Cation exchange capacity of loess and overlying soil in the non-carbonate loess sections, North-Western Croatia

The adsorption properties in terms of cation exchange capacity and their relation to the soil and sediment constituents (clay minerals, Fe-, Mn-, and Al-oxyhydroxides, organic matter) were investigated in loess, soil-loess transition zone, and soil at four loess-soil sections in North-Western Croatia. Cation exchange capacity of the bulk samples, the samples after oxalate extraction of Fe, Mn and Al, and after removal of organic matter, as well as of the separated clay fraction, was determined using copper ethylenediamine. Cation exchange capacity (pH～7) of the bulk samples ranges from 5 to 12 cmol _c /kg in soil, from 7 to 15 cmol _c /kg in the soil-loess transition zone, and from 12 to 20 cmol _c /kg in loess. Generally, CEC values increase with depth. Oxalate extraction of Fe, Mn, and Al, and removal of organic matter cause a CEC decrease of 3–38% and 8–55%, respectively, proving a considerable influence of these constituents to the bulk CEC values. In the separated clay fraction (<2 μm) CEC values are up to several times higher relative to those in the bulk samples. The measured CEC values of the bulk samples generally correspond to the clay mineral content identified. Also, a slight increase in muscovite/illite content with depth and the vermiculite occurrence in the loess horizon are concomitant with the CEC increase in deeper horizons, irrespective of the sample pretreatment.     

Application of the photoacoustic method for characterization of natural galena (PbS)

Electron transport properties of single crystal and polycrystalline natural mineral galena (PbS) samples from the Trep?a mine, Yugoslavia, were determined using the photoacoustic frequency transmission technique. Their thermal diffusivity (D _T≈0.16 × 10^?5 m² s^?1), the coefficient of diffusion (D between 0.15×10^?2 0.16×10^?2 m² s^?1) and lifetime of the excess carrier (τ≈35 μs and the front and rear recombination velocity (s _g≈65.5 m s^?1 and s _b≈66.4 m s^?1, respectively), were calculated by comparing the experimental results and the theoretical photoacoustic amplitude and phase signals. The lattice parameter obtained by X-ray work was a?=5.936?Å. The free carrier concentration of these single-crystal samples was measured using the Hall method (N?=?3×10¹⁸ cm^?3). Measurements of the optical reflectivity of the same samples, as a function of wavelength, in the infrared and far infrared ranges, were performed. In the far infrared range a free electron plasma frequency was observed and numerically analyzed, using the least-squares fitting procedure. The values of optical parameters were calculated and the value of the free carrier concentration obtained by the Hall method was confirmed.     

In situ Raman observation of the crystallization in NaNO3–Na2SO4–H2O solution droplets

Several double salts have been detected in building materials and most of these salts are incongruently soluble compounds. In contrast to single salts, however, no systematic investigations of the crystallization behavior and deleterious effects of incongruently soluble double salts exist. To assess the damage potential of these salts, a systematic investigation of their highly complex behavior is desirable. This paper deals with the crystallization behavior of various solids in the ternary mixed NaNO₃–Na₂SO₄ system including the formation of the double salt darapskite, Na₃NO₃SO₄·H₂O. The crystallization sequence during droplet evaporation experiments at room conditions was determined using Raman and polarization microscopy. The basic idea of this research is to use deviations of the crystallization sequence of a salt or a mixed salt solution from the equilibrium pathway as an indicator to detect the degree of supersaturation. The observed crystallization pathway includes the formation of the metastable phases Na₂SO₄(III), Na₂SO₄(V) and darapskite. The experimental observations are discussed on the basis of the NaNO₃–Na₂SO₄–H₂O phase diagram and the results provide evidence for crystal growth from highly supersaturated solutions in both systems. If the crystals growing under these conditions are confined, these supersaturations result in substantial crystallization pressures.     

Photometric and spectrophotometric observations of Nova Delphini 1967

Photographic, photovisual and photoelectric (V) observations of Nova Delphini 1967 were made from August 8 to October 31 (Table I, Figure 1). Simultaneously spectrophotometric measurements of the continuum were made on objective prism exposures extending to November 26, and spectrophotometric gradients derived (Tables II and III; Figures 3, 4, and 5). The continuum of Nova near its flat maximum is close to that of an early-type star in contrast to late-type absorptionline spectrum.     

Croatia — “a small country for a great vacation”

Croatia is a country of tourism, and this is primarily due to its position by the warm Adriatic Sea, its varying and picturesque landscapes, its diverse and generally favorable climate for tourism, its rich Mediterranean and Central European cultural heritage and its proximity to the leading European consumer countries.In the international tourism market, Croatia presents itself with the slogan A Small Country for a Great Vacation, because its 4.8 million inhabitants and surface area of 56,538 km² place Croatia in the ranks of the world's smaller countries. Its significance is increased by an additional 33,200 km² of territorial waters, of which a large part is considered internal waters because of its location within the limits of a series of islands.The tourism offering of Croatia is very diverse, but its basis is formed by three differing and mutually complimentary regions, through their natural characteristics and cultural heritage: coastal, montane and Pannonian and peri-Pannonian Croatia. The total tourism offering of Croatia includes 900,000 beds, of which over one-fifth are in hotels or similar places, two-fifths are in private rooms and one-third in camps.The tradition of tourism in Croatia is over one hundred years old, and according to the number of foreign tourists it is ranked as the fifth country for tourism in southern Europe.     

The global structural response model for multi-deck ships in concept design phase

This paper is an attempt to contribute to the improvement of an analysis model within overall structural synthesis procedure for the multi-deck ships. The paper is organized in two parts: modeling principles and model validation. Principles of the proposed generic model formulation on the global and sub-structure levels are given in detail while the load model is briefly summarized. The basic building blocks (macro-elements and gross-elements) for the modeling of ordinary stiffened panels, combining numerical and analytical approaches, are presented and discussed w.r.t. requirements for a multi-deck structure. Different surrogates (sets of elements and ordinary macro-elements) used for equivalent modeling of large side openings are evaluated, since the reduced shear stiffness of superstructure sides has large influence on the hull girder stress distributions along the entire cross section height. The generic ship models developed using outlined principles and the basic building blocks are further validated through complex examples of a large cruise ship and a livestock carrier. On the global level, the accuracy of the generic model w.r.t. the longitudinal stress distribution over ships height is compared with a standard full ship FE model. The results confirmed that the suggested structural modeling principles, based on the generic FE model can be applied for the fast investigation of different structural topological/geometrical concepts as well as for the ordinary scantling/material optimization.     

An analysis of close binaries (CB) based on photometric measurements (VII)

The paper is devoted to the actual problematics in the determination of orbital and physical parameters of active CB on the basis of the interpretation of photometric observations. One solves the problem in two stages: by obtaining a synthetic light curve in the case when the parameters of the corresponding CB model (Djuraevi, 1992a) are given a priori (direct problem) and by determining the parameters of the given model for which the best fit between the synthetic light curve and the observations is achieved (inverse problem) (Djuraevi, 1992b). In this paper, the above procedure is applied to a particular case of an interpretation of CB light curves AU Ser and RV Corvi.     

Kinematics in the z = 2.81 Galaxy and the Evidence for Rotation

The existence of rotation signatures in damped Lyαabsorption systems represents a crucial test of the hypothesis that these features arise in disks of normal spiral galaxies. We apply the method for evaluating such signatures to the metal absorption lines in QSO 0528-250. In particular, the systemic redshift of the absorber is inferred from the recent detection of emission in the absorber by Möller and Warren. The kinematics of this absorber are particularly interesting because molecular hydrogen, the densest ISM component of the assumed foreground absorbing galaxy, is detected. Contrary to a recent claim, the method yields a satisfactory value for the assumed rotation velocity of the absorber.     

Meridional Motion and Reynolds Stress from Debrecen Photoheliographic Data

The Debrecen Photoheliographic Data catalogue is a continuation of the Greenwich Photoheliographic Results providing daily positions of sunspots and sunspot groups. We analyse the data for sunspot groups focussing on meridional motions and transfer of angular momentum towards the solar equator. Velocities are calculated with a daily shift method including an automatic iterative process of removing the outliers. Apart from the standard differential rotation profile, we find meridional motion directed towards the zone of solar activity. The difference in measured meridional flow in comparison to Doppler measurements and some other tracer measurements is interpreted as a consequence of different flow patterns inside and outside of active regions. We also find a statistically significant dependence of meridional motion on rotation velocity residuals confirming the transfer of angular momentum towards the equator. Analysis of horizontal Reynolds stress reveals that the transfer of angular momentum is stronger with increasing latitude up to about \(40^{\circ}\), where there is a possible maximum in absolute value.