Inputs of organic carbon from Ria de Aveiro coastal lagoon to the Atlantic Ocean

Land/ocean boundaries constitute complex systems with active physical and biogeochemical processes that affect the global carbon cycle. An example of such a system is the mesotidal lagoon named Ria de Aveiro (Portugal, 40°38′N, 08°45′W), which is connected to the Atlantic Ocean by a single channel, 350 m wide. The objective of this study was to estimate the seasonal and inter-tidal variability of organic carbon fluxes between the coastal lagoon and the Ocean, and to assess the contribution of the organic carbon fractions (i.e. dissolved organic carbon (DOC) and particulate organic carbon (POC)) to the export of organic carbon to the Ria de Aveiro plume zone. The organic carbon fractions fluxes were estimated as the product of the appropriate fractional organic carbon concentrations and the water fluxes calculated by a two-dimensional vertically integrated hydrodynamic model (2DH). Results showed that the higher exchanges of DOC and POC fractions at the system cross-section occurred during spring tides but only resulted in a net export of organic carbon in winter, totalling 85 t per tidal cycle. Derived from the winter and summer campaigns, the annual carbon mass balance estimated corresponded to a net export of organic carbon (7957 = 6585 t yr⁻¹ POC + 1372 t yr⁻¹ DOC). On the basis of the spring tidal drainage area, it corresponds to an annual flux of 79 g m⁻² of POC and 17 g m⁻² of DOC out of the estuary.     

Granulometric selectivity in Liza ramado and potential contamination resulting from heavy metal load in feeding areas

The stomach contents of thin-lipped grey mullets Liza ramado were analysed in terms of granulometric composition and compared to the sediment of potential feeding areas in the Tagus estuary. Total organic matter (TOM) content and heavy metal content were determined in the surface sediment of three areas and eight trace elements were quantified: Cd, Co, Cr, Cu, Hg, Ni, Pb and Zn. The three sampled areas did not differ in TOM; and the heavy metal content was below Effects Range-Low level for most elements. The mean observed concentrations were present in the following sequence: Zn > Pb > Cr > Cu ≈ Ni > Co > Cd > Hg. Stomach contents granulometric composition provided information about the feeding selectivity of the mullets. Sediment fractions with particle size between 20 and 50 μm are preferred, independently of the fishes' length. Smaller standard length (SL) fishes have a higher positive selection of fine grained sediments than those with a larger SL. Finer fractions usually have higher concentration of heavy metals, which makes younger specimens of the thin-lipped grey mullet potentially more exposed to heavy metal load in the estuary. Metal concentration was not independent from the sampling point, presenting higher values near the margins and the estuary tidal drainage system. This means that during the first period of each tidal cycle, the mullets will feed first on the most contaminated areas, as a consequence of their movement following the rising tide to feed on previously exposed areas.     

Spatial patterns and temporal trends of precipitation in Iran

Spatial patterns of monthly, seasonal and annual precipitation over Iran and the corresponding long-term trends for the period 1951–2009 are investigated using the Global Precipitation Climatology Centre gridded dataset. Results suggest that the spatial patterns of annual, winter and spring precipitation and the associated coefficients of variation reflect the role of orography and latitudinal extent between central-southern arid and semi-arid regions and northern and western mountainous areas. It is also shown that precipitation occurrence is almost regularly distributed within the year in northern areas while it is more concentrated in a few months in southern Iran. The spatial distribution of Mann–Kendal trend test (Z statistics) for annual precipitation showed downward trend in north-western and south-eastern Iran, whereas western, central and north-eastern exhibited upward trend, though not statistically significant in most regions. Results for winter and autumn revealed upward trend in most parts of the country, with the exception of north-western and south-eastern where a downward trend is observed; in spring and summer, a downward trend seems to prevail in most of Iran. However, for all seasons the areas where the detected trend is statistically significant are limited to a few spot regions. The overall results suggest that the precipitation is decreasing in spring and summer and increasing in autumn and winter in most of Iran, i.e. less precipitation during the warm season with a consequent intensification of seasonality and dryness of the country. However, since the detected trends are often not statistically significant, any stringent conclusion cannot be done on the future tendencies.     

Physical controls on sand composition and relative durability of detrital minerals during ultra‐long distance littoral and aeolian transport (Namibia and southern Angola)

Sediment in coastal Namibia to southern Angola is supplied dominantly from the Orange River with minor additional fluvial input and negligible modifications by chemical processes, which makes this a great test case for investigating physical controls on sand texture and composition. This study monitored textural, mineralogical and geochemical variability in beach and aeolian‐dune sands along a ca 1750 km stretch of the Atlantic coast of southern Africa by using an integrated set of techniques, including image analysis, laser granulometry, optical microscopy, Raman spectroscopy and bulk‐sediment geochemistry. These results contrast with previous reports that feldspars and volcanic detritus break down during transport, that sand grains are rounded rapidly in shallow‐marine environments, and that quartzose sands may be produced by physical processes. Mechanical wear is unable to modify the relative abundance of detrital components, including pyroxene and mafic volcanic rock fragments traditionally believed to be destroyed rapidly. The sole exceptions are poorly lithified or cleaved sedimentary/metasedimentary rock fragments, readily lost at the transition to the marine environment, and slow‐settling flaky micas, winnowed and deposited offshore. Coastal sediments tend to be depleted in relatively mobile amphibole, preferentially entrained offshore or re‐deposited in sheltered beaches, while less mobile garnet is retained onshore. No detrital mineral displays a significant increase in grain roundness after 300 to 350 km of longshore transport in high‐energy littoral environments from the Orange mouth to south of the Namib Erg, but all minerals get rapidly rounded after passing into the dunefield. Pyroxene and opaques get rounded faster than harder quartz and garnet, but sand mineralogy remains unchanged. Excepting strong transient selective‐entrainment effects, physical processes are unable to modify sand composition significantly. Selective mechanical breakdown can be largely neglected in quantitative provenance analysis of sand and sandstone even in the case of ultra‐long‐distance transport in high‐energy environments dominated by strong persistent winds and waves.     

A viscoplastic subloading soil model for rate‐dependent cyclic anisotropic structured behaviour

This paper presents a new purely viscoplastic soil model based on the subloading surface concept with a mobile centre of homothety, enabling the occurrence of viscoplastic strains inside the yield surface and avoiding the abrupt change in stiffness of the traditional overstress viscoplastic models. This is required for overconsolidated soils. The model is formulated to reproduce the soil rate‐dependent behaviour under cyclic loading (changes in loading direction) and incorporates both initial and induced anisotropy, as well as destructuring. The model shows good qualitative response to some imposed three‐dimensional stress paths under quasi‐inviscid (elastoplastic) behaviour. Some of the main time‐dependent aspects of soil behaviour that the model is capable of reproducing were also illustrated. The capability of the model to adequately reproduce the results from an undrained triaxial test performed on stiff overconsolidated clays from the Lisbon region (Formação de Benfica), with an unloading–reloading deviatoric stress cycle at constant mean stress, that incorporates a series of staggered fast loading and creep stages, was evaluated. The model was able to reproduce well the main observed aspects of the time‐dependent stress–strain response and pore pressure evolution of a stiff overconsolidated clay under complex loading. The revised and generalised viscoplastic subloading surface concept is viable and can be applied to a consistent extension to viscoplasticity, including in the interior of the yield surface, of existing elastoplastic models formulated for soils and other materials. Copyright © 2016 John Wiley & Sons, Ltd.     

Improving GSMaP V06 precipitation products over the Upper Tocantins River basin in the Brazilian Cerrado,based on local rain-gauge network

Theoretical and Applied Climatology - Gridded precipitation products from remote sensing are currently available and could potentially enhance the use of precipitation data in regions with sparse...     

Correction to: Observational Investigation of the Statistical Properties of Surface-Layer Turbulence in a Suburban Area of São Paulo,Brazil: Objective Analysis of Scaling-Parameter Accuracy and Uncertainties

Boundary-Layer Meteorology -     

Mercury distribution in Douro estuary (Portugal)

Determinations of dissolved reactive and total dissolved mercury, particulate and sedimentary mercury, dissolved organic carbon (DOC), particulate organic carbon (POC) and suspended particulate matter (SPM) have been made in the estuary of river Douro, in northern Portugal. The estuary was stratified by salinity along most of its length, it had low concentrations of SPM, typically <20 mg dm(-3), and concentrations of DOC in the range <1.0-1.8 mg dm(-3). The surface waters had a maximum dissolved concentration of reactive mercury of about 10 ng dm(-3), whereas for the more saline bottom waters it was about 65 ng dm(-3). The surface waters had maximum concentrations of total suspended particulate mercury of approximately 7 microg g(-1) and the bottom waters were always <1 microg g(-1). Concentrations of mercury in sediments was low and in the range from 0.06 to 0.18 microg g(-1). The transport of mercury in surface waters was mainly associated with organic-rich particulate matter, while in bottom waters the dissolved phase transport of mercury is more important. Lower particulate organic matter, formation of chlorocomplexes in more saline waters and eventually the presence of colloids appear to explain the difference of mercury partitioning in Douro estuarine waters.