The second factor (19%) based on a tourmaline—epidote—staurolite—garnet relationship indicates that provenance is another major cause of heavy-mineral variability within the lower bay.     

Thermal fronts and cross-frontal heat flux in the southern Huanghai Sea and the East China Sea

Synoptic features in/around thermal fronts and cross-frontal heat fluxes in the southern Huanghai./Yellow Sea and East China Sea （HES） were examined using the data collected from four airborne expendable bathythermograph surveys with horizontal approxmately 35 km and vertical 1 m（from the surface to 400 m deep） spacings. Since the fronts are strongly affected by HES current system, the synoptic thermal features in/around them represent the interaction of currents with surrounding water masses. These features can not be obtained from climatological data. The identified thermal features are listed as follows ： （ 1 ） multiple boundaries of cold water, asymmetric thermocline intrusion, locally-split front by homogeneous water of approxmately 18 ℃, and mergence of the front by the Taiwan Warm Current in/around summertime southern Cheju - Changjiang/Yangtze front and Tsushima front; （2） springtime frontal eddy-like feature around Tsushima front; （3） year-round cyclonic meandering and summertime temperature-inversion at the bottom of the surface mixed layer in Cheju - Tsushima front; and （4） multistructure of Kuroshio front. In the Kuroshio front the mean variance of vertical temperature gradient is an order of degree smaller than that in other HES fronts. The southern Cheju- Changjiang front and Cheju -Tsushima front are connected with each other in the summer with comparable cross-frontal temperature gradient. However, cross-frontal heat flux and lateral eddy diffusivity are stronger in the southern Cheju - Changjiang front. The cross-frontal heat exchange is the largest in the mixing zone between the modified Huanghai Sea bottom cold water and the Tsushima Warm Current, which is attributable to enhanced thermocline intrusions.     

Reconstruction of past methane availability in an Arctic Alaska wetland indicates climate influenced methane release during the past ~12,000?years

Atmospheric contributions of methane from Arctic wetlands during the Holocene are dynamic and linked to climate oscillations. However, long-term records linking climate variability to methane availability in Arctic wetlands are lacking. We present a multi-proxy ~12,000?year paleoecological reconstruction of intermittent methane availability from a radiocarbon-dated sediment core (LQ-West) taken from a shallow tundra lake (Qalluuraq Lake) in Arctic Alaska. Specifically, stable carbon isotopic values of photosynthetic biomarkers and methane are utilized to estimate the proportional contribution of methane-derived carbon to lake-sediment-preserved benthic (chironomids) and pelagic (cladocerans) components over the last ~12,000?years. These results were compared to temperature, hydrologic, and habitat reconstructions from the same site using chironomid assemblage data, oxygen isotopes of chironomid head capsules, and radiocarbon ages of plant macrofossils. Cladoceran ephippia from ~4,000?cal?year BP sediments have ??¹³C values that range from ~?39 to ?31??, suggesting peak methane carbon assimilation at that time. These low ??¹³C values coincide with an apparent decrease in effective moisture and development of a wetland that included Sphagnum subsecundum. Incorporation of methane-derived carbon by chironomids and cladocerans decreased from ~2,500 to 1,500?cal?year BP, coinciding with a temperature decrease. Live-collected chironomids with a radiocarbon age of 1,640?cal?year BP, and fossil chironomids from 1,500?cal?year BP in the core illustrate that ??old?? carbon has also contributed to the development of the aquatic ecosystem since ~1,500?cal?year BP. The relatively low ??¹³C values of aquatic invertebrates (as low as ?40.5??) provide evidence of methane incorporation by lake invertebrates, and suggest intermittent climate-linked methane release from the lake throughout the Holocene.     

REDD+ readiness process in Cameroon: an analysis of multi-stakeholder perspectives

Cameroon has been a keen participant in Reducing Emissions from Deforestation and Forest Degradation plus conservation, sustainable management of forests and enhancement of carbon stocks (REDD+) negotiations since 2005 and has engaged in activities to enhance the implementation of REDD+. This article reviews progress on REDD+ readiness in Cameroon based on a multiple REDD+ functions framework. Results show that some progress has been made in terms of planning and coordination, institutional development, and the development of some REDD+ projects. Absence of a legal framework, inadequate procedures for stakeholder participation, slow progress in the development of a national strategy, monitoring, reporting, and verification (MRV) challenges, and weak financing remain prominent constraints. Despite having one of the slowest REDD Readiness Preparation Proposal (R-PP) processes in the Congo Basin, stakeholders feel strong ownership because the R-PP was done almost entirely by Cameroonian experts. Some opportunities for improving REDD+ can be considered going forward, including the establishment of procedures for a broader participatory process, speeding up the operationalization of the National Observatory on Climate Change, making use of the ongoing forestry law reform, consideration of a carbon concessions concept, tapping from international initiatives to build on MRV, and improving benefit sharing and financing through the development of an appropriate and decentralized mechanism. Enhancing these opportunities is fundamental for successful REDD+ implementation in Cameroon.

Policy relevance

This article offers a new multidimensional approach to assessing the REDD+ readiness process in Cameroon. This critical assessment, which is done using six key functions, provides an opportunity for enhanced understanding of the process by policy makers, decision makers, and professionals with a view to enabling improvements in the readiness process. Furthermore, the article proffers a series of opportunities that the government and other relevant stakeholders can capitalize on to overcome current hurdles affecting the REDD+ readiness process. It is hoped that policy makers driving the REDD+ process in Cameroon will be able to incorporate the findings of this research into their strategic policy, formulated to advance the REDD+ readiness process. More importantly, it is hoped that the multidimensional framework applied in this study could be useful for assessing REDD+ in similar contexts in the Congo Basin.     

Lunar Laser Ranging: Glorious Past And A Bright Future

Lunar Laser Ranging (LLR), a part of the NASA Apollo program, has beenon-going for more than 30 years. It provides the grist for a multi-disciplinarydata analysis mill. Results exist for solid Earth sciences, geodesy and geodynamics,solar system ephemerides, terrestrial and celestial reference frames, lunar physics,general relativity and gravitational theory. Combined with other data, it treatsprecession of the Earth's spin axis, lunar induced nutation, polar motion/Earthrotation, Earth orbit obliquity to the ecliptic, intersection of the celestial equatorwith the ecliptic, luni-solar solid body tides, lunar tidal deceleration, lunar physicaland free librations, structure of the moon and energy dissipation in the lunar interior.LLR provides input to lunar surface cartography and surveying, Earth station and lunar retroreflector location and motion, mass of the Earth-moon system, lunar and terrestrial gravity harmonics and Love numbers, relativistic geodesic precession, and the equivalence principle of general relativity. With the passive nature of the reflectors and steady improvement in observing equipment and data analysis, LLR continues to provide state-of-the-art results. Gains are steady as the data-base expands. After more than 30 years, LLR remains the only active Apollo experiment. It is important to recognize examples of efficient and cost effective progress of research. LLR is just such an example.     

A method for uncertainty constraint of catchment discharge and phosphorus load estimates

River discharge and nutrient measurements are subject to aleatory and epistemic uncertainties. In this study, we present a novel method for estimating these uncertainties in colocated discharge and phosphorus (P) measurements. The “voting point”‐based method constrains the derived stage‐discharge rating curve both on the fit to available gaugings and to the catchment water balance. This helps reduce the uncertainty beyond the range of available gaugings and during out of bank situations. In the example presented here, for the top 5% of flows, uncertainties are shown to be 139% using a traditional power law fit, compared with 40% when using our updated “voting point” method. Furthermore, the method is extended to in situ and lab analysed nutrient concentration data pairings, with lower uncertainties (81%) shown for high concentrations (top 5%) than when a traditional regression is applied (102%). Overall, for both discharge and nutrient data, the method presented goes some way to accounting for epistemic uncertainties associated with nonstationary physical characteristics of the monitoring site.     

TOURISM DEVELOPMENT ON VANCOUVER ISLAND: AN ASSESSMENT OF THE CORE-PERIPHERY MODEL *

This paper examines tourism development on Vancouver Island, B.C. in terms of the core-periphery approach to regional planning. It examines whether a core area (Victoria) is willing to share its tourism business with the rest of the island, and then focuses on the situation in a peripheral region (the Cowichan Valley Regional District–CVRD). A discriminant analysis of CVRD residents reveals they have different views regarding tourism's potential and future in their region. A follow-up analysis, reflecting a change in the scale of enquiry and local core-periphery conditions, shows residents'perceptions and priorities will change according to their respective area groupings. This analysis reveals that residents of a peripheral region, who are expected to participate in and welcome tourism development initiatives developed by senior levels of government, will in fact have different opinions regarding the industry and its potential. These differences are linked to present levels of tourism activity within the periphery and the varying community aspirations linking tourism's development potential with local needs and priorities.     

From nappe stacking to exhumation: Cretaceous tectonics in the Apuseni Mountains (Romania)

International Journal of Earth Sciences - New Ar–Ar muscovite and Rb–Sr biotite age data in combination with structural analyses from the Apuseni Mountains provide new constraints on...     

Exponential leap-forward gradient scheme for determining the isothermal layer depth from profile data

Two distinct layers usually exist in the upper ocean. The first has a near-zero vertical gradient in temperature (or density) from the surface and is called the isothermal layer (or mixed layer). Beneath that is a layer with a strong vertical gradient in temperature (or density), called the thermocline (or pycnocline). The isothermal layer depth (ILD) or mixed layer depth (MLD) for the same profile varies depending on the method used to determine it. Also, whether they are subjective or objective, existing methods of determining the ILD do not estimate the thermocline (pycnocline) gradient. Here, we propose a new exponential leap-forward gradient (ELG) method of determining the ILD that retains the strengths of subjective (simplicity) and objective (gradient change) methods and avoids their weaknesses (subjective methods are threshold-sensitive and objective methods are computationally intensive). This new method involves two steps: (1) the estimation of the thermocline gradient G _th for an individual temperature profile, and (2) the computation of the vertical gradient by averaging over gradients using exponential leap-forward steps. Such averaging can filter out noise in the profile data. Five existing methods of determining the ILD (difference, gradient, maximum curvature, maximum angle, and optimal linear fitting methods) as well as the proposed ELG method were verified using global expendable bathythermograph (XBT) temperature and conductivity–temperature–depth (CTD) datasets. Among all the methods considered, the ELG method yielded the highest skill score and the lowest Shannon information entropy (i.e., the lowest uncertainty).