Application of biomarkers for improving risk assessments of chemicals under the Water Framework Directive: a case study

To answer the requirement of the European Commission's Water Framework Directive (WFD) for biological-effects endpoints to classify the ecological health of aquatic ecosystems, we propose the biomarker response index (BRI). The BRI, based on a suite of biomarkers at different levels of biological response at the individual level, provides an integrated relative measure of the general health status of coastal invertebrates. Using the BRI, the health of mussels (Mytilus edulis) from 10 estuaries classified by the Environment Agency of England and Wales under the WFD was compared. Eight sites were healthier than predicted and two showed a similar health status to that of the predicted point-source pollution risk classification. Results indicate that the BRI offers a potential measure of organism health that can be used in monitoring under the WFD as an additional aid to reduce uncertainty in defining risk classification and to provide better evidence of existing impact.     

Neogene-Quaternary tectonic evolution of the Leeward Antilles islands (Aruba, Bonaire, Curaçao) from fault kinematic analysis

Aruba, Bonaire, and Curaçao are islands aligned along the crest of a 200-km-long segment of the east-west-trending Leeward Antilles ridge within the broad Caribbean-South America plate boundary zone presently characterized by east-west, right-lateral strike-slip motion. The crust of the Leeward Antilles ridge represents the western segment of the Cretaceous-early Cenozoic Great Arc of the Caribbean, which obliquely collided, with the continental margin of northern South America in early Cenozoic time. Following the collision, the ridge was affected by folding and was segmented by oblique, northwest-striking normal faults that have produced steep-sided, northwest-trending, elongate islands and narrow shelves separated by deepwater, sediment-filled and fault-controlled basins. In this paper, we present the first fault slip observations on the Neogene carbonate rocks that cover large areas of all three islands. Our main objective is to quantify the timing and nature of Neogene to Quaternary phases of faulting and folding that have affected the structure and topography of this area including offshore sedimentary basins that are being explored for their petroleum potential. These data constrain three fault phases that have affected Aruba, Bonaire, and Curaçao and likely the adjacent offshore areas: 1) NW-SE-directed late Paleogene compression; 2) middle Miocene syndepositional NNW-SSE to NNE-SSW extension that produced deep rift basins transverse to the east-west-trending Leeward Antilles ridge; and 3) Pliocene-Quaternary NNE-trending compression that produced NW-SE-trending anticlines present on Aruba, Curaçao and Bonaire islands. Our new observations - that include detailed relationships between striated fault planes, paleostress tensors, and bedding planes - show that prominent bedding dips of Neogene limestone on Aruba, Bonaire and Curaçao were produced by regional tectonic shortening across the entire Leeward Antilles ridge rather than by localized, syndepositional effects as proposed by previous workers. We interpret Pliocene-Quaternary NNE-directed shortening effects on the Leeward Antilles ridge as the result of northeastward extrusion or “tectonic escape” of continental areas of western Venezuela combined with southeastward shallow subduction of the Caribbean plate beneath the ridge.     

International Silica Cycle Workshop held in Hangzhou

正Silicon is the second most abundant element on the planet Earth. Its electronic configuration is close to that of carbon, but the aqueous environment prevailing on our planet gives advantages to carbon compounds at the expenses of siliceous compounds.Silicified organisms, however, are everywhere on Earth, particularly in the marine realm where siliceous diatoms play a key role in the ocean biological carbon pump. Thus, a better understanding of the processes that control the silica cycle at global scale is crucial.     

Transforming local natural resource conflicts to cooperation in a changing climate: Bangladesh and Nepal lessons

ABSTRACT

Since the 1990s, climate change impact discourse has highlighted potential for large scale violent conflicts. However, the role of climate stresses on local conflicts over natural resources, the role of policies and adaptation in these conflicts, and opportunities to enhance cooperation have been neglected. These gaps are addressed in this paper using evidence from participatory action research on 79 cases of local collective action over natural resources that experience conflicts in Bangladesh and Nepal. Climate trends and stresses contributed to just under half of these conflict cases. Nine factors that enable greater cooperation and transformation of conflict are identified. Participatory dialogue and negotiation processes, while not sufficient, changed understanding, attitudes and positions of actors. Many of the communities innovated physical measures to overcome natural resource constraints, underlying conflict, and/or institutional reforms. These changes were informed by improving understanding of resource limitations and indigenous knowledge. Learning networks among community organizations encouraged collective action by sharing successes and creating peer pressure. Incentives for cooperation were important. For example, when community organizations formally permitted excluded traditional resource users to access resources, those actors complied with rules and paid towards management costs. However, elites were able to use policy gaps to capture resources with changed characteristics due to climate change. In most of the cases where conflict persisted, power, policy and institutional barriers prevented community-based organizations from taking up potential adaptations and innovations. Policy frameworks recognizing collective action and supporting flexible innovation in governance and adaptation would enable wider transformation of natural resource conflicts into cooperation.

Key policy insights

• Climate stresses, policy gaps and interventions can all worsen local natural resource conflicts.

• Sectoral knowledge and technical approaches to adaptation are open to elite capture and can foster conflicts.

• Many local natural resource conflicts can be resolved but this requires an enabling environment for participatory dialogue, external facilitation, flexible responses to context, and recognition of disadvantaged stakeholder interests.

• Transforming conflict to greater cooperation mostly involves social and institutional changes, so adaptation policies should focus less on physical works and more on enabling factors such as negotiation, local institutions, knowledge, and incentives.

     

Aluminous goethite: A mössbauer study

Mössbauer measurements at 300 K, 77 K and 4.2 K and X-ray data are presented for synthetic aluminous goethites (α Fe_1?x Al _x OOH) in two series containing up to 15 mole percent aluminium (hydrothermal preparation) and 19 mole percent aluminium (low-temperature preparation). The Mössbauer spectra for specimens at 300 K and 77 K display broadened and relaxed line-shapes with the relaxation rate increasing with aluminium substitution, whereas all the 4.2 K spectra can be described by a single magnetically split spectrum. At 4.2 K the magnitude of this splitting is 505 kOe for pure goethite and it decreases by 0.52 kOe per mole percent aluminium substitution. The absolute value of the recoil-free fraction f at 4.2 K has been measured for pure goethite and for aluminous goethites containing 7, 15 and 19 mole percent aluminium; it increases from f=0.69±0.02 to f=0.89±0.02 in this range. The increase is attributed to a stiffening of the goethite lattice as it contracts to accommodate the smaller aluminium ion. At 300 K f is found to decrease from f=0.65±0.05 for pure goethite to f=0.50±0.03 for goethite with 19 mole percent aluminium.     

Phytoplankton abundance and contributions to suspended particulate matter in the Ohio,Upper Mississippi and Missouri Rivers

Main channel habitats of the Ohio, Missouri, and Upper Mississippi Rivers were surveyed during the summers of 2004, 2005 and 2006 using a probability-based sampling design to characterize inter-annual and inter-river variation in suspended chlorophyll a (CHLa) and related variables. Large (fivefold) differences in CHLa were observed with highest concentrations in the Upper Mississippi (32.3 ± 1.8 μg L⁻¹), intermediate values in the Missouri (19.7 ± 1.1 μg L⁻¹) and lowest concentrations in the Ohio (6.8 ± 0.5 μg L⁻¹). Inter-annual variation was small in comparison to inter-river differences suggesting that basin-specific factors exert greater control over river-wide CHLa than regional-scale processes influencing climate and discharge. The rivers were characterized by variable but generally low light conditions as indicated by depth-averaged underwater irradiance <4 E m⁻² day⁻¹ and high ratios of channel depth to euphotic depth (>3). Despite poor light conditions, regression analyses revealed that TP was the best single predictor of CHLa (R ² = 0.40), though models incorporating both light and TP performed better (R ² = 0.60). Light and nutrient conditions varied widely within rivers and were inversely related, suggesting that riverine phytoplankton may experience shifts in resource limitation during transport. Inferred grazing and sedimentation losses were large yet CHLa concentrations did not decline downriver indicating that growth and loss processes were closely coupled. The contribution by algae to suspended particulate organic matter in these rivers (mean = 41%) was similar to that of lakes (39%) but lower relative to reservoirs (61%).     

At the heart of the cultural approach in geography: Thinking space

The way that space is thought of is at the heart of the cultural approach in geography. The passing down of all the components of a culture depends upon the way data is aquired and processed, the results memorized or broadcast. Communication shapes the experience and the knowledge of space and time. It gives to everyone the idea that the real world is doubled by a beyond which plays a central role in social life, since it is upon such a beyond that normative thinking relies and that a significance is given to individual and social life. The spheres of lived-in and known space and time, as well as that of the beyond, vary according to available technologies. This revised version was published online in July 2006 with corrections to the Cover Date.     

Spatial and temporal variability and drivers of net ecosystem metabolism in western Gulf of Mexico estuaries

Net ecosystem metabolism (NEM) is becoming a commonly used ecological indicator of estuarine ecosystem metabolic rates. Estuarine ecosystem processes are spatially and temporally variable, but the corresponding variability in NEM has not been properly assessed. Spatial and temporal variability in NEM was assessed in four western Gulf of Mexico shallow water estuaries. NEM was calculated from high-frequency dissolved oxygen measurements. Interbay, intrabay, and water column spatial scales were assessed for NEM, gross primary production (GPP), and respiration (R) rate variability. Seasonal, monthly, and daily temporal scales in NEM, GPP, and R were also assessed. Environmental conditions were then compared to NEM to determine which factors were correlated with each temporal and spatial scale. There was significant NEM spatial variability on interbay, intrabay, and water column spatial scales. Significant spatial variability was ephemeral, so it was difficult to ascertain which environmental conditions were most influential at each spatial scale. Significant temporal variability in NEM on seasonal, monthly, and daily scales was found and it was correlated to temperature, salinity, and freshwater inflow, respectively. NEM correlated strongly with dissolved oxygen, temperature, and salinity, but the relationships where different in each bay. The dynamics of NEM on daily scales indicate that freshwater inflow events may be the main driver of NEM in the semiarid estuaries studied. The variable nature of NEM found here is further evidence that it is not valid to use single station monitoring deployments for assessment of whole estuarine ecosystem metabolic rates in large ecosystems. The relationship between NEM and temperature, salinity, and freshwater inflow events could drive predictive models assessing the potential influence of projected climate change and watershed development scenarios on estuarine metabolic rates.