Extension of Penman's formulae to multi-layer models

In this paper, the well-established multi-layer model originally devised by Waggoner and Reifsnyder (1968) is used. This steady-state model based on an electrical analogue simulates the energy exchange between the vegetation and the atmosphere. A purely mathematical development of the basic equations of this model yields explicit expressions of the total fluxes of sensible and latent heat at the top of the canopy as a function of the net radiation absorbed in each layer, the soil heat flux, the water vapour pressure deficit at a reference height and the whole set of elementary conductances (stomatal, boundary-layer and aerodynamic). These new equations can be considered as a generalization of the familiar Penman's formulae to a multi-layer model.     

Macroseepage of methane and light alkanes at the La Brea tar pits in Los Angeles

Geologic seepage of methane and light (C₂-C₅) alkanes was measured at the La Brea Tar Pits in Los Angeles. Samples were collected using flux chambers with stainless steel canisters and analyzed using gas chromatography. Average seepage rates from individual seepage sites were 970 ± 330 mg/h of methane, 14.0 ± 5.5 mg/h of ethane, 9.1 ± 3.7 mg/h of propane, 3.7 ± 1.6 mg/h of i-butane, 0.33 ± 0.16 mg/h of n-butane, 260 ± 120 μg/h of i-pentane, and 5.3 ± 1.9 μg/h of n-pentane, while maximum seepage rates exceeded 17 g/h of methane, 270 mg/h of ethane, 190 mg/h of propane, 95 mg/h of i-butane, 10 mg/h of n-butane, 7 mg/h of i-pentane, and 0.1 mg/h of n-pentane. These absolute fluxes have an additional unknown amount of error associated with them due to sampling methodology, and should be taken as the lower limit of emissions. Samples collected revealed generally dry gas, with high methane emissions relative to the light alkanes. Overall emissions from the tar pits were found to come not only from the active geologic seepage, but also from the outgassing of the standing asphalt at the site. Using the gas ratios, which are negligibly affected by errors introduced by sampling methodology, observed in this study, daily emissions of C₂ – C₅ alkanes from the La Brea area were estimated to be 4.7 ± 1.6 Mg, which represents 2–3 % of total emissions in the entire Los Angeles region.     

Enhancing the relevance of Shared Socioeconomic Pathways for climate change impacts,adaptation and vulnerability research

This paper discusses the role and relevance of the shared socioeconomic pathways (SSPs) and the new scenarios that combine SSPs with representative concentration pathways (RCPs) for climate change impacts, adaptation, and vulnerability (IAV) research. It first provides an overview of uses of social–environmental scenarios in IAV studies and identifies the main shortcomings of earlier such scenarios. Second, the paper elaborates on two aspects of the SSPs and new scenarios that would improve their usefulness for IAV studies compared to earlier scenario sets: (i) enhancing their applicability while retaining coherence across spatial scales, and (ii) adding indicators of importance for projecting vulnerability. The paper therefore presents an agenda for future research, recommending that SSPs incorporate not only the standard variables of population and gross domestic product, but also indicators such as income distribution, spatial population, human health and governance.     

Geoarchaeological and Bioarchaeological Studies at Mira,an Early Upper Paleolithic Site in the Lower Dnepr Valley,Ukraine

New geoarchaeological and bioarcheological research was undertaken at the open‐air site of Mira, which is buried in deposits of the Second Terrace of the Dnepr River, roughly 15 km downstream from the city of Zaporozhye in Ukraine. Previous excavation of the site revealed two occupation layers dating to ∼32,000 cal BP. The lower layer (II/2) yielded bladelets similar to those of the early Gravettian, while the upper layer (I) contained traces of an artificial shelter and hundreds of bones and teeth of horse (Equus latipes). Mira represents the only firmly dated early Upper Paleolithic (EUP) site in the Dnepr Basin, and occupies a unique topographic setting for the EUP near the center of the broad floodplain of the Dnepr River. The site was visited during a period of floodplain stability, characterized by overbank deposition and weak soil formation under cool climate conditions. Mira was used as a long‐term camp, but also was the locus of large‐mammal carcass processing associated with a nearby kill of a group of horses (Layer I).     

The presence of moral hazard regarding flood insurance and German private businesses

Natural Hazards - There is a movement towards the concepts of integrated flood risk management and governance. In these concepts, each stakeholder prone to flooding is tasked with actively limiting...     

Determination of the REE in Geological Reference Materials DTS-1 (Dunite) and PCC-1 (Peridotite) by Ultrasonic and Microconcentric Desolvating Nebulisation ICP-MS

Inductively coupled plasma-mass spectrometry is well suited for the precise, accurate and rapid determination of rare earth elements in most geological samples. However, determination of rare earth elements in certain mantle-derived materials, without applying preconcentration techniques, remains problematical due to low natural concentrations (generally < 1 ng g⁻¹). Consequently, USGS reference materials DTS-1 (a dunite) and PCC-1 (a partially serpentinized harzburgite) have only suggested rather than recommended values for the rare earth elements in reference material compilations. We compared results obtained using two ICP-MS instruments: a U-5000AT ultrasonic nebuliser coupled to a PQ2+ quadrupole ICP-MS and an ELEMENT sector field ICP-MS equipped with a MCN-6000 microconcentric desolvating nebuliser, with the suggested literature values for these two reference materials. Precision and accuracy of analytical methods employed by both instruments were demonstrated by excellent relative standard deviations (< 2%) and inter-laboratory agreement (< 5%) for numerous analyses of BHVO-1 and BIR-1, which are well established with rare earth elements contents at the μg g⁻¹ level. Repeat analyses of DTS-1 and PCC-1 at each laboratory indicate that each method is generally precise to better than 5% at sub-g g⁻¹ levels. Furthermore, values from both instruments generally agree to within 10%. Our DTS-1 and PCC-1 values agree reasonably well with selected data reported in the literature (except for Ce and Sm in DTS-1) but exhibit poorer agreement with reported compilation values. With the demonstrated level of precision and accuracy, we contend that these new values for DTS-1 and PCC-1, generated by two different instruments, are the best estimates of the true whole-rock composition of these samples reported to date.     

全新世长江泥沙堆积的时空分布及通量估算

利用长江中下游、河口及口外、浙-闽沿岸陆架6个主要沉积盆地的40个晚第四纪钻孔及其年代学数据和长江口外、陆架的浅地层剖面,计算了全新世不同阶段各沉积盆地的沉积速率,并进行了近7 000年来泥沙堆积通量的估算。研究发现全新世早期距今10 000年至8 000年间长江口下切古河谷是长江泥沙的主要堆积中心,沉积速率可高达15m/ka。随着海平面上升,全新世中期长江中下游也成为长江泥沙的重要沉积盆地,其中江汉盆地的沉积速率可达10m/ka。近2 000年来,口外、陆架的堆积呈明显增加趋势,反映长江中下游盆地和河口可容空间日益减小。根据沉积速率估算,距今7 000年来长江中下游堆积泥沙约13 074×108 t,同期水下三角洲和陆架的泥沙堆积量约为9 470×108 t。研究还发现全新世以来有两个异常低沉积速率时期：距今8000-7 000年期间上述各沉积盆地沉积速率均显著低,未见长江泥沙的沉积中心; 距今4 000-2 000 年期间长江口呈现低沉积速率。 这两次异常的原因推测与海平面、气候波动事件密切相关。     

Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.     

Effects of cloud types on cloud-radiation interaction over the Asian monsoon region

This paper quantifies the sensitivity of radiation budget quantities to different cloud types over the Asian monsoon region using the International Satellite Cloud Climatology Project. Multiple regression was used to estimate the radiative effects of individual cloud type. It was observed that the regression performed better when the solution was constrained with clear sky fluxes, which is evident by an improvement in R ² statistics. The sensitivity coefficients calculated for the Asian monsoon region reveal that, while the LWCRCF and SWCRF will be most vulnerable to changes in cloud cover of deep convective clouds, NETCRF will be susceptible to changes in the nimbostratus clouds. Although the cloud radiative forcing of individual cloud types are found to be similar in sign to previous global findings, their magnitudes are found to vary. It is seen that cirrus clouds play an important role in governing the radiative behavior of this region.