Noble gases in the Allende and Abee meteorites and a gas-rich mineral fraction: investigation by stepwise heating

Noble gases in three meteoritic samples were examined by stepwise heating, in an attempt to relate peaks in the outgassing curves to specific minerals: NeKrXe in Allende (C3V) and an Allende residue insoluble in HF-HCl, and Xe in Abee (E4). In Allende, chromite and carbon contain most of the trapped Ne (²⁰Ne/²²Ne ≈ 8.7) and anomalous Xe enriched in light and heavy isotopes, and release it at ~850°C (bulk meteorite) or 1000°C (residue). Mineral Q, containing most of the trapped Ar, Kr, Xe as well as some Ne (²⁰Ne/²²Ne ≈ 10.4), releases its gases mainly between 1200 and 1600°C, well above the release temperatures of organic polymers (300–500°) or amorphous carbon (800–1000°). The high noble-gas release temperature, ready solubility in oxidizing acids, and correlation with acid-soluble Fe and Cr all point to an inorganic rather than carbonaceous nature of Q.All the radiogenic ¹²⁹Xe is contained in HCl, HF-soluble minerals, and is distributed as follows over the peaks in the release curve: Attend 1000° (75%), 1300° (25%); Abee (data of Hohenberg and Reynolds, 1969) ~850° (15%), 1100° (60%), 1300° (25%). No conclusive identifications of host phases can yet be given; possible candidates are troilite and silicates for Allende, and djerfisherite, troilite and silicates for Abee.Mineral Q strongly absorbs air xenon, and releases some of it only at 800–1000°C. Dilution by air Xe from Q and other minerals may explain why temperature fractions from bulk meteorites often contain less ^124–130Xe for a given enrichment in heavy isotopes than does xenon from etched chromitecarbon samples, although chromite-carbon is the source of the anomalous xenon in either case. Air xenon contamination thus is an important source of error in the derivation of fission xenon spectra.     

Absolute spectrophotomery of comets 1973XII and 1975IX: II. Profiles of the Swan bands

Absolute spectrophotometric measurements of the Swan bands of two comets have been compared with computed synthetic spectra using modern Franck-Condon and Hönl-London factors, and varying rotational, vibrational, and electronic excitation temperatures. Rotational and vibrational temperatures were obtained for the comets. Although the electronic excitation temperature and the molecular column density cannot be separated, a relationship is found between these two quantities. A review is made of recent determinations of column densities for CN in comets.     

Effective temperatures,radii and bolometric magnitudes of Ap and Am stars

The effective temperatures radii and bolometric magnitudes of Ap, Am and normal A stars have been estimated from their energy distribution curves between 478 nm and 680 nm. All the Am stars and one Ap star (i.e. CrB) were found to be affected by line blanketing, a rough estimation of which in the respective (B-V) colours has been found out in each case.The range in effective temperature is 0.45–0.60 in terms of (=5040/T _e), while it is 1.8–4.8R in the case of radius, that in bolometric magnitude being from-0^m.67 to+1^m.61. An approximate estimate of the masses shows that they are between 1.5 and 3.0M . All these estimates are in agreement with those of the normal A stars. The Ap and Am stars are found to be slightly evolved and, therefore, are probably in the hydrogen shell-burning phase.     

Properties of the clouds of Venus,as inferred from airborne observations of its near-infrared reflectivity spectrum

We have measured the shape and absolute value of Venus' reflectivity spectrum in the 1.2-to 4.0-μm spectral region with a circular variable filter wheel spectrometer having a spectral resolution of 1.5%. The instrument package was mounted on the 91-cm telescope of NASA Ames Kuiper Airborne Observatory, and the measurements were obtained at an altitude of about 41,000 feet, when Venus had a phase angle of 86°. Comparing these spectra with synthetic spectra generated with a multiple-scattering computer code, we infer a number of properties of the Venus clouds. We obtain strong confirmatory evidence that the clouds are made of a water solution of sulfuric acid in their top unit optical depth and find that the clouds are made of this material down to an optical depth of at least 25. In addition, we determine that the acid concentration is 84 ± 2% H_2SO4 by weight in the top unit optical depth, that the total optical depth of the clouds is 37.5 ± 12.5, and that the cross-sectional weighted mean particle radius lies between 0.5 and 1.4 μm in the top unit optical depth of the clouds. These results have been combined with a recent determination of the location of the clouds' bottom boundary [Marov et al., Cosmic Res.14, 637–642 (1976)] to infer additional properties about Venus' atmosphere. We find that the average volume mixing ratio of H₂SO₄ and H₂O contained in the cloud material both equal approximately 2× 10^?6. Employing vapor pressure arguments, we show that the acid concentration equals 84 ± 6% at the cloud bottom and that the water vapor mixing ratio beneath the clouds lies between 6 × 10^?4 and 10^?2.     

Galilean satellites: 1976 radar results

Radar observations of the Galilean satellites, made in late 1976 using the 12.6-cm radar system of the Arecibo Observatory, have yielded mean geometric albedos of 0.04 ± , 0.69 ± 0.17, 0.37 ± 0.09, and 0.15 ± 0.04, for Io, Europa, Ganymede, and Callisto, respectively. The albedo for Io is about 40% smaller than that obtained approximately a year earlier, while the albedos for the outer three satellites average about 70% larger than the values previously reported for late 1975, raising the possibility of temporal variation. Very little dependence on orbital phase is noted; however, some regional scattering inhomogeneities are seen on the outer three satellites. For Europa, Ganymede, and Callisto, the ratios of the echo received in one mode of circular polarization to that received in the other were: 1.61 ± 0.20 1.48 ± 0.27, and 1.24 ± 0.19, respectively, with the dominant component having the same sence of circularity as that transmitted. This behavior has not previously been encountered in radar studies of solar system objects, whereas the corresponding observations with linear polarization are “normal.” Radii determined from the 1976 radar data for Europa and Ganymede are: 1530 ± 30 and 2670 ± 50 km, in fair agreement with the results from the 1975 radar observations and the best recent optical determinations. Doppler shifts of the radar echoes, useful for the improvement of the orbits of Jupiter and some of the Galilean satellites, are given for 12 nights in 1976 and 10 nights in 1975.     

Pre-flare association of magnetic fields and millimeter-wave radio emission

Observations of radio emission at 3.3 mm wavelength associated with magnetic fields in active regions are reported. Results of more than 200 regions during the years 1967–1968 show a strong correlation between peak enhanced millimeter emission, total flux of the longitudinal component of photospheric magnetic fields and the number of flares produced during transit of active regions. For magnetic flux greater than 10²¹ maxwells flares will occur and for flux of 10²³ maxwells the sum of the H flare importance numbers is about 40. The peak millimeter enhancement increases with magnetic flux for regions which subsequently flared. Estimates of the magnetic energy available and the correlation with flare production indicate that the photospheric fields and probably chromospheric currents are responsible for the observed pre-flare heating and provide the energy of flares.This work was supported in part by NASA Contract No. NAS2-7868 and in part by Company funds of The Aerospace Corporation.     

Depositional environments of Upper Miocene (Messinian) evaporite deposits of the Sicilian Basin*

In Sicily, Messinian evaporitic sedimentary deposits are developed under a wide variety of hypersaline conditions and in environments ranging from continental margin (subaerial), to basin-margin supratidal, to intertidal, to subtidal and out into the hypersaline basin proper. The actual water depth at the time of deposition is indeterminate; however, relative terms such as ‘wave base’ and ‘photic zone’ are utilized. The inter-fingering relationships of specific evaporitic facies having clear and recognizable physical characteristics are presented. These include sub-aerial deposits of nodular calcium sulphate formed displacively within clastic sediments; gypsiferous rudites, arenites and arenitic marls, all of which are reworked sediments and are mixed in varying degrees with other clastic materials (subaerial, supratidal, and intertidal to deep basinal deposits). Laminated calcium sulphate alternating with very thin carbonate interlaminae and having two different aspects; one being even and continuous and the other of a wavy, irregular appearance (subtidal, intertidal, and supratidal deposits). Nodular calcium sulphate beds, usually associated with wavy, irregular laminated beds (supratidal, sabkha deposits); very coarsely crystalline gypsum beds (selenite), associated with more even, laminated beds (subaqueous, intertidal to subtidal deposits); wavy anastomozing gypsum beds, composed of very fine, often broken crystals (subaqueous, current-swept deposits); halite having hopper and chevron structures (supratidal to intertidal); and halite, potash salts, etc. having continuous laminated structure (subaqueous, possibly basinal). Evidence for diagenetic changes is observed in the calcium sulphate deposits which apparently formed by tectonic stress and also by migrating hypersaline waters. These observations suggest that the common, massive form of alabastrine gypsum (or anhydrite, in the subsurface) may not always be ascribed to original depositional features, to syndiagenesis or to early diagenesis but may be the result of late diagenesis.