Adsorption of anionic dye on magnesium hydroxide-coated pyrolytic bio-char and reuse by microwave irradiation

Magnesium hydroxide-coated pyrolytic bio-char composite was prepared by chemical precipitation, and the adsorption behavior of anionic dye (directly frozen yellow) onto magnesium hydroxide-coated pyrolytic bio-char was investigated in the batch mode. The Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy and X-ray fluorescence spectroscopy of adsorbents were characterized. Adsorption studies were performed at different pH, salt concentration, contacting time and dye concentration. The pH value of the solution influenced the adsorption capacity significantly, and adsorption is favored of pH 6–8. Salt coexisted in solution increased slightly directly frozen yellow adsorption capacity. The isotherm data were analyzed by Langmuir and Freundlich isotherm model, and Langmuir model was better to predict the equilibrium data. Thermodynamic calculations showed that the adsorption was a spontaneous and endothermic process. Exhausted magnesium hydroxide-coated pyrolytic bio-char was treated by microwave irradiation, and yield of regeneration was 98 % in the case of microwave irradiated time 5 min at 320 W. The magnesium hydroxide-coated pyrolytic bio-char can be reused.     

有机蒙脱石层间微结构的分子模拟

采用分子动力学模拟方法,对舍烷基长链阳离子表面活性剂改性有机蒙脱石的层间域内分子环境及烷基长链排列状况进行模拟研究,并考察改性剂负载量与层间域含水量的改变对烷基链排列方式和活动性以及表面活性剂离子中N,C原子的分布状况的影响.1.0倍阳离子交换容量改性的有机蒙脱石在含少量水的情况下(干态),N,C原子均呈双层分布,表明烷基长链为双层平卧排列.含水量的提高(湿态)会导致烷基链从双层分布向在层闻域内均匀分布转变.2.0倍阳离子交换容量改性的有机蒙脱石在舍少量水的情况下(干态),烷基链呈双层倾斜分布于层间域内,烷基链的头部靠近四面体片层.含水量的提高(湿态)对烷基链在层间域内分布状态影响有限,但会导致烷基链整体向层间域中心平面移动,水分子优先占据靠近四面体片层的位置.     

武汉市日供水量与气象要素的相关分析

利用武汉市逐日供水量资料与温度、降水、日照等气象要素进行同步相关分析,选取相关性较高的气温作为预报因子,建立了日供水量的简易预测模型。     

工业部门污染物治理协同控制温室气体效应评价——基于重庆市的实证分析

以高能耗为主要特征的工业部门是大气污染物和温室气体的重要排放源.为推动协同管控,文中结合生态环境部在重庆市组织开展的试点工作,对工业企业NOx污染治理协同控制温室气体的效应进行了量化分析.结果表明,以末端治理为手段的NOx治理措施协同控制温室气体的效果为负,即工业企业去除1 t NOx会直接或间接增加CO2排放1.81...     

Investigation about the dependence of spectral diffuse-to-direct-beam irradiance ratio on atmospheric turbidity and solar zenith angle

Summary The modifications of the solar spectral diffuse and direct-beam irradiances as well as the diffuse-to-direct-beam ratio, E_dλ/E_bλ, as a function of the aerosol optical depth, AOD, and solar zenith angle, SZA, is investigated. The E_dλ/E_bλ ratios decrease rapidly with wavelength and exponential curves in the form E_dλ/E_bλ = aλ^−b can be fitted with a great accuracy. These curves are strongly modified by the solar spectrum distribution, which is affected by the aerosol loading, aerosol optical properties and SZA. The spectral dependence of the above E_dλ/E_bλ ratios in logarithmic coordinates does not yield a straight line, while a significant departure from the linearity is revealed. The reasons for this departure are investigated in detail and it is established that the aerosol physical properties such as single scattering albedo and size distribution along with the effect of SZA are responsible. These parameters strongly affect the scattering processes in the atmosphere and as a consequence the diffuse spectral distribution. The E_dλ/E_bλ ratio, which is an indicator of the atmospheric transmittance (King, 1979), exhibits a strong wavelength and aerosol-loading dependence. The observed differences between turbid and clear atmospheres constitute a manifestation of contrasting air properties and influence solar irradiance spectra. The present work aims at investigating the effect of atmospheric turbidity and SZA on the E_dλ/E_bλ ratio. For this reason, two distinct cases are examined: one having different atmospheric turbidity conditions but same SZA and a second having different SZAs and same atmospheric turbidity levels.     

南极威德尔海冬季冰脊形拖曳力

利用2006年南极威德尔海冬季科学考察期间由机载激光高度计测得的海冰上表面形态数据,以拖曳分割理论为基础研究了冰脊形拖曳力及其对冰-气总拖曳力的贡献以及中性条件下对应10 m高度处风速的冰-气拖曳系数C_dn(10)。结果显示,在密集冰区,冰脊形拖曳力及其对总拖曳力的贡献随冰脊强度(脊高/脊距)的增大呈递增趋势,而随粗糙长度的增大而减小,对应于威德尔海冬季典型冰脊强度和粗糙长度,占总拖曳力的35%,说明了冰脊形拖曳力在冰-气界面动量交换中的重要作用。C_dn(10)随冰脊强度的增大而增大,但冰脊强度较小时,C_dn(10)随粗糙长度增大而增大;而对较大的冰脊强度,C_dn(10)则随粗糙长度增大而减小。     

三种非线性回归逐时气温预报比较订正

选取ECMWF和T639的2013年1月至2014年12月的数值预报场构造预报因子,基于神经网络、支持向量机和构造函数的非线性方法,预报地面逐时气温。试验结果显示,在单个方法预报误差较大时,3种方法的偏差订正集成方法更利于减小误差,通过偏差订正,3种非线性方法预报效果良好,平均绝对误差减小了0.5 ℃。在近1年独立样本的预报检验中,集成方法、神经网络、支持向量机和构造函数预报的平均绝对误差分别为1.5 ℃、1.7 ℃、1．8 ℃和1．4 ℃,总体上构造函数预报更为准确。     

冬春季切变类冰雹发生条件的对比分析

本文以 1996年 12月 31日和 1981年 5月 1日为例 ,对冬、春季节发生在江苏的较大范围的切变类冰雹天气过程作了对比分析。结果指出 ,无论冬季或春季当高原东部有深槽东移 ,冷暖空气在江淮地区交汇 ,地面抬升系统为暖切 ,并有大气层结不稳定 (Δθse( 50 0 - 850 ) <0℃ =中心和较强的风向和风速垂直切变、85 0hPa西南急流轴、85 0hPa最大水汽通量轴线、5 0 0和 85 0hPa正涡度中心等相配置时 ,就可能导致江苏地区较大范围强对流天气的发生。