Eutrophication processes and trophic interactions in a shallow estuary: Preliminary results based on stable isotope analysis (δ13C and δ15N)

Stable isotopes ratios (δ¹³C and δ¹⁵N) were measured in primary producers and consumers of two bays with contrasting eutrophic conditions in the Patos Lagoon estuary, southern Brazil: the Justino bay, a more pristine ecosystem, and the Mangueira bay, a heavily polluted region that receives the Rio Grande city sewage and effluencts of several industries. δ¹³C values of organisms collected in both subsystems were not different, but δ¹⁵N values had significant statistical differences, ca. 3.5‰ higher in the Mangueira bay. It is likely that primary producers and consumers in this subsystem are greatly influenced by higher nitrogen input due to domestic and industrial sewages. The stable isotope analysis also corroborated several trophic interactions previously established by gut content analysis, and due to its higher sensitivity, it was possible to better determine the contributions of different primary producers and detrital fractions to the consumers' diets. It was confirmed that plant detritus represents the main food source for most organisms. The stable isotope analysis also demonstrated that detritivorous benthic organisms in the same habitat have distinct diet compositions, with differential consumption of C3 and C4 plants. This technique showed that some consumers that eat detritus do not have in their stable isotopic signature any relationship with that of plants. It is likely that these consumers assimilate their carbon and nitrogen from other sources like microalgae or microorganisms that colonize decaying plants.     

The link between partial melting,granitization and granulite development in central Ribeira Fold Belt,SE Brazil: New evidence from elemental and Sr–Nd isotopic geochemistry

Elemental and Sr–Nd isotopic data on metatexites, diatexites, orthogneisses and charnockites from the central Ribeira Fold Belt indicate that they are LILE-enriched weakly peraluminous granodiorites. Harker and Th–Hf–La correlation trends suggest that these rocks represent a co-genetic sequence, whereas variations on CaO, MnO, Y and HREE for charnockites can be explained by garnet consumption during granulitic metamorphism.Similar REE patterns and isotopic results of ?_Nd⁵⁶⁵ = ?5.4 to ?7.3 and ⁸⁷Sr/⁸⁶Sr₅₆₅ = 0.706–0.711 for metatexites, diatexites, orthogneisses and charnockites, as well as similar T_DM ages between 2.0 and 1.5 Ga are consistent with evolution from a relatively homogeneous and enriched common crustal (metasedimentary) protolith.Results suggest a genetic link between metatexites, diatexites, orthogneisses and charnockites and a two-step process for charnockite development: (a) generation of the hydrated igneous protoliths by anatexis of metasedimentary rocks; (b) continuous high-grade metamorphism that transformed the “S-type granitoids” (leucosomes and diatexites) into orthogneisses and, as metamorphism and dehydration progressed, into charnockites.     

Contributions of individual countries?? emissions to climate change and their uncertainty

We have compiled historical greenhouse gas emissions and their uncertainties on country and sector level and assessed their contribution to cumulative emissions and to global average temperature increase in the past and for a the future emission scenario. We find that uncertainty in historical contribution estimates differs between countries due to different shares of greenhouse gases and time development of emissions. Although historical emissions in the distant past are very uncertain, their influence on countries?? or sectors?? contributions to temperature increase is relatively small in most cases, because these results are dominated by recent (high) emissions. For relative contributions to cumulative emissions and temperature rise, the uncertainty introduced by unknown historical emissions is larger than the uncertainty introduced by the use of different climate models. The choice of different parameters in the calculation of relative contributions is most relevant for countries that are different from the world average in greenhouse gas mix and timing of emissions. The choice of the indicator (cumulative GWP weighted emissions or temperature increase) is very important for a few countries (altering contributions up to a factor of 2) and could be considered small for most countries (in the order of 10%). The choice of the year, from which to start accounting for emissions (e.g. 1750 or 1990), is important for many countries, up to a factor of 2.2 and on average of around 1.3. Including or excluding land-use change and forestry or non-CO₂ gases changes relative contributions dramatically for a third of the countries (by a factor of 5 to a factor of 90). Industrialised countries started to increase CO₂ emissions from energy use much earlier. Developing countries?? emissions from land-use change and forestry as well as of CH₄ and N₂O were substantial before their emissions from energy use.     

Modeling rock permeability from NMR relaxation data by PLS regression

This study explores the application of the partial least squares regression (PLSR) technique to rock permeability prediction from nuclear magnetic resonance (NMR) relaxation data. A total of 68 Brazilian sandstone cores selected from reservoirs and outcrop analogs were fully saturated and analyzed by NMR. The permeability of the cores ranged from 0.007 to 9,800 mD. From their ¹H transverse relaxation times (T₂) measured at 2 MHz, two PLSR models were developed for the relaxation spectra and the raw relaxation curves. Both models led to more uniform and accurate predictions (RMSE = 0.47 and 0.50 log mD, respectively) compared with the classical Kenyon model (RMSE = 0.78 log mD).     

Complex size-dependent habitat associations in potamodromous fish species

Knowledge of the distribution of species life stages at multiple spatial scales is fundamental to both a proper assessment of species management and conservation programmes and the ability to predict the consequences of human disturbances for river systems. The habitat requirements of three native cyprinid species—the Iberian barbel Barbus bocagei Steindachner, the Iberian straight-mouth nase Pseudochondrostoma polylepis (Steindachner), and the Northern straight-mouth nase Pseudochondrostoma duriense (Coelho)—were examined at 174 undisturbed or minimally disturbed sites in 8 river catchments across western Iberia, by modelling occurrence and counts of species life stages at two spatial scales—large (regional) and instream (local)—using hurdle models. All the life stages of the barbel showed a negative association with upstream high-gradient river reaches, whereas juvenile P. duriense favoured such areas. Stream width and openness were negatively related with the occurrence of juvenile and small adult barbel, but not with large adults. Juvenile nase, on the other hand, were found to be mainly confined to fast-flowing habitats with high instream cover and coarser substrata. Advanced life stages of the barbel were mainly associated with the “pure” regional and shared components, whereas the purely local attributes accounted for much of the model variation among nases, in particular juveniles, and juvenile barbel. The results of this study are useful for setting or refining management goals, and highlight the need to separately consider life stages when performing conservation-related studies of species distribution.     

Recovery of macrobenthos in defaunated tropical estuarine sediments

In the estuarine environment, hypoxia and/or anoxia have become a major cause of benthic defaunation and are strongly associated with increased eutrophication. Mesoscale field experiments were carried out to examine the recolonization and recovery time of macrobenthos after defaunation. Azoic sediments were achieved by covering four areas with polyethylene sheeting. Temporal changes and depth distribution of macrobenthos within the defaunated sediments were compared with those in undisturbed natural sediments at the same site. Within 3 days, annelids appeared as the first immigrants. After 153 days, the process of recovery had not yet been completed in terms of species richness. Whereas diversity and evenness showed no significant differences between treatments during the entire experiment, multivariate analyses proved that differences between treatments were still significant 93 days after the start of the experiment.     

Numerical analysis of an embankment built on soft soil reinforced with deep mixing columns: Parametric study

The behaviour of an embankment built on normally consolidated soft soil reinforced with deep mixing columns is studied using a coupled soil–water formulation. The numerical predictions are analysed in terms of settlements, increments in vertical effective stresses and excess pore pressures. Firstly, the effectiveness of the use of deep mixing columns is studied. Afterwards, a parametric analysis is performed to study the influence on the soil-columns system of the replacement ratio (columns’ spacing), the deformability of the embankment and columns, and the coefficient of vertical permeability of the columns.     

Free Eu(III) Determination by Donnan Membrane Technique with Electrochemical Detection: Implementation and Evaluation

Aquatic Geochemistry - The aim of this study was to develop an analytical method to determine free concentrations of Europium (Eu(III)) in natural waters. Europium(III) in solution was detected...     

Analysis of the 1 November 2015 heavy rainfall episode in Algarve by using weather radar and rain gauge data

The trigger for the study presented in this paper was the extreme rain event of 1 November 2015 in Algarve region. The main objective was the analysis and improvement of the precipitation field using a radar–rain gauge merging method. Ordinary kriging with radar-based error correction has been applied to hourly values of precipitation from both sensors. The merging technique allowed keeping the better radar spatial pattern, being the respective estimates corrected by the rain gauges observations. The procedure led to a reduction in the errors of the precipitation estimates, evaluated by cross-validation, when compared to univariate interpolation of rain gauge observation or radar rain product. Finally, some discussion is also added on the problematic of flooding in urban areas, especially those with absent or deficient urban planning.