Glass and Mineral Chemistry of Northern Central Indian Ridge Basalts:Compositional Diversity and Petrogenetic Significance

Abstract: The glass and mineral chemistry of basalts examined from the northern central Indian ridge (NCIR) provides an insight into magma genesis around the vicinity of two transform faults: Vityaz (VT) and Vema (VM). The studied mid-ocean ridge basalts (MORBs) from the outer ridge flank (VT area) and a near-ridge seamount (VM area) reveal that they are moderately phyric plagioclase basalts composed of plagioclase (phenocryst [An60–90] and groundmass [An35–79]), olivine (Fo81–88), diopside (Wo45–51, En25–37, Fs14–24), and titanomagnetite (FeOt ~63.75 wt% and TiO2 ~22.69 wt%). The whole-rock composition of these basalts has similar Mg# [mole Mg/mole(Mg+Fe2+)] (VT basalt: ~0.56–0.58; VM basalt: ~0.57), but differ in their total alkali content (VT basalt: ~2.65; VM basalt: ~3.24). The bulk composition of the magma was gradually depleted in MgO and enriched in FeOt, TiO2, P2O5, and Na2O with progressive fractionation, the basalts were gradually enriched in Y and Zr and depleted in Ni and Cr. In addition, the SREE of magma also increased with fractionation, without any change in the (La/Yb)N value. Glass from the VM seamount shows more fractionated characters (Mg#: 0.56–0.57) compared to the outer ridge flank lava of the VT area (Mg#: 0.63–0.65). This study concludes that present basalts experienced low-pressure crystallization at a relatively shallow depth. The geochemical changes in the NCIR magmas resulted from fractional crystallization at a shallow depth. As a consequence, spinel was the first mineral to crystallize at a pressure >10 kbar, followed by Fe-rich olivine at <10 kbar pressure.     

Systematic increase in model complexity helps to identify dominant streamflow mechanisms in two small forested basins

This study shows how the use of increasing model complexity allows us to hypothesize about dominant streamflow mechanisms in two small Brazilian forested basins. Nine different structures from SUPERFLEX, an objective framework to systematically increase hydrological model complexity, were tested and we extended the flexible modelling methodology to error models as well. We show that applying a rigorous methodology in a model evaluation framework, with residual analysis and control of model complexity, is essential for testing a model as a hypothesis for dominant hydrological controls. Our results indicate that the model architecture was more important than the increase in the number of model parameters. Better performing models were those with a parallel structure, which confirms our a priori belief about the dominant runoff mechanisms of the studied catchments, characterized by a rapid response to rainfall, but also a constant river discharge fed by water storage on the thick soil layer.     

Combined effects of waves and plants on a mud deposition event at a mudflat-saltmarsh edge in the Bahía Blanca estuary

This study was carried out at the Bahía Blanca Estuary, Argentina, at the seaward edge of a saltmarsh. The saltmarsh-mudflat boundary in the study area shows sediment deposits at a higher elevation immediately seaward of the saltmarsh edge. We compared field determinations of water velocity, bed shear stress, wind wave conditions and variations of the bed elevation in the mudflat and within the Spartina alterniflora canopy at the seaward edge of a saltmarsh, and we evaluated the relative role of vegetation in the observed morphology. A mud deposition event that raised bed elevation in more than 5 cm occurred during the study period, with TSS concentrations > 500 mg l⁻¹, but simultaneous measurements performed on the bed levels confirmed that the sediments deposited did not originate from local resuspension within the edge of the canopy. In similar tidal cycles in terms of local wave activity and bed shear stresses at the sampling site, deposition occurred only with winds aligned with the azimuth of the Canal Principal, reaching a maximum fetch of more than 20 km in front of the sampling site.     

Effects of naphthalene and phenanthrene on visual and prey capture endpoints during early stages of the dourado Salminus brasiliensis

Naphthalene (NAP) and phenanthrene (PHE) effects on Salminus brasiliensis, a carnivorous freshwater fish, were investigated using behavioral tests. Larval stages of S. brasiliensis were exposed to water concentrations of 0, 0.04 mg/l, 0.20mg/l and 0.50mg/l for naphthalene and 0, 0.01 mg/l, 0.05 mg/l and 0.1mg/l for phenanthrene during two developmental phases. The prey fish Prochilodus lineatus were not exposed. Visual acuity was measured at the end of phase 2 in individual S. brasiliensis, which were also tested at the end of each phase for number of attacks on prey, number of prey captured, prey capture efficiency, and distance swam. Vision was impaired by PHE exposure, as acuity angles increased in exposed fish. At Stage I 2.3+/-1.2 prey were captured with 46% efficiency in controls compared to 0.4+/-0.3 prey captured with 13.4% efficiency in fish exposed to 0.05 mg PHEl(-1), the LOEL for both endpoints. At Stage II 4.0+/-1.1 preys were captured in controls compared to 2.5+/-0.9 preys captured in fish exposed to 0.01 mg PHEl(-1), the LOEL. Stage II control fish captured prey with 70% efficiency compared to 30% efficiency at Stage II fish exposed to 0.05 mg PHEl(-1), the LOEL. Distance swam was not affected by either NAP or PHE exposure. The exposure of larval stages of S. brasiliensis to realistic water concentrations of PHE impairs foraging skills and could affect recruitment of the species.     

Horse mackerel egg identification using DNA methodology

Egg identification in plankton samples is usually needed for purposes of stock assessment. Until recently, only morphological characters were used for identifying the eggs of different fish species. Late developmental stages are easily distinguishable due to pigmentation as well as egg and oil globule size range. However, for early stages, these characteristics are difficult to be discriminated and may overlap with other species. European horse mackerel species (Trachurus trachurus, T. mediterraneus, T. picturatus) overlap significantly in their spawning areas in some European waters. Because of the fact that their eggs are morphologically similar, genetic methodologies are needed to identify eggs and larvae to species correctly. In the present study, formalin‐ and ethanol‐preserved eggs were tested to estimate the efficacy of genetic methodologies for species identification of eggs when different preservatives are used. A 370‐bp fragment of cytochrome b was successfully amplified followed by restriction fragment analysis with two restriction enzymes aiming to identify the eggs to species. Horse mackerel egg identification was accomplished with the maximum success in ethanol‐preserved eggs. However, it seems that various preservatives had different effects on the DNA quality of eggs as genetic identification was less successful in formalin‐preserved eggs. Preserving in ethanol a part of the eggs obtained in plankton surveys is suggested for purposes of accurate genetic identification, even if their morphological features are distorted in time.     

Freshwater export from the Labrador Current to the North Atlantic Current at the Tail of the Grand Banks of Newfoundland

Historical hydrographic data, spanning the period 1896–2006, are used to examine the annual mean and seasonal variations in the distribution of freshwater along and across the shelf/slope boundary along the Labrador and Newfoundland Shelves and the Grand Banks of Newfoundland. Particular attention is paid to the export of freshwater along the eastern Grand Banks, between Flemish Cap and the Tail of the Grand Banks, as this has long been identified as a preferential region for the loss of mass and freshwater from the boundary. The data are combined into isopycnally averaged long-term annual and monthly mean gridded property fields and the evolving distribution of fresh arctic-origin water is analyzed in fields of salinity anomaly, expressed as departures from the “central water” temperature–salinity relation of the Gulf Stream. The climatology confirms that cold/fresh northern-source waters are advected offshore within the retroflecting Labrador Current along the full length of the boundary between Flemish Cap and the Tail of the Grand Banks. In fact, it is estimated that most of the equatorward baroclinic transport at the boundary must retroflect back toward the north in order to explain the annual mean distribution of salinity in the climatology. While the retroflection of the Labrador Current appears seasonally robust, the freshwater distribution within the retroflection region varies in response to (1) the freshness of the water available for export which is set by the arrival and rapid flushing of the seasonal freshwater pulse at the boundary, (2) seasonal buoyancy forcing at the surface which alters the vertical stratification across the retroflection region, restricting certain isopycnal export pathways, and (3) the density structure along the eastern Grand Banks, which defines the progressive retroflection of the Labrador Current.     

Small-scale fisheries and food security strategies in countries in the Benguela Current Large Marine Ecosystem (BCLME) region: Angola,Namibia and South Africa

This paper provides an overview of the small-scale fisheries sector in countries within the Benguela Current Large Marine Ecosystem (BCLME), one of the most productive large marine ecosystems in the world. The study revealed that Angola, Namibia and South Africa have very different legal and policy frameworks, show different levels of compliance with international and regional agreements to protect the livelihoods and food security of small-scale fishers, as well as of integration of fisheries into food security objectives. Angolan law recognises and protects small-scale fishers through legal and institutional mechanisms. In Namibia, this sector of fishers is not legally recognised, while in South Africa traditional fishers have been largely excluded from the new fisheries management framework. Trends in national and regional fish consumption and in the extent of export orientation in fisheries are explored, as well as the potential threats to small-scale producers and food security in the region posed by ongoing drives to incorporate fisheries in the World Trade Organisation (WTO) agreements.     

Long-Term Trends in Intertidal and Subtidal Benthic Communities in Response to Water Quality Improvement Measures

Long-term monitoring studies are needed to understand changes in ecosystem status when restoration measures are implemented. A long-term data series (1996–2007) of the Tagus estuary (Portugal) intertidal and subtidal benthic communities was collected in a degraded area where mitigation measures were implemented. Multivariate analysis was used to analyze spatial and temporal patterns in benthic community composition and trends in five benthic community metrics (i.e., taxonomic richness, density, biomass, Shannon–Wiener diversity and the AMBI index) were also examined. The results revealed a clear separation between intertidal and subtidal assemblages, although they had 50% of taxa in common, including the most abundant. Significant positive trends were found for all metrics showing that both intertidal and subtidal communities responded to the restoration measures implemented. Nevertheless, biotic indices need some adaptation before being universally applied to intertidal and subtidal habitats.     

Short-range order and frustration in omphacite: Comparison of three CVM approximations

We compare three cluster variation method (CVM) models for order-disorder in omphacite (Al_0.5Mg_0.5)[Na_0.5Ca_0.5]Si₂O₆: the generalized point approximation (GPA), generalized pair approximation (GPaA) and an approximation that is based on two eight-body clusters (2X8A). The same Hamiltonian (set of pairwise interactions) is used for all three approximations. Pair probabilities predicted by the GPA obey the geometric constraints of the crysal structure (the frustration constraint), but the exclusion of short-range order (SRO) leads to overestimates of the configurational internal energy (〈E〉), and the critical temperature for cation order-disorder (T _c ). The GPaA violates the frustration constraint, and it therefore fails to predict a P2 ₁/n → C2/c order-disorder transition and yields values for 〈E〉 and SRO that are inconsistent with the omphacite crystal structure. The 2X8A predicts SRO that is consistent with the frustration constraint, and it yields improved (lower) estimates of 〈E〉 and T _c relative to the GPA: 〈E〉_2X8A<〈E〉_GPA, and T _c (2X8A)≈0.741 T _c (GPA).